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A vertical cylindrical tank contains 1.80 mol of an ideal gas under a pressure of 0.300 atm at 20.0\(^\circ\)C. The round part of the tank has a radius of 10.0 cm, and the gas is supporting a piston that can move up and down in the cylinder without friction. There is a vacuum above the piston. (a) What is the mass of this piston? (b) How tall is the column of gas that is supporting the piston?

Short Answer

Expert verified
(a) The mass of the piston is approximately 97.3 kg. (b) The height of the gas column is about 4.58 m.

Step by step solution

01

Understand the Problem

We need to find the mass of the piston that the gas can support, and the height of the gas column in the tank. We are given the amount of gas (1.80 mol), the pressure (0.300 atm), the temperature (20°C), and the radius of the tank (10.0 cm). We'll use the ideal gas law and formulas for pressure and force.
02

Convert Units

Convert the pressure to Pascals and the radius to meters. The pressure is 0.300 atm, which is equivalent to:\[P = 0.300 \times 101325 \, \text{Pa} = 30397.5 \, \text{Pa}.\]The radius is 10.0 cm, which is:\[r = 0.10 \, \text{m}.\]
03

Apply the Ideal Gas Law

The ideal gas law is given by: \[ PV = nRT. \]We solve for the volume \( V \) of the gas. First, convert the temperature from Celsius to Kelvin:\[T = 20 + 273.15 = 293.15 \, \text{K}.\]Substitute the values:\[(30397.5) V = (1.80) (8.314) (293.15). \]\[ V \approx 0.1439 \, \text{m}^3. \]
04

Calculate the Area of the Piston

The area \( A \) of the piston is the same as the area of the circle of the tank's radius:\[A = \pi r^2 = \pi (0.10)^2 = 0.0314 \, \text{m}^2.\]
05

Calculate the Force Exerted by the Gas

The force \( F \) exerted by the gas can be calculated using:\[ F = PA = (30397.5) (0.0314) = 954.5 \, \text{N}.\]
06

Determine the Mass of the Piston

The mass \( m \) of the piston can be found using the equation for force, where \[F = mg. \]Therefore, \[ m = \frac{F}{g} = \frac{954.5}{9.81} \approx 97.3 \, \text{kg}.\]
07

Calculate the Height of the Gas Column

Now, to find the height \( h \) of the gas column, use:\[ V = Ah. \]Solve for \( h \):\[ h = \frac{V}{A} = \frac{0.1439}{0.0314} \approx 4.58 \, \text{m}.\]

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Pressure conversion
Converting pressure units is crucial, especially when applying formulas that require the pressure in a specific unit like Pascals. In this exercise, the initial pressure is provided in atmospheres (atm), a common unit often used when discussing gases at a macroscopic level. However, for calculations involving the ideal gas law, the pressure needs to be in Pascals (Pa), which is more widely used in scientific formulas due to being a standard SI unit.
To convert from atmospheres to Pascals, use the conversion factor:
  • 1 atm = 101,325 Pa.
This gives us the formula:
  • \[ P = 0.300 \times 101,325 \, \text{Pa} = 30,397.5 \, \text{Pa}. \]
Understanding how to switch between these two units ensures accuracy across physical equations and helps when learning about physical principles expressed in different systems.
Piston mechanics
Pistons are vital components in many engineering and physics applications because they can change the volume of gas containers, consequently affecting pressure and work.In the given problem, the piston is supported by gas within a cylindrical tank. Key aspects to consider include:
  • The area of the piston, which corresponds to the area of the tank's top circle. This is calculated through:\[ A = \pi r^2 = \pi (0.10 \, \text{m})^2 = 0.0314 \, \text{m}^2. \]
  • The force exerted by the gas on the piston. This force can be calculated by multiplying the pressure of the gas by the area of the piston:\[ F = PA = 30,397.5 \, \text{Pa} \times 0.0314 \, \text{m}^2 = 954.5 \, \text{N}. \]
  • Finally, the mass of the piston can be determined since the force exerted by the gas balances the gravitational force on the piston (assuming equilibrium):\[ m = \frac{F}{g} = \frac{954.5}{9.81} \approx 97.3 \, \text{kg}. \]
Understanding these mechanics helps explain how gases can be used to exert and balance forces in mechanical systems, highlighting the practical applications of physics principles.
Temperature conversion
Temperature conversion is essential in the application of the ideal gas law, as the law requires temperature to be in Kelvin (K), the standard SI unit for temperature.In Celsius, water freezes at 0°C, but in Kelvin, the same point is 273.15 K. To convert Celsius to Kelvin, use the simple conversion formula:
  • \[ T(\text{K}) = T(\text{°C}) + 273.15. \]
For this problem, where the temperature is 20°C, the conversion to Kelvin gives:
  • \[ T = 20 + 273.15 = 293.15 \, \text{K}. \]
Using Kelvin allows for straightforward and correct use of the ideal gas law:
  • \[ PV = nRT, \]where \( R \) is the universal gas constant.
Grasping temperature conversion is pivotal for accurately working with thermal expansion, reactions, and various gas laws across scientific disciplines.

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Most popular questions from this chapter

For diatomic carbon dioxide gas (CO\(_2\), molar mass 44.0 g/mol) at \(T\) = 300 K, calculate (a) the most probable speed \(\upsilon{_m}{_p}\); (b) the average speed \(\upsilon {_a}{_v}\); (c) the root-mean-square speed \(\upsilon {_r}{_m}{_s}\).

A 20.0-L tank contains \(4.86 \times 10{^-}{^4}\) kg of helium at 18.0\(^\circ\)C. The molar mass of helium is 4.00 g/mol. (a) How many moles of helium are in the tank? (b) What is the pressure in the tank, in pascals and in atmospheres?

An empty cylindrical canister 1.50 m long and 90.0 cm in diameter is to be filled with pure oxygen at 22.0\(^\circ\)C to store in a space station. To hold as much gas as possible, the absolute pressure of the oxygen will be 21.0 atm. The molar mass of oxygen is 32.0 g/mol. (a) How many moles of oxygen does this canister hold? (b) For someone lifting this canister, by how many kilograms does this gas increase the mass to be lifted?

The \(vapor\) \(pressure\) is the pressure of the vapor phase of a substance when it is in equilibrium with the solid or liquid phase of the substance. The \(relative\) \(humidity\) is the partial pressure of water vapor in the air divided by the vapor pressure of water at that same temperature, expressed as a percentage. The air is saturated when the humidity is 100%. (a) The vapor pressure of water at 20.0\(^\circ\)C is 2.34 \(\times\) 103 Pa. If the air temperature is 20.0\(^\circ\)C and the relative humidity is 60%, what is the partial pressure of water vapor in the atmosphere (that is, the pressure due to water vapor alone)? (b) Under the conditions of part (a), what is the mass of water in 1.00 m\(^3\) of air? (The molar mass of water is 18.0 g/mol. Assume that water vapor can be treated as an ideal gas.)

(a) Calculate the density of the atmosphere at the surface of Mars (where the pressure is 650 Pa and the temperature is typically 253 \(K\), with a \(CO_2\) atmosphere), Venus (with an average temperature of 730 \(K\) and pressure of 92 atm, with a \(CO_2\) atmosphere), and Saturn's moon Titan (where the pressure is 1.5 atm and the temperature is -178\(^\circ\)C, with a \(N_2\) atmosphere). (b) Compare each of these densities with that of the earth's atmosphere, which is 1.20 kg/m\(^3\). Consult Appendix D to determine molar masses.

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