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State whether each of the following statements is true or false a) In a one-dimensional quantum harmonic oscillator, the energy levels are evenly spaced. b) In an infinite one-dimensional potential well, the energy levels are evenly spaced. c) The minimum total energy possible for a classical harmonic oscillator is zero. d) The correspondence principle states that because the minimum possible total energy for the classical simple harmonic oscillator is zero, the expected value for the fundamental state \((n=0)\) of the one-dimensional quantum harmonic oscillator should also be zero. e) The \(n=0\) state of the one-dimensional quantum harmonic oscillator is the state with the minimum possible uncertainty \(\Delta x \Delta p\)

Short Answer

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Step by step solution

01

a) In a one-dimensional quantum harmonic oscillator, the energy levels are evenly spaced.

True. The energy levels of a one-dimensional quantum harmonic oscillator follow the formula \(E_n = (n+\frac{1}{2})\hbar\omega\), where \(n = 0, 1, 2, 3,...\) is the quantum number, \(\hbar\) is the reduced Planck's constant, and \(\omega\) is the angular frequency. As we can see, the energy levels differ by a constant value of \(\hbar\omega\) for each step in \(n\). Therefore, the energy levels are evenly spaced.
02

b) In an infinite one-dimensional potential well, the energy levels are evenly spaced.

False. The energy levels in an infinite one-dimensional potential well follow the formula \(E_n = \frac{n^2 \pi^2\hbar^2}{2mL^2}\), where \(n = 1, 2, 3, ...\) is the quantum number, \(\hbar\) is the reduced Planck's constant, \(m\) is the mass of the particle, and \(L\) is the width of the well. As \(n\) increases, the difference between consecutive energy levels increases. Therefore, the energy levels are not evenly spaced.
03

c) The minimum total energy possible for a classical harmonic oscillator is zero.

True. For a classical harmonic oscillator, the total energy consists of kinetic energy and potential energy. The minimum total energy occurs when the potential energy is at its minimum and the kinetic energy is zero (the particle is at rest). In this situation, the minimum total energy is zero.
04

d) The correspondence principle states that because the minimum possible total energy for the classical simple harmonic oscillator is zero, the expected value for the fundamental state \((n=0)\) of the one-dimensional quantum harmonic oscillator should also be zero.

False. The correspondence principle states that the behavior of a quantum system should approach the classical behavior in the limit of large quantum numbers. This doesn't mean that the minimum possible total energy for the quantum harmonic oscillator should be zero. In fact, the ground state energy of a one-dimensional quantum harmonic oscillator is given by the formula \(E_0 = \frac{1}{2}\hbar\omega\), which is non-zero.
05

e) The \(n=0\) state of the one-dimensional quantum harmonic oscillator is the state with the minimum possible uncertainty \(\Delta x \Delta p\)

True. According to the Heisenberg uncertainty principle, the product of the uncertainties in position and momentum has a minimum value \(\Delta x \Delta p \geq \frac{1}{2}\hbar\). For a one-dimensional quantum harmonic oscillator, the ground state (when \(n=0\)) achieves this minimum possible uncertainty. In this state, the wave function represents a Gaussian distribution, which optimally satisfies the uncertainty principle.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Energy Levels
Understanding energy levels in quantum systems is essential for grasping the nature of quantum mechanics. In a one-dimensional quantum harmonic oscillator, the energy levels are indeed evenly spaced. The energy in this system is described by the formula \(E_n = (n+\frac{1}{2})\hbar\omega\), where \(n\) represents the quantum number. Here, \(\hbar\) is the reduced Planck's constant and \(\omega\) stands for the angular frequency of the oscillator. The evenly spaced nature is due to the term \(\hbar\omega\), which adds the same amount of energy for each consecutive level.

However, when dealing with an infinite potential well, the scenario changes. The energy levels follow \(E_n = \frac{n^2 \pi^2\hbar^2}{2mL^2}\). This indicates that the spacing between levels increases as \(n\) grows larger. Hence, the energy levels are not evenly spaced in an infinite potential well. This difference in spacing is due to the \(n^2\) dependence, which causes a quadratic increase in energy with respect to the quantum number.
Infinite Potential Well
The infinite potential well is a fundamental concept in quantum mechanics, illustrating how quantum particles behave under constraints. In this model, a particle is confined to a box with perfectly rigid walls, creating a situation where its wave function is zero outside the well, forcing specific allowed energy levels inside.

