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You see a movie in which a shallow puddle of water coalesces into a perfectly cubical ice cube. How do you know the movie is being played backwards? Otherwise, what physical principle would be violated?

Short Answer

Expert verified

A violation of the second rule of thermodynamics would be very unlikely; the entropy of the Universe is lowered as a result of this process.

Step by step solution

01

Concept of the second law of thermodynamics

More and more energy is lost in the process of converting a source of heat into a new one.

A thermodynamic law is one of four that define the connection between thermal energy (heat), as well as other types of energy, and how they interact with matter.

02

Evaluating entropy

Entropy is the method for determining the level of order in a system if we increase the entropy of any system, the change in the thermodynamic system's state of disorder that occurs when heat or enthalpy is converted into work.

Thus, the second law of thermodynamics will be violated.

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Most popular questions from this chapter

A block of copper (one mole has a mass of 63.5 g ) at a temperature of 35ยฐis put in contact with a 100 gblock of aluminum (molar mass 27 g) at a temperature of20ยฐC. The blocks are inside an insulated enclosure, with little contact with the walls. At these temperatures, the high-temperature limit is valid for the specific heat. Calculate the final temperature of the two blocks. Do NOT look up the specific heats of aluminum and copper; you should be able to figure them out on your own.

You see a movie in which a shallow puddle of water coalesces into a perfectly cubical ice cube. How do you know the movie is being played backwards? Otherwise, what physical principle would be violated?

The interatomic spring stiffness for tungsten is determined from Youngโ€™s modulus measurements to be 90 N. The mass of one mole of tungsten is 0185 kg . If we model a block of tungsten as a collection of atomic โ€œoscillatorsโ€ (masses on springs), note that since each oscillator is attached to two โ€œsprings,โ€ and each โ€œspringโ€ is half the length of the interatomic bond, the effective interatomic spring stiffness for one of these oscillators is 4 times the calculated value given above.Use these precise values for the constants: hฬถ=1.05ร—10-34โ€„J.s(Planckโ€™s constant divided by 2ฯ€), Avogadroโ€™s number = 6.0221ร—1023โ€„molecule/mole, kB=1.3807ร—10-23โ€„J/K(the Boltzmann constant). (a) What is one quantum of energy for one of these atomic oscillators? (b) Figure 12.56 contains the number of ways to arrange a given number of quanta of energy in a particular block of tungsten. Fill in the blanks to complete the table, including calculating the temperature of the block. The energy E is measured from the ground state. Nothing goes in the shaded boxes. Be sure to give the temperature to the nearest 0.1 kelvin. (c) There are about 60 atoms in this object. What is the heat capacity on a per-atom basis? (Note that at high temperatures the heat capacity on a per-atom basis approaches the classical limit of 3kB = 4.2ร—10โˆ’23 J/K/atom.)

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