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Question: Explain to your friend. who has just learned about simple one-dimensional standing waves on a string fixed at its ends, why hydrogen's electron has only certain energies, and why, for some of those energies, the electron can still be in different states?

Short Answer

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Answer:

If the energy levels are limited, still waves can have different orientations and may result in a different state but of the same energy.

Step by step solution

01

Significance of the one-dimensional standing waves

One-dimensional standing waves can be observed when a medium is having its opposite ends fixed, and nodes are located at the endpoints. The simplest example of the one-dimensional standing wave will be the one having only one antinode in the middle. This will be half of the wavelength.

02

Identification of reason for electrons having the same energy but different states

The electron of hydrogen behaves as a wave of the bound state, that is why they have only certain energy or certain allowed standing waves. But when multiple dimensions are introduced in space, it is possible to have different standing waves but still have the same frequency/energy.

Assume a square wave of two dimensions for instance, the energy/frequency of the wave will be the same for both the following conditions,

(i) when the wave contains two waves along –axis and one wave along -axis

(ii) when the wave contains two waves along -axis and one wave along –axis.

Thus, if the energy levels are limited, still waves can have different orientations and may result in a different state but of the same energy.

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Most popular questions from this chapter

Verify for the angular solutions (θ)φ(ϕ)of Table 7.3 that replacing ϕ with ϕ+π and replacing θ with π-θgives the same function whenis even and the negative of the function when lis odd.

Question: Section 7.5 argues that knowing all three components of would violate the uncertainty principle. Knowing its magnitude and one component does not. What about knowing its magnitude and two components? Would be left any freedom at all and if so, do you think it would be enough to satisfy the uncertainly principle?

The only visible spectral lines of hydrogen are four Balmer series lines noted at the beginning of Section 7.3. We wish to cause hydrogen gas to glow with its characteristic visible colors.

(a) To how high an energy level must the electrons be exited?

(b) Energy is absorbed in collisions with other particles. Assume that after absorbing energy in one collision, an electron jumps down through lower levels so rapidly that it is in the ground state before another collision occurs. If an electron is to be raised to the level found in part (a), how much energy must be available in a single collision?

(c) If such energetic collisions are to be affected simply by heating the gas until the average kinetic energy equals the desired upward energy jump, what temperature would be required? (This explains why heating is an impractical way to observe the hydrogen spectrum. Instead, the atoms are ionized by strong electric fields, as is the air when a static electric spark passes through.)

Consider a cubic 3D infinite well.

(a) How many different wave functions have the same energy as the one for which (nx,ny,nz)=(5,1,1)?

(b) Into how many different energy levels would this level split if the length of one side were increased by 5% ?

(c) Make a scale diagram, similar to Figure 3, illustrating the energy splitting of the previously degenerate wave functions.

(d) Is there any degeneracy left? If so, how might it be “destroyed”?

Consider a vibrating molecule that behaves as a simple harmonic oscillator of mass 10-27kg, spring constant 103N/m and charge is +e , (a) Estimate the transition time from the first excited state to the ground state, assuming that it decays by electric dipole radiation. (b) What is the wavelength of the photon emitted?

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