Chapter 20: Problem 24
Is it a violation of the Second Law of Thermodynamics to capture all the exhaust heat from a steam engine and funnel it back into the system to do work? Why or why not?
Chapter 20: Problem 24
Is it a violation of the Second Law of Thermodynamics to capture all the exhaust heat from a steam engine and funnel it back into the system to do work? Why or why not?
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Get started for freeWhile looking at a very small system, a scientist observes that the entropy of the system spontaneously decreases. If true, is this a Nobelwinning discovery or is it not that significant?
In some of the thermodynamic cycles discussed in this chapter, one isotherm intersects one adiabatic curve. For an ideal gas, by what factor is the adiabatic curve steeper than the isotherm?
A heat engine cycle often used in refrigeration, is the Brayton cycle, which involves an adiabatic compression, followed by an isobaric expansion, an adiabatic expansion, and finally an isobaric compression. The system begins at temperature \(T_{1}\) and transitions to temperatures \(T_{2}, T_{3},\) and \(T_{4}\) after respective parts of the cycle. a) Sketch this cycle on a \(p V\) -diagram. b) Show that the efficiency of the overall cycle is given by \(\epsilon=1-\left(T_{4}-T_{1}\right) /\left(T_{3}-T_{2}\right)\).
An outboard motor for a boat is cooled by lake water at \(15.0^{\circ} \mathrm{C}\) and has a compression ratio of \(10.0 .\) Assume that the air is a diatomic gas. a) Calculate the efficiency of the engine's Otto cycle. b) Using your answer to part (a) and the fact that the efficiency of the Carnot cycle is greater than that of the Otto cycle, estimate the maximum temperature of the engine.
The entropy of a macroscopic state is given by \(S=k_{B} \ln w,\) where \(k_{B}\) is the Boltzmann constant and \(w\) is the number of possible microscopic states. Calculate the change in entropy when \(n\) moles of an ideal gas undergo free expansion to fill the entire volume of a box after a barrier between the two halves of the box is removed.
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