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Question: An ideal monatomic gas is contained in a tall cylindrical jar of cross-sectional area \({\bf{0}}{\bf{.080}}\;{{\bf{m}}^{\bf{2}}}\) fitted with an airtight frictionless 0.15-kg movable piston. When the gas is heated (at constant pressure) from 25°C to 55°C, the piston rises 1.0 cm. How much heat was required for this process? Assume atmospheric pressure outside. (Hint: See Section 14–2.)

Short Answer

Expert verified

The heat required for this process is \(202\;{\rm{J}}\).

Step by step solution

01

Determination of pressure

The pressure can be obtained by dividing the force exerted on an object by the cross-sectional area of the object. Its value is inversely related to the value of the cross-sectional area of the object.

02

Given information

The cross-sectional area of the cylinder is \(A = 0.080\;{{\rm{m}}^{\rm{2}}}\).

The atmospheric pressure or outside pressure is \({P_{\rm{o}}} = 1.01 \times {10^5}\;{\rm{Pa}}\).

The mass of the piston is \(m = 0.15\;{\rm{kg}}\).

The displacement of the piston is \(\Delta y = 1.0\;{\rm{cm}}\).

03

Evaluation of the pressure inside the cylindrical jar

The pressure inside the cylindrical jar is calculated below:

\(\begin{aligned}{c}{P_{\rm{i}}} &= {P_{\rm{o}}} + \frac{{mg}}{A}\\{P_{\rm{i}}} &= \left( {1.01 \times {{10}^5}\;{\rm{Pa}}} \right) + \frac{{\left( {0.15\;{\rm{kg}}} \right)\left( {9.8\;{{\rm{m}} \mathord{\left/{\vphantom {{\rm{m}} {{{\rm{s}}^{\rm{2}}}}}} \right.} {{{\rm{s}}^{\rm{2}}}}}} \right)}}{{\left( {0.080\;{{\rm{m}}^{\rm{2}}}} \right)}}\\{P_{\rm{i}}} &= 1.0102 \times {10^5}\;{\rm{Pa}} \approx {\rm{1}}{\rm{.01}} \times {\rm{1}}{{\rm{0}}^5}\;{\rm{Pa}}\end{aligned}\)

The change in the pressure is negligible; therefore, the system can be treated as a constant pressure process.

04

Evaluation of the heat required for the process

The heat required for the process is calculated below:

\(\begin{aligned}{l}Q &= \Delta U + W\\Q &= \frac{3}{2}P\Delta V + P\Delta V\\Q &= \frac{5}{2}P\Delta V\\Q &= \frac{5}{2}PA\Delta y\end{aligned}\)

Substitute the values in the above equation.

\(\begin{aligned}{c}Q &= \frac{5}{2}\left( {1.01 \times {{10}^5}\;{\rm{Pa}}} \right)\left( {0.080\;{{\rm{m}}^{\rm{2}}}} \right)\left( {1.0\;{\rm{cm}}} \right)\left( {\frac{{{\rm{1}}{{\rm{0}}^{{\rm{ - 2}}}}\;{\rm{m}}}}{{{\rm{1}}\;{\rm{cm}}}}} \right)\\Q &= 202\;{\rm{J}}\end{aligned}\)

Thus, the heat required for this process is \(202\;{\rm{J}}\).

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Most popular questions from this chapter

(II) A gas is enclosed in a cylinder fitted with a light frictionless piston and maintained at atmospheric pressure. When 254 kcal of heat is added to the gas, the volume is observed to increase slowly from to \({\bf{16}}{\bf{.2}}\;{{\bf{m}}^{\bf{3}}}\).Calculate (a) the work done by the gas and (b) the change in internal energy of the gas.

A 38% efficient power plant puts out 850 MW of electrical power. Cooling towers take away the exhaust heat.

(a) If the air \(\left( {{\bf{k}}{{\bf{m}}{\bf{3}}}} \right)\) temperature is allowed to rise by 7.0°C, estimate what volume of air is heated per day. Will the local climate be heated significantly?

(b) If the heated air were to form a layer 180 m thick, estimate how large an area it would cover for 24 h of operation. Assume the air has a density of \({\bf{1}}{\bf{.3 kg/}}{{\bf{m}}{\bf{3}}}\) and a specific heat of about \({\bf{1}}{\bf{.0}}{\rm{ }}{\bf{kJ/kg}} \cdot {\bf{\circ C}}\) at constant pressure.

On a very hot day, could you cool your kitchen by leaving the refrigerator door open?

(a) Yes, but it would be very expensive.

(b) Yes, but only if the humidity is below 50%.

(c) No, the refrigerator would exhaust the same amount of heat into the room as it takes out of the room.

(d) No, the heat exhausted by the refrigerator into the room is more than the heat the refrigerator takes out of the room.

Question: Living organisms, as they grow, convert relatively simple food molecules into complex structures. Is this a violation of the second law of thermodynamics? Explain your answer.

Question: Give three examples, other than those mentioned in this Chapter, of naturally occurring processes in which order goes to disorder. Discuss the observability of the reverse process.

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