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The Slater determinant is introduced in Exercise 42. Show that if states nand n'of the infinite well are occupied and both spins are up, the Slater determinant yields the antisymmetric multiparticle state:ψn(x1)ψn'(x2)ψn'(x1)ψn(x2)

Short Answer

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The resultant answer is proved.

Step by step solution

01

Given data

The given data is ψn(x1)ψn(x2)ψn(x1)ψn(x2).

02

Concept of Slater determinant

A determinant is an expression that describes the wave function of a multi-fermionic system.

It satisfies anti-symmetry requirements, and consequently the Pauli principle, by changing sign upon exchange of two electrons (or other fermions).

03

Simplify the expression

The multi particle for fermions of anti-symmetric character can be expressed with the help of Slater determinant.

The two wave functionsψ(x1) and ψ(x2) have states n and n' that are occupied for both spins up.

The Slater determinant of these states can be expressed by the determinant of 2×2matrix as shown below.

ψ=ψn(x1)ψn(x1)ψn(x2)ψm(x2)ψ=ψn(x1)ψm(x2)ψn(x1)ψn(x2)

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Most popular questions from this chapter

Were it to follow the standard pattern, what would be the electronic configuration of element 119.

A lithium atom has three electrons. These occupy individual particle states corresponding to the sets of four quantum numbers given by .

(n,l,ml,mj)=(1,0,0,+12),(1,0,0,-12)and(2,0,0,+12)

Using ψ1,0,0(rj),ψ1,0,0(rj),andψ2,0,0(rj) to represent the individual-particle states when occupied by particlej . Apply the Slater determinant discussed in Exercise 42 to find an expression for an antisymmetric multiparticle state. Your answer should be sums of terms like .

ψ1,0,0(r1),ψ1,0,0(r2),andψ2,0,0(r3)

Angular momenta J1and J2interact so that they obey the strict quantum mechanical rules for angular momentum addition. If J1=1and J2=32what angles between J1and J2 allowed?

A hydrogen atom is subjected to a magnetic field Bstrong enough to completely overwhelm the spin-orbit coupling. Into how many levels would the 2p level split, and what would be the spacing between them?

To investigate the claim that lowerimplies lower f energy. consider a simple case: lithium. which has twon=1electrons and alonen=2valence electron.

(a)First find the approximate orbit radius, in terms ofa0. of ann=1electron orbiting three protons. (Refer to Section 7.8.)

(b) Assuming then=1electrons shield/cancel out two of the protons in lithium's nucleus, the orbit radius of ann=2electron orbiting a net charge of just+e.

(c) Argue that lithium's valence electron should certainly have lower energy in a 25 state than in a2pstale. (Refer Figure 7.15.)

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