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A block of copper (one mole has a mass of 63.5 g ) at a temperature of 35°is put in contact with a 100 gblock of aluminum (molar mass 27 g) at a temperature of20°C. The blocks are inside an insulated enclosure, with little contact with the walls. At these temperatures, the high-temperature limit is valid for the specific heat. Calculate the final temperature of the two blocks. Do NOT look up the specific heats of aluminum and copper; you should be able to figure them out on your own.

Short Answer

Expert verified

The final temperature of two blocks is 37°C.

Step by step solution

01

Identification of given data

The given data can be listed below,

  • The mass of copper block is, mcu=50g.
  • The temperature of the block of copper is, Tcu=35°C=308K.
  • The mass of aluminium block is, mAI=100g.
  • The temperature of the block of aluminium is, TAI=20°C=293K.
02

Concept/Significance of specific heat capacity

The amount of heat absorbed by a unit mass of an item to produce a unit temperature rise is referred to as its specific heat capacity.

03

Determination of the final temperature of the two blocks

The specific heat of a metal is given by,

C=mMNA3kB

Here, m is the given mass of the atom and Mis the molar mass of the atom,NAis the Avogadro number whose value is 6.023×1023J/K.

The heat lost by copper block is equal to Aluminum is given by,

Qcu=QAImcuCcuTcu-T=mAICAITAI-T

The total temperature is given by,

T=mAICAITAI-mcuCcuTcumAICAI-mcuCcu=mAI2mAITAI+mcu2mcuTcuMAI2MAI+mcu2mcu

Substitute all the values in the above,

localid="1657860339433" T=Tcu/63.5+4TAI/274/27+1/63.5=308K/63.5+293K4/27+1/63.5=309.89K

The final temperature of two blocks is given by,

TF=309.89-273°C=37°C

Thus, the final temperature of two blocks is 37°C.

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Most popular questions from this chapter

A block of copper at a temperature of 50°C is placed in contact with a block of aluminium at a temperature of45°C in an insulated container. As a result of a transfer of 2500 J of energy from the copper to the aluminium, the final equilibrium temperature of the two blocks is 48°C. (a) What is the approximate change in the entropy of the aluminium block? (b) What is the approximate change in the entropy of the copper block? (c) What is the approximate change in the entropy of the Universe? (d) What is the change in the energy of the Universe?

The interatomic spring stiffness for tungsten is determined from Young’s modulus measurements to be 90 N. The mass of one mole of tungsten is 0185 kg . If we model a block of tungsten as a collection of atomic “oscillators” (masses on springs), note that since each oscillator is attached to two “springs,” and each “spring” is half the length of the interatomic bond, the effective interatomic spring stiffness for one of these oscillators is 4 times the calculated value given above.Use these precise values for the constants: h̶=1.05×10-34J.s(Planck’s constant divided by 2π), Avogadro’s number = 6.0221×1023molecule/mole, kB=1.3807×10-23J/K(the Boltzmann constant). (a) What is one quantum of energy for one of these atomic oscillators? (b) Figure 12.56 contains the number of ways to arrange a given number of quanta of energy in a particular block of tungsten. Fill in the blanks to complete the table, including calculating the temperature of the block. The energy E is measured from the ground state. Nothing goes in the shaded boxes. Be sure to give the temperature to the nearest 0.1 kelvin. (c) There are about 60 atoms in this object. What is the heat capacity on a per-atom basis? (Note that at high temperatures the heat capacity on a per-atom basis approaches the classical limit of 3kB = 4.2×10−23 J/K/atom.)

The reasoning developed for counting microstates applies to many other situations involving probability. For example, if you flip a coin 5 times, how many different sequences of 3 heads and 2 tails are possible? Answer: 10 different sequences, such as HTHHT or TTHHH. In contrast, how many different sequences of 5 heads and 0 tails are possible? Obviously only one, HHHHH, and our equation gives , using the standard definition thatis defined to equal 1.

If the coin is equally likely on a single throw to come up heads or tails, any specific sequence like HTHHT or HHHHH is equally likely. However, there is only one way to get HHHHH, while there are 10 ways to get 3 heads and 2 tails, so this is 10 times more probable than getting all heads.

Use the expression to calculate the number of ways to get 0 heads, 1 head, 2 heads, 3 heads, 4 heads, or 5 heads in a sequence of 5 coin tosses. Make a graph of the number of ways vs. the number of heads.

Explain why it is a disadvantage for some purposes that the specific heat of all materials decreases a low temperature.

In Chapter 4 you determined the stiffness of the interatomic “spring” (chemical bond) between atoms in a block of lead to be 5 N/m, based on the value of Young’s modulus for lead. Since in our model each atom is connected to two springs, each half the length of the interatomic bond, the effective “interatomic spring stiffness” for an oscillator is

4 × 5 N/m = 20 N/m. The mass of one mole of lead is 207 g (0.207 kg). What is the energy, in joules, of one quantum of energy for an atomic oscillator in a block of lead?

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