Warning: foreach() argument must be of type array|object, bool given in /var/www/html/web/app/themes/studypress-core-theme/template-parts/header/mobile-offcanvas.php on line 20

Here we Pursue the more rigorous approach to the claim that the property quantized according to ml is Lz,

(a) Starting with a straightforward application of the chain rule,

φ=xφ/x+yφy+zφz

Use the transformations given in Table 7.2 to show that

φ=-yx+xy

(b) Recall that L = r x p. From the z-component of this famous formula and the definition of operators for px and py, argue that the operator for Lz is -ihφ..

(c) What now allows us to say that our azimuthal solutioneimlφ has a well-defined z-component of angular momentum and that is value mlh.

Short Answer

Expert verified

(a) φ=-yx+xy

(b)Lz is the operator from eq(1) multiplied by -ih or -ihφ.

(c) When the operator operates on the function, it gives the product of itself and the well-defined observable.

Step by step solution

01

Given data

The function given is φ=xφ/x+yφy+zφz.

02

(a) Application of chain rule using transformations

The chain rule is a technique for finding the differential of composite functions.

Given,

φ=xφ/x+yφy+zφz

From table 7.2, we know that, distances from the origin on all the axes are given by:

x=rsinθcosϕy=rsinθsinφz=rcosθ

Now, if you use the equations given above to solve the given equation

xφ=rsinθcosφφx+rsinθsinφφy+rcosθφz=rsinθcosφy-rsinθsinφx+0z=-yx+xy(1)

Thus we found φ=-yx+xy..

03

(b) Operator of Lz

As you know that, the z-component of L is x.py – y.px.

You also know that, px=-ihxandpy=-ihy

Where, h = Plank’s constant

Hence, now the equation (1) becomes,

φ=-ypx-ih+xpy-ih

And you can see that Lz is the operator from eq (1) multiplied by -ih orrole="math" localid="1659177997912" -ihφ.

Thus,Lz is the operator from eq (1) multiplied by -ih or -ihφ.

04

(c) z-component of angular momentum

From section 5.11, you know that when the operator operates on the function, it gives the product of itself and the well-defined observable.

Hence,

-ihφeimlφ=mlheimlφ

Thus, when the operator operates on the function, it gives the product of itself and the well-defined observable

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

  1. What are the initial and final energy levels for the third (i.e., third-longest wavelength) line in the Paschen series? (See Figure 7.5)
  2. Determine the wavelength of this line.

The Diatomic Molecule: Exercise 80 discusses the idea of reduced mass. Classically or quantum mechanically, we can digest the behavior of a two-particle system into motion of the center of mass and motion relative to the center of mass. Our interest here is the relative motion, which becomes a one-particle problem if we merely use μfor the mass for that particle. Given this simplification, the quantum-mechanical results we have learned go a long way toward describing the diatomic molecule. To a good approximation, the force between the bound atoms is like an ideal spring whose potential energy is 12kx2, where x is the deviation of the atomic separation from its equilibrium value, which we designate with an a. Thus,x=r-a . Because the force is always along the line connecting the two atoms, it is a central force, so the angular parts of the Schrödinger equation are exactly as for hydrogen, (a) In the remaining radial equation (7- 30), insert the potential energy 12kx2and replace the electron massm with μ. Then, with the definition.f(r)=rR(r), show that it can be rewritten as

-ħ22μd2dr2f(r)+ħ2I(I+1)2μr2f(r)+12kx2f(r)=Ef(r)

With the further definition show that this becomes

-ħ22μd2dx2g(x)+ħ2I(I+1)2μ(x+a)g(x)+12kx2g(x)=Eg(x)

(b) Assume, as is quite often the case, that the deviation of the atoms from their equilibrium separation is very small compared to that separation—that is,x<<a. Show that your result from part (a) can be rearranged into a rather familiar- form, from which it follows that
E=(n+12)ħkμ+ħ2I(I+1)2μa2n=0,1,2,...I=0,1,2,...

(c)

Identify what each of the two terms represents physically.

Consider an electron in the ground state of a hydrogen atom. (a) Sketch plots of E and U(r) on the same axes (b) Show that, classically, an electron with this energy should not be able to get farther than 2a0from the proton. (c) What is the probability of the electron being found in the classically forbidden region?

We have noted that for a given energy, as lincreases, the motion is more like a circle at a constant radius, with the rotational energy increasing as the radial energy correspondingly decreases. But is the radial kinetic energy 0 for the largest lvalues? Calculate the ratio of expectation values, radial energy to rotational energy, for the(n,l,mt)=(2.1,+1)state. Use the operators

KErad=-h22m1r2r(rr)KErad=h2l(l+1)2mr2

Which we deduce from equation (7-30).

A hydrogen atom electron is in a 2p state. If no experiment has been done to establish a z-component of angular momentum, the atom is equally likely to be found with any allowed value of LZ. Show that if the probability densities for these different possible states are added (with equal weighting), the result is independent of both ϕandθ

See all solutions

Recommended explanations on Physics Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free