Chapter 7: Q36E (page 281)
Prove that if the functionis to meet itself smoothly whenchanges by , must be an integer.
Short Answer
For the function to have a period of , must be an integer.
Chapter 7: Q36E (page 281)
Prove that if the functionis to meet itself smoothly whenchanges by , must be an integer.
For the function to have a period of , must be an integer.
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Get started for freeWhen applying quantum mechanics, we often concentrate on states that qualify as “orthonormal”, The main point is this. If we evaluate a probability integral over all space of or of , we get 1 (unsurprisingly), but if we evaluate such an integral for we get 0. This happens to be true for all systems where we have tabulated or actually derived sets of wave functions (e.g., the particle in a box, the harmonic oscillator, and the hydrogen atom). By integrating overall space, show that expression (7-44) is not normalized unless a factor of is included with the probability.
Calculate the “series limit” of the Lyman series of spectral lines. This is defined as the shortest wavelength possible of a photon emitted in a transition from a higher initial energy level to the final level. (Note: In figure 7.5, the spectral lines of the series “crowd together” at the short-wavelength end of the series).
Knowing precisely all components of a nonzero would violate the uncertainty principle, but knowingthat is precisely zerodoes not. Why not?
(Hint:For states, the momentum vector is radial.)
Consider a cubic 3D infinite well.
(a) How many different wave functions have the same energy as the one for which ?
(b) Into how many different energy levels would this level split if the length of one side were increased by ?
(c) Make a scale diagram, similar to Figure 3, illustrating the energy splitting of the previously degenerate wave functions.
(d) Is there any degeneracy left? If so, how might it be “destroyed”?
Question: Show that the angular normalization constant in Table 7.3 for the case is correct.
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