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What is the most important general difference between a system in steady state and a system in equilibrium?

Short Answer

Expert verified

When a system is at equilibrium, there is no net heat transmission. The term "steady state" describes a (possibly) open system in which there may be heat transmission but no change in the system's state.

Step by step solution

01

Significance of the steady state and equilibrium

A chemical reaction is said to be in a steady state when the concentration of an intermediate remains constant, as opposed to equilibrium, where the rates of the forward and backward reactions are equal.

02

Determination of the difference between a system in steady state and a system in equilibrium

In contrast to steady state, which is the stage of a chemical reaction when an intermediate's concentration is constant, equilibrium is a condition in which the rates of the forward and backward reactions are equal.

In contrast to steady state, when just some components are maintained constant, equilibrium maintains the concentrations of all components at a constant level.

When a system is at equilibrium, there is no net heat transmission. The term "steady state" describes a (possibly) open system in which there may be heat transmission but no change in the system's state.

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Most popular questions from this chapter

Question: Some students intended to run a light bulb off two batteries in series in the usual way, but they accidentally hooked up one of the batteries backwards, as shown in Figure 18.89 (the bulb is shown as a thin filament).

(a)Use+โ€™s and -โ€™s to show the approximate steady-state charge distribution along the wires and bulb.

(b)Draw vectors for the electric field at the indicated locations inside the connecting wires and bulb.

(c)Compare the brightness of the bulb in this circuit with the brightness the bulb would have had if one of the batteries hadnโ€™t been put in backwards.

(d)Try the experiment to check your analysis. Does the bulb glow about as you predicted?

In the few nanoseconds before the steady state is established in a circuit consisting of a battery, copper wires, and a single bulb, is the current the same everywhere in the circuit? Explain.

Suppose that a wire leads into another, thinner wire of the same material that has only a third the cross-sectional area. In the steady state, the number of electrons per second flowing through the thick wire must be equal to the number of electrons per second flowing through the thin wire. If the drift speedV1ยฏin the thick wire is 4ร—10-5ms, what is the drift speed Vยฏ2in the thinner wire?

In the circuit shown in Figure 18.87, bulbs 1 and 2 are identical in mechanical construction (the filaments have the same length and the same cross-sectional area), but the filaments are made of different metals. The electron mobility in the metal used in bulb 2 is three times as large as the electron mobility in the metal used in bulb 1, but both metals have the same number of mobile electrons per cubic meter. The two bulbs are connected in series to two batteries with thick copper wires (like your connecting wires).

(a)In bulb 1, the electron current is i1and the electric field is E1. In terms of these quantities, determine the corresponding quantities i2and E2for bulb 2, and explain your reasoning.

(b)When bulb 2 is replaced by a wire, the electron current through bulb 1 is i0and the electric field in bulb 1 is E0. How big is i1 in terms of i0? Explain your answer, including explicit mention of any approximations you must make. Do not use ohms or series-resistance equations in your explanation, unless you can show in detail how these concepts follow from the microscopic analysis introduced in this chapter.

(c)Explain why the electric field inside the thick copper wires is very small. Also explain why this very small electric field is the same in all of the copper wires, if they all have the same cross-sectional area.

(d)Figure 18.88 is a graph of the magnitude of the electric field at each location around the circuit when bulb 2 is replaced by a wire. Copy this graph and add to it, on the same scale, a graph of the magnitude of the electric field at each location around the circuit when both bulbs are in the circuit. The very small field in the copper wires has been shown much larger than it really is in order to give you room to show how that small field differs in the two circuits.

Criticize the statement below on theoretical and experimental grounds. Be specific and precise. Refer to your own experiments, or describe any new experiments you perform: โ€œA flashlight battery always puts out the same amount of current, no matter what is connected to it.โ€

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