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Find the allowed energies of the half harmonic oscillator

V(x)={(1/2)mω2x2,x>0,,x<0.
(This represents, for example, a spring that can be stretched, but not compressed.) Hint: This requires some careful thought, but very little actual calculation.

Short Answer

Expert verified

The allowed energies of the half harmonic oscillator can be written as:

E2q-1=2q-12ħω

Where,q=1, 2, 3 ...

Step by step solution

01

Splitting the partial differential equation over the intervals that V(x,t) is defined on

Schrodinger equation governs the time evolution of the wave function ψ(x,t)

ψt=-ħ22mψ2x2+vx,tψx,tψt=-ħ22mψ2x2+ψx,tψt=-ħ22mψ2x2+122x2ψx,tOnlyψx,t=0satisfiestheoneforx<0.Sincethewavefunctionmustbecontinuous,

localid="1658138151187" iħψt=-ħ22m2ψx2+12mω2ψx,t,ψ0,t=0ψx,0=ψx

02

Applying the method of reflection

Consider the corresponding problem over the whole line, using the odd extension of the initial condition. Doing so automatically satisfies the boundary condition at x=0. The solution for ψ-will then be the restriction fo ψ-tox>0to .

iħψ-t=-ħ22m2ψ-x2+12mω2x2ψ-x,t

ψ-x,0=ψ0oddx=ψ0x-ψ0-x,x>0x<0

Assuming a product solution of the form role="math" localid="1658135063605" ψ-x,t=ψxϕtand plugging it into the partial differential equation.

iħtψxϕt=-ħ2m2x2[ψxϕt]+12mω2x2[ψ(x)ϕ(t)]

role="math" localid="1658135677928" iħψxϕt=-ħ2mψ,,xϕt+12mω2x2ψ(x)ϕ(t)

iħϕ'tϕt=-ħ22mψ,,xψx12mω2x2

Hence,

iħϕ'tϕt=E-ħ22mψ''xψx+12mω2x2=E

The system was solved using the method of operator factorization, refer to problem 2.10

Hence, the energy can be find with the expression:

En=n+12ħω; where, n=0,1,2,...

03

General solution

According to the principle of superposition,

ψ-x,t=n=0Bnψnxe-iEnt/hψ-x,0=n=0Bnψnxψ-x,0=ψ0oddx

Multiplying by ψmxand Integrating both sides,

-n=0Bnψnxψmxdx=-ψ0oddxψmxdx

Since, the eigenstates are orthogonal, this integral on the left is zero for all nm. The infinite series consequently yields one term,n=mone.

Bn-ψnx2dx=-ψ0oddxψnxdx

Integral on the left side would be one, since the eigenstates are normalized.

So

Bn-ψ0oddxψnxdx

Eigenstate ψnx is an even function of x if n is even, which means thatis zero because the integrand is odd and the integration interval is symmetric. And if n is odd, then the eigenstate ψnxis an odd function, which means that the integrand is even.

Bn=20ψ0oddxψnxdxBn=20ψ0xψnxdx

Writing the general solution forψ-for the even and odd integers separately.

localid="1658138598630" ψ-x,t=q=0B2qψ2qxe-iE2qt/h+q=0B2q-1ψ2q-1xe-iE2q-1t/h

Hence, the solution to Schrödinger’s equation over the whole line,

localid="1658138720669" ψ-x,t=q=0B2q-1ψ2q-1xe-iE2q-1t/h-<x<

Now, take the restriction of ψ-to x > 0

ψ-x,t=q=0B2q-1ψ2q-1xe-iE2q-1t/h

Therefore, for the half harmonic oscillator,

ψx,t=0,x<0q=0B2q-1ψ2q-1xe-iE2q-1t/hx>0ψx,t=θq=0B2q-1ψ2q-1xe-iE2q-1t/h

Where, only the odd energies of the harmonic oscillator is allowed.

i.e.

