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Whereas an infinite well has an infinite number of bound states, a finite well does not. By relating the well heightU0 to the kinetic energy and the kinetic energy (through λ) to n and L. Show that the number of bound states is given roughly by8ml2U0/h2 (Assume that the number is large.)

Short Answer

Expert verified

Hence, the number of bound states is given bynmax8U0mL2h2 is proved

Step by step solution

01

Assumption

We assume that the wave function and energies correspond to the infinite well.

If,E<U0 then inside the well, the energy is totally kinetic and is given by,

h2k22m=n2π2h22mL2

02

Calculation

The highest bound state exists whenE=U0. i.e., the differenceEU00. For this state,

nmax2π2h22mL2U0nmax8U0mL2h2

Hence the number of bounded states nmax8U0mL2h2is proved.

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Most popular questions from this chapter

Outline a procedure for predicting how the quantum-mechanically allowed energies for a harmonic oscillator should depend on a quantum number. In essence, allowed kinetic energies are the particle-in-a box energies, except the length Lis replaced by the distance between classical tuning points. Expressed in terms of E. Apply this procedure to a potential energy of the form U(x) = - b/x where b is a constant. Assume that at the origin there is an infinitely high wall, making it one turning point, and determine the other numing point in terms of E. For the average potential energy, use its value at half way between the tuning points. Again in terms of E. Find and expression for the allowed energies in terms of m, b, and n. (Although three dimensional, the hydrogen atom potential energy is of this form. and the allowed energy levels depend on a quantum number exactly as this simple model predicts.)

A 2kg block oscillates with an amplitude of 10cm on a spring of force constant 120 N/m .

(a) In which quantum state is the block?

(b) The block has a slight electric charge and drops to a lower energy level by generating a photon. What is the minimum energy decrease possible, and what would be the corresponding fractional change in energy?

To show that the potential energy of finite well is U=h2(n1)28mL2

Consider the wave function that is a combination of two different infinite well stationary states the nth and the mth

ψx,t=12ψnxe-iEn/t+12ψme-iEm/t

  1. Show that the ψx,tis properly normalized.
  2. Show that the expectation value of the energy is the average of the two energies:E¯=12En+Em
  3. Show that the expectation value of the square of the energy is given by .
  4. Determine the uncertainty in the energy.

A comet in an extremely elliptical orbit about a star has, of course, a maximum orbit radius. By comparison, its minimum orbit radius may be nearly 0. Make plots of the potential energy and a plausible total energyversus radius on the same set of axes. Identify the classical turning points on your plot.

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