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Show that the constant b used in the quantum-harmonic-oscillator wave functions (a) has units of length and (b) is the classical turning point of an oscillator in the n=1ground state.

Short Answer

Expert verified

All the statements are proved.

Step by step solution

01

Part (a) Step 1: Given information 

We have given,

System of quantum harmonic oscillator.

We have to find the unit of constant b.

02

Simplify

Since we know that the value of b is given by,

b=h2πmω

Where

h has unit J.s and m has unit of kg and w is in per second then,

bunit=ML2T-1MT-112bunit=L

Hence proved.

03

Part (b) Step 1: Given information

We have to show that b is classical turning point for ground state.

04

Simplify

To show that the classical turning point is b is ,

E=12kx2=12mω2A2A=2Emω2A=2mω2(n+1)hω2πA=(2n+1)h2πmωfor,n=0A=h2πmω=bb=x

Hence proved.

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Most popular questions from this chapter

In most metals, the atomic ions form a regular arrangement called a crystal lattice. The conduction electrons in the sea of electrons move through this lattice. FIGURE CP40.47is a one-dimensional model of a crystal lattice. The ions have mass m, charge eand an equilibrium separation b.

a. Suppose the middle charge is displaced a very small distance xbfrom its equilibrium position while the outer charges remain fixed. Show that the net electric force on the middle charge is given approximately by

F=e2b3πε0x

In other words, the charge experiences a linear restoring force.

b. Suppose this crystal consists of aluminum ions with an equilibrium spacing of 0.30nm. What are the energies of the four lowest vibrational states of these ions?

c. What wavelength photons are emitted during quantum jumps between adjacent energy levels? Is this wavelength in the infrared, visible, or ultraviolet portion of the spectrum?

A particle confined in a rigid one-dimensional box of length 10fmhas an energy level En=32.9MeVand an adjacent energy level En+1=51.4MeV.

a. Determine the values of n and n + 1.

b. Draw an energy-level diagram showing all energy levels from 1 through n + 1. Label each level and write the energy beside it.

c. Sketch the n + 1 wave function on the n + 1 energy level.

d. What is the wavelength of a photon emitted in the n+1ntransition? Compare this to a typical visible-light wavelength.

e. What is the mass of the particle? Can you identify it?

The graph in FIGURE EX40.16 shows the potential-energy function U(x of a particle. Solution of the Schrödinger equation finds that the n=3 level has E3=0.5eVand that the n=6 level has E6=2.0eV.

a. Redraw this figure and add to it the energy lines for the n=3 and n=6 states.

b. Sketch the n=3 and n=6 wave functions. Show them as oscillating about the appropriate energy line.

FIGURE Q40.7shows two possible wave functions for an electron in a linear triatomic molecule. Which of these is a bonding orbital and which is an antibonding orbital? Explain how you can distinguish them.

a. Determine the normalization constant A1for the n=1ground-state wave function of the quantum harmonic oscillator. Your answer will be in terms of b.

b. Write an expression for the probability that a quantum harmonic oscillator in its n=1ground state will be found in the classically forbidden region.

c. (Optional) Use a numerical integration program to evaluate your probability expression of part b.

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