E2q-12q-12ħω,where,q=1,2,3,... where,

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Most popular questions from this chapter

If two (or more) distinct44solutions to the (time-independent) Schrödinger equation have the same energy E . These states are said to be degenerate. For example, the free particle states are doubly degenerate-one solution representing motion to the right. And the other motion to the left. But we have never encountered normalizable degenerate solutions, and this is no accident. Prove the following theorem: In one dimension45 there are no degenerate bound states. Hint: Suppose there are two solutions, ψ1and ψ2with the same energy E. Multiply the Schrödinger equation for ψ1by ψ2and the Schrödinger equation for ψ2by ψ1and subtract, to show that ψ2dψ1/dx-ψ2dψ1/dxis a constant. Use the fact that for normalizable solutions ψ0at±to demonstrate that this constant is in fact zero.Conclude that ψ2s a multiple of ψ1and hence that the two solutions are not distinct.

The gaussian wave packet. A free particle has the initial wave function

Y(x,0)=Ae-ax2

whereAand are constants ( is real and positive).

(a) NormalizeY(x,0)

(b) Find Y(x,t). Hint: Integrals of the form

-+e-(ax2+bx)dx

Can be handled by “completing the square”: Lety=a[x+bl2a], and note that(ax2+bx)=y2-(b2l4a). Answer:

localid="1658297483210" Y(x,t)=(2aπ)1/4e-ex2l[1+(2ihatlm)]1+(2ihatlm)

(c) Find . Express your answer in terms of the quantity

localid="1658297497509" ω=a1+(2ihatlm)2

Sketchlocalid="1658124147567" |Y|2(as a function of x) at t=0, and again for some very large t. Qualitatively, what happens to |Y|2, as time goes on?

(d) Find <x>,<p>,<x2>,<p2>,σxand σP. Partial answer:localid="1658297458579" <p2>=ah2, but it may take some algebra to reduce it to this simple form.

(e) Does the uncertainty principle hold? At what time tdoes the system come

closest to the uncertainty limit?

This is a strictly qualitative problem-no calculations allowed! Consider the "double square well" potential (Figure 2.21). Suppose the depth V0and the width a are fixed, and large enough so that several bound states occur.

(a) Sketch the ground state wave function Ψ1and the first excited state localid="1658211858701" Ψ2(i) for the case b = 0 (ii) forbaand (iii) for ba

(b) Qualitatively, how do the corresponding energies(E1andE2)and vary, as b goes from 0 to ? Sketch E1(b)and E2(b)on the same graph.

(c) The double well is a very primitive one-dimensional model for the potential experienced by an electron in a diatomic molecule (the two wells represent the attractive force of the nuclei). If the nuclei are free to move, they will adopt the configuration of minimum energy. In view of your conclusions in (b), does the electron tend to draw the nuclei together, or push them apart? (Of course, there is also the internuclear repulsion to consider, but that's a separate problem.)

A particle in the infinite square well has as its initial wave function an even mixture of the first two stationary states:

Ψ(x,0)=A[ψ1(x)+ψ2(x)]

You can look up the series

116+136+156+=π6960

and

114+134+154+=π496

in math tables. under "Sums of Reciprocal Powers" or "Riemann Zeta Function."

(a) Normalize Ψ(x,0) . (That is, find A. This is very easy, if you exploit the orthonormality of ψ1and ψ2 Recall that, having ψnormalized at , t=0 , you can rest assured that is stays normalized—if you doubt this, check it explicitly after doing part(b).

(b) Find Ψ(x,t)and |Ψ(x,t)|2Express the latter as a sinusoidal function of time. To simplify the result, let ωπ22ma2

c)Compute x . Notice that it oscillates in time. What is the angular frequency of the oscillation? What is the amplitude of the oscillation?(If your amplitude is greater than a2 , go directly to jail.

(d) Compute p

(e) If you measured the energy of this particle, what values might you get, and what is the probability of getting each of them? Find the expectation value ofH.How does it compare with E1 and E2

Although the overall phase constant of the wave function is of no physical significance (it cancels out whenever you calculate a measurable quantity), the relative phase of the coefficients in Equation 2.17 does matter. For example, suppose we change the relative phase of ψ1andψ2in problem 2.5:ψ(x,0)=A[ψ1x+eiϕψ2x]Where ϕis some constant. Find ψ(x,t),|ψx,t|2, and (x), and compare your results with what you got before. Study the special cases ϕ=π2andϕ=π.

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