The energy levels in an infinite potential well are determined by \(E_n = \frac{n^2 \pi^2 \hbar^2}{2mL^2}\). This expression shows that as the quantum number \(n\) increases, the energy levels rise in a nonlinear (quadratic) manner, explaining why they aren't evenly spaced. This contrasts with the linear spacing observed in the quantum harmonic oscillator. This characteristic behavior is crucial in understanding the quantization of energy states in constrained quantum systems.
Heisenberg Uncertainty Principle
The Heisenberg Uncertainty Principle is a cornerstone of quantum mechanics, positing that certain pairs of physical properties, like position and momentum, cannot simultaneously be measured with arbitrary precision. The principle is mathematically represented as \(\Delta x \Delta p \geq \frac{1}{2}\hbar\).

This principle highlights the concept of intrinsic uncertainty in quantum states, emphasizing that the more precisely one property is measured, the less precisely the other can be ascertained. For the ground state \((n=0)\) of a quantum harmonic oscillator, the system reaches this minimal uncertainty relationship. The ground state is often represented by a Gaussian wave function, which is adept at achieving this precise balance of measurement in position and momentum.
Correspondence Principle
The correspondence principle bridges the gap between classical and quantum mechanics. It asserts that the predictions of quantum mechanics should reconcile with classical physics in the limit of large quantum numbers. This principle implies that as systems grow larger or as quantum numbers increase, the quantum behavior appears more classical.

In the context of a quantum harmonic oscillator, while one might expect based on classical intuition that the minimum possible total energy \(E_0\) should be zero, quantum mechanics dictates otherwise. The ground state energy is \(E_0 = \frac{1}{2}\hbar\omega\), which is not zero. This non-zero ground state energy, termed "zero-point energy," underscores how quantum systems retain properties absent in classical systems, even as they transition toward classicality. This highlights the distinctive characteristics of quantum systems, even when they approximate classical behavior.

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Most popular questions from this chapter

A surface is examined using a scanning tunneling microscope (STM). For the range of the working gap, \(L\), between the tip and the sample surface, assume that the electron wave function for the atoms under investigation falls off exponentially as \(|\Psi|=e^{-\left(10.0 \mathrm{nm}^{-1}\right) a}\). The tunneling current through the STM tip is proportional to the tunneling probability. In this situation, what is the ratio of the current when the STM tip is \(0.400 \mathrm{nm}\) above a surface feature to the current when the tip is \(0.420 \mathrm{nm}\) above the surface?

Is the superposition of two wave functions, which are solutions to the Schrödinger equation for the same potential energy, also a solution to the Schrödinger equation? a) no b) yes c) depends on potential energy d) only if \(\frac{d^{2} \psi(x)}{d x^{2}}=0\)

The wavelength of an electron in an infinite potential is \(\alpha / 2,\) where \(\alpha\) is the width of the infinite potential well. Which state is the electron in? a) \(n=3\) b) \(n=6\) c) \(n=4\) d) \(n=2\)

Is it possible for the expectation value of the position of an electron to occur at a position where the electron's probability function, \(\Pi(x)\), is zero? If it is possible, give a specific example.

Consider an attractive square-well potential, \(U(x)=0\) for \(x<-\alpha, U(x)=-U_{0}\) for \(-\alpha \leq x \leq \alpha\) where \(U_{0}\) is a positive constant, and \(U(x)=0\) for \(x>\alpha .\) For \(E>0,\) the solution of the Schrödinger equation in the 3 regions will be the following: For \(x<-\alpha, \psi(x)=e^{i \kappa x}+R e^{-i \kappa x}\) where \(\kappa^{2}=2 m E / \hbar^{2}\) and \(R\) is the amplitude of a reflected wave. For \(-\alpha \leq x \leq \alpha, \psi(x)=A e^{i \kappa^{\prime} x}+B e^{-i \kappa^{\prime} x}\) and \(\left(\kappa^{\prime}\right)^{2}=2 m\left(E+U_{0}\right) / \hbar^{2}\). For \(x>\alpha, \psi(x)=T e^{i \kappa x}\) where \(T\) is the amplitude of the transmitted wave. Match \(\psi(x)\) and \(d \psi(x) / d x\) at \(-\alpha\) and \(\alpha\) and find an expression for \(R\). What is the condition for which \(R=0\) (that is, there is no reflected wave)?

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