Chapter 37: Problem 35
Consider an electron approaching a potential barrier \(2.00 \mathrm{nm}\) wide and \(7.00 \mathrm{eV}\) high. What is the energy of the electron if it has a \(10.0 \%\) probability of tunneling through this barrier?
Chapter 37: Problem 35
Consider an electron approaching a potential barrier \(2.00 \mathrm{nm}\) wide and \(7.00 \mathrm{eV}\) high. What is the energy of the electron if it has a \(10.0 \%\) probability of tunneling through this barrier?
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Get started for freeAn electron in a harmonic potential well emits a photon with a wavelength of \(360 \mathrm{nm}\) as it undergoes a \(3 \rightarrow 1\) quantum jump. What wavelength photon is emitted in a \(3 \rightarrow 2\) quantum jump? (Hint: The energy of the photon is equal to the energy difference between the initial and the final state of the electron.)
Example 37.1 calculates the energy of the wave function with the lowest quantum number for an electron confined to a box of width \(2.00 \AA\) in the one-dimensional case. However, atoms are three-dimensional entities with a typical diameter of \(1.00 \AA=10^{-10} \mathrm{~m} .\) It would seem then that the next, better approximation would be that of an electron trapped in a three-dimensional infinite potential well (a potential cube with sides of \(1.00 \mathrm{~A}\) ). a) Derive an expression for the electron wave function and the corresponding energies for a particle in a three dimensional rectangular infinite potential well. b) Calculate the lowest energy allowed for the electron in this case.
Suppose a quantum particle is in a stationary state (energy eigenstate) with a wave function \(\psi(x, t) .\) The calculation of \(\langle x\rangle,\) the expectation value of the particle's position, is shown in the text. Calculate \(d\langle x\rangle / d t(\operatorname{not}\langle d x / d t\rangle)\).
Think about what happens to infinite square well wave functions as the quantum number \(n\) approaches infinity. Does the probability distribution in that limit obey the correspondence principle? Explain.
Find the ground state energy (in units of eV) of an electron in a one- dimensional quantum box, if the box is of length \(L=0.100 \mathrm{nm}\).
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