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To determine the classical expectation value of the position of a particle in a box is L2 , the expectation value of the square of the position of a particle in a box isrole="math" localid="1658324625272" L23 , and the uncertainty in the position of a particle in a box isL12 .

Short Answer

Expert verified

The uncertainty in the position of a particle in a box of lengthLisΔx=x2x¯2=L23L24=L12.

Step by step solution

01

Step 1:

Given information: The classical probability per unit length of finding a particle in a box of lengthL is1L along the entire length of the box i.e.dPdx=1L .

02

Step 2:

The classical expectation value of the position of a particle in a box of length Lis

x¯=0LxdP=0LxdPdxdx=1L0Lxdx=1L×L22=L2.

The expectation value of the square of the position of a particle in a box of length role="math" localid="1658325211080" Lis

x2¯=0Lx2dP=0Lx2dPdxdx=1L0Lx2dx=1L×L33=L23

The uncertainty in the position of a particle in a box of length Lis

Δx=x2x¯2=L23L24=L12

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Most popular questions from this chapter

Consider the delta well potential energy:

U(x)={0x0-x=0

Although not completely realistic, this potential energy is often a convenient approximation to a verystrong, verynarrow attractive potential energy well. It has only one allowed bound-state wave function, and because the top of the well is defined as U = 0, the corresponding bound-state energy is negative. Call its value -E0.

(a) Applying the usual arguments and required continuity conditions (need it be smooth?), show that the wave function is given by

ψ(x)=(2mE0h2)1/4e-(2mE0/)|x|

(b) Sketch ψ(x)and U(x) on the same diagram. Does this wave function exhibit the expected behavior in the classically forbidden region?

Consider a particle of mass mand energy E in a region where the potential energy is constant U0. Greater than E and the region extends tox=+

(a) Guess a physically acceptable solution of the Schrodinger equation in this region and demonstrate that it is solution,

(b) The region noted in part extends from x = + 1 nm to +. To the left of x = 1nm. The particle’s wave function is Dcos (109m-1 x). Is also greater than Ehere?

(c) The particle’s mass m is 10-3 kg. By how much (in eV) doesthe potential energy prevailing from x=1 nm to U0. Exceed the particle’s energy?

A student of classical physics says, "A charged particle. like an electron orbiting in a simple atom. shouldn't have only certain stable energies: in fact, it should lose energy by electromagnetic radiation until the atom collapses." Answer these two complaints qualitatively. appealing to as few fundamental claims of quantum mechanics as possible.

What is the probability that the particle would be found between x = 0and x = 1/a?

Determine the particle’s most probable position.

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