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Sketch the n=8wave function for the potential energy shown in FIGURE EX40.14.

Short Answer

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The shape of the n=8 wave function for the potential energy,

Step by step solution

01

Step 1. Given information

Considering the three factors to sketch the graph for n=8wave function.

(1) If the speed and kinetic energy of the particle decreases, the de Broglie wavelength increases because de Broglie wavelength is inversely dependent on speed of the particle. Hence, the spacing between the nodes of the wave function will increases in regions where the potential energy is larger (or where the kinetic energy is smaller).

(2) The classical particle is more likely to be found where it moves more slowly. In quantum mechanics, the probability of finding the particle increases when the amplitude of the wave function increases. Consequently, the amplitude of the wave function is larger in regions where the potential energy is larger.

(3) The wave function for quantum state n has (n-1) nodes and n, antinodes. Therefore, the wave function has four antinodes for n=8quantum state.

02

Step 2. The shape ofn=8 wave function for the potential energy,

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Most popular questions from this chapter

Verify that the n=1 wave function ψ1(x) of the quantum harmonic oscillator really is a solution of the Schrödinger equation. That is, show that the right and left sides of the Schrödinger equation are equal if you use the ψ1(x) wave function.

What is the probability that an electron will tunnel through a 0.45nmgap from a metal to a STM probe if the work function is 4.0eV?

Model an atom as an electron in a rigid box of length 0.100nm, roughly twice the Bohr radius.

a. What are the four lowest energy levels of the electron?

b. Calculate all the wavelengths that would be seen in the emission spectrum of this atom due to quantum jumps between these four energy levels. Give each wavelength a label λnmto indicate the transition.

c. Are these wavelengths in the infrared, visible, or ultraviolet portion of the spectrum?

d. The stationary states of the Bohr hydrogen atom have negative energies. The stationary states of this model of the atom have positive energies. Is this a physically significant difference? Explain.

e. Compare this model of an atom to the Bohr hydrogen atom. In what ways are the two models similar? Other than the signs of the energy levels, in what ways are they different?

| FIGURE EX40.4 shows the wave function of an electron in a rigid box. The electron energy islocalid="1650137157775" 12.0eV. What is the energy, in localid="1650137162096" eV, of the next higher state?

| FIGURE EX 40.3shows the wave function of an electron in a rigid box. The electron energy is25eV. How long is the box?

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