Chapter 8: Q71E (page 344)
Repeat example 8.6 but assume that the upper state is the rather than the
Short Answer
The and states are both split into two levels.
Chapter 8: Q71E (page 344)
Repeat example 8.6 but assume that the upper state is the rather than the
The and states are both split into two levels.
All the tools & learning materials you need for study success - in one app.
Get started for freeWhat is the minimum possible energy for five (non-interacting) spin particles of massmin a one dimensional box of length L ? What if the particles were spin-1? What if the particles were spin ?
Using the general rule for adding angular momenta discussed in Section 8.7 and further in Exercise 66, Find the allowed values offor three spin fermions. First add two, then add the third.
A Simple Model: The multielectron atom is unsolvable, but simple models go a long way. Sectiongives energies and orbit radii forone-electron/hydrogenlike atoms. Let us see how useful these are by considering lithium.
(a) Treat one of lithium'selectrons as a single electron in a one-electron atom ofrole="math" localid="1659948261120" . Find the energy and orbit radius.
(b) The otherelectron being in the same spatial state. must have the same energy and radius, but we must account for the repulsion between these electrons. Assuming they are roughly one orbit diameter apart, what repulsive energy would they share, and if each claims half this energy. what would be the energies of these two electrons?
(c) Approximately what charge does lithium's lone valence electron orbit, and what radius and energy would it have?
(d) Is in reasonable to dismiss the role of theelectrons in chemical reactions?
(e) The actual energies of lithium's electrons are about(twice, of course) and. How good is the model?
(f) Why should the model's prediction for the valence electron's energy differ in the direction it does from the actual value?
To investigate the claim that lowerimplies lower f energy. consider a simple case: lithium. which has twoelectrons and alonevalence electron.
(a)First find the approximate orbit radius, in terms of. of anelectron orbiting three protons. (Refer to Section 7.8.)
(b) Assuming theelectrons shield/cancel out two of the protons in lithium's nucleus, the orbit radius of anelectron orbiting a net charge of just.
(c) Argue that lithium's valence electron should certainly have lower energy in a 25 state than in astale. (Refer Figure 7.15.)
What angles might the intrinsic angular momentum vector make with the z-axis for a deuteron? (See Table 8.1)
What do you think about this solution?
We value your feedback to improve our textbook solutions.