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Suppose you don’t assume Haa=Hbb=0

(a) Find ca(t)and cb(t) in first-order perturbation theory, for the case

.show that , to first order in .

(b) There is a nicer way to handle this problem. Let

.

Show that

where

So the equations for are identical in structure to Equation 11.17 (with an extra

(c) Use the method in part (b) to obtain in first-order
perturbation theory, and compare your answer to (a). Comment on any discrepancies.

Short Answer

Expert verified

ca2=1-ih0tHaat'dt'1-ih0tHaat'dt'=11-ih0tHaat'dt'2=1ca2=1-ih0tHaat'dt'1-ih0tHaat'dt'=0Soca2+cb2=1tofirstorder

(b) role="math" localid="1658488366910" da=-ihein0tHtdtcbHabeiω0tdb=ein0tHtdtihHbbcb+eih0tHtdtcb

(c) db=ein0tHtdtihHbbcb+eih0tHtdtcb

Step by step solution

01

(a) Finding  ca(t) and cb(t)

ca=-ihcaHaa+cbHabeiω0tcb=-ihcaHaa+cbHabeiω0t

cb=-ihcaHaa+cbHabe-iEb-Ebt/h

cb=-ihcaHaa+cbHabe-iEb-Ebt/h

Initial conditions:cat=1,cb0=0,

Zero order:.

First order:

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Most popular questions from this chapter

The first term in Equation 9.25 comes from the eiωt/2, and the second from e-iωt/2.. Thus dropping the first term is formally equivalent to writing H^=(V/2)e-iωt, which is to say,

cbl-ihvba0tcos(ωt')eiω0t'dt'=-iVba2h0tej(ω0+ω)t'+ej(ω0-ω)t'dt'=--iVba2hej(ω0+ω)t'-1ω0+ω+ej(ω0-ω)t'-1ω0-ω(9.25).Hba'=Vba2e-iωt,Hab'=Vab2eiωt(9.29).

(The latter is required to make the Hamiltonian matrix hermitian—or, if you prefer, to pick out the dominant term in the formula analogous to Equation 9.25 forca(t). ) Rabi noticed that if you make this so-called rotating wave approximation at the beginning of the calculation, Equation 9.13 can be solved exactly, with no need for perturbation theory, and no assumption about the strength of the field.

c.a=-ihHab'e-iω0tcb,c.b=-ihHba'e-iω0tca,

(a) Solve Equation 9.13 in the rotating wave approximation (Equation 9.29), for the usual initial conditions: ca(0)=1,cb(0)=0. Express your results (ca(t)andcb(t))in terms of the Rabi flopping frequency,

ωr=12(ω-ω0)2+(Vab/h)2 (9.30).

(b) Determine the transition probability,Pab(t), and show that it never exceeds 1. Confirm that.

ca(t)2+cb(t)2=1.

(c) Check that Pab(t)reduces to the perturbation theory result (Equation 9.28) when the perturbation is “small,” and state precisely what small means in this context, as a constraint on V.

Pab(t)=cb(t)2Vab2hsin2ω0-ωt/2ω0-ω2(9.28)

(d) At what time does the system first return to its initial state?


A hydrogen atom is placed in a (time-dependent) electric fieldE=E(t)k.calculateallfourmatrixelementsHij,oftheperturbationH,=eEzbetween the ground state (n = 1 ) the (quadruply degenerate) first excited states (n = 2 ) . Also showthatHii,=0 for all five states. Note: There is only one integral to be done here, if you exploit oddness with respect to z; only one of the n = 2 states is “accessible” from the ground state by a perturbation of this form, and therefore the system functions as a two-state configuration—assuming transitions to higher excited states can be ignored.

A particle of mass m is initially in the ground state of the (one-dimensional) infinite square well. At time t = 0 a “brick” is dropped into the well, so that the potential becomes

V(x)={V0,0xa/20,a/2<xa;,otherwise

where V0E1After a time T, the brick is removed, and the energy of the particle is measured. Find the probability (in first-order perturbation theory) that the result is nowE2 .

Solve Equation 9.13 to second order in perturbation theory, for the general case ca(0)=a,cb(0)=bca=-ihH'abe-0tcb,cb=-ihH'bae-0tca

(9.13).

Close the “loophole” in Equation 9.78 by showing that ifl'=l=0thenn'l'm'|r|nlm=0

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