Warning: foreach() argument must be of type array|object, bool given in /var/www/html/web/app/themes/studypress-core-theme/template-parts/header/mobile-offcanvas.php on line 20

Prove the commutation relation in Equation 9.74. Hint: First show that

[L2,z]=2ih(xLy-yLx-ihz)

Use this, and the fact that localid="1657963185161" r.L=r.(r×p)=0, to demonstrate that

[L2,[L2,z]]=2h2(zL2+L2z)

The generalization from z to r is trivial.

Short Answer

Expert verified

The communication relation in Equation 9.74 is[L2,[L2,z]]=2h2(zL2+L2z)

Step by step solution

01

Definition of commutation relation

Fundamental quantum mechanical relationships that link successive operations on the wave function or state vector of two operators (L1 and L2) in opposing orders, i.e., L1 L2 and L2 L1. The operators' algebra is defined by the commutation relations.

02

Proving the commutation relation in Equation 9.74.

[L2,z]=[Lx2,z]+[Ly2,z]+[Lz2,z]=Lx[Lx,z]+[Lx,z]Lx+Ly[Ly,z]+[Ly,z]Ly+Lz[Lz,z]+[Lz,z]Lz.

But{[Lx,z]=[ypzzpy,z]=[ypz,z][zpy,z]=y[pz,z]=iy[Ly,z]=[zpxxpz,z]=[zpx,z][xpz,z]=x[pz,z]=ix[Lz,z]=[xpyypx,z]=[xpy,z][ypx,z]=0

So:   [L2,z]=Lx(iy)+(iy)Lx+Ly(ix)+(ix)Ly=i(LxyyLx+Lyx+xLy).

But{Lxy=LxyyLx+yLx=[Lx,y]+yLx=iz+yLxLyx=LyxxLy+xLy=[Ly,x]+xLy=iz+xLy

So:[L2,z]=i(2xLyiz2yLxiz)[L2,z]=2i(xLyyLxiz)[L2,[L2,z]]=2i{[L2,xLy][L2,yLx]i[L2,z]}=2i{[L2,x]Ly+x[L2,Ly][L2,y]Lxy[L2,Lx]i(L2zzL2)}[L2,Ly]=[L2,Lx]=0

so,

[L2,Lx]=0,   [L2,Ly]=0,   [L2,Lz]=0(4.102).

[L2,[L2,z]]=2i{2i(yLzzLyix)Ly2i(zLxxLziy)Lxi(L2zzL2)}[L2,[L2,z]]=2i,or[L2,[L2,z]]=22(2yLzLy2zLy22zLx22z(Lx2+Ly2+Lz2)+2zLz22ixLy+2xLzLx+2iyLxL2z+z

=22(2yLzLy2ixLy+2xLzLx+2iyLx+2zLz22zL2L2z+zL2)=22(zL2+L2z)42[(yLzix)LzyLy+(xLz+iy)LzxLx+zLzLz]=22(zL2+L2z)42(LzyLy+LzxLx+LzzLz)Lz(rL)=0=22(zL2+L2z)

Unlock Step-by-Step Solutions & Ace Your Exams!

  • Full Textbook Solutions

    Get detailed explanations and key concepts

  • Unlimited Al creation

    Al flashcards, explanations, exams and more...

  • Ads-free access

    To over 500 millions flashcards

  • Money-back guarantee

    We refund you if you fail your exam.

Over 30 million students worldwide already upgrade their learning with Vaia!

One App. One Place for Learning.

All the tools & learning materials you need for study success - in one app.

Get started for free

Most popular questions from this chapter

We have encountered stimulated emission, (stimulated) absorption, and spontaneous emission. How come there is no such thing as spontaneous absorption?

As a mechanism for downward transitions, spontaneous emission competes with thermally stimulated emission (stimulated emission for which blackbody radiation is the source). Show that at room temperature (T = 300 K) thermal stimulation dominates for frequencies well below 5×1012Hz , whereas spontaneous emission dominates for frequencies well above . Which mechanism dominates for visible light?

Magnetic resonance. A spin-1/2 particle with gyromagnetic ratio γ at rest in a static magnetic fieldB0k^ precesses at the Larmor frequencyω0=γB0 (Example 4.3). Now we turn on a small transverse radiofrequency (rf) field,Brf[cos(ωt)ı^sin(ωt)j^]$, so that the total field is

role="math" localid="1659004119542" B=Brfcos(ωt)ı^Brfsin(ωt)j^+B0k^

(a) Construct the 2×2Hamiltonian matrix (Equation 4.158) for this system.

(b) If χ(t)=(a(t)b(t))is the spin state at time t, show that

a˙=i2(Ωeiωtb+ω0a):   b˙=i2(Ωeiωtaω0b)

where ΩγBrfis related to the strength of the rf field.

(c) Check that the general solution fora(t) andb(t) in terms of their initial valuesa0 andb0 is

role="math" localid="1659004637631" a(t)={a0cos(ω't/2)+iω'[a0(ω0ω)+b0Ω]sin(ω't/2)}eiωt/2b(t)={b0cos(ω't/2)+iω'[b0(ωω0)+a0Ω]sin(ω't/2)}eiωt/2

Where

ω'(ωω0)2+Ω2

(d) If the particle starts out with spin up (i.e. a0=1,b0=0,), find the probability of a transition to spin down, as a function of time. Answer:P(t)={Ω2/[(ωω0)2+Ω2]}sin2(ω't/2)

(e) Sketch the resonance curve,

role="math" localid="1659004767993" P(ω)=Ω2(ωω0)2+Ω2,

as a function of the driving frequencyω (for fixed ω0andΩ ). Note that the maximum occurs atω=ω0 Find the "full width at half maximum,"Δω

(f) Since ω0=γB0we can use the experimentally observed resonance to determine the magnetic dipole moment of the particle. In a nuclear magnetic resonance (nmr) experiment the factor of the proton is to be measured, using a static field of 10,000 gauss and an rf field of amplitude gauss. What will the resonant frequency be? (See Section for the magnetic moment of the proton.) Find the width of the resonance curve. (Give your answers in Hz.)

The first term in Equation 9.25 comes from the eiωt/2, and the second from e-iωt/2.. Thus dropping the first term is formally equivalent to writing H^=(V/2)e-iωt, which is to say,

cbl-ihvba0tcos(ωt')eiω0t'dt'=-iVba2h0tej(ω0+ω)t'+ej(ω0-ω)t'dt'=--iVba2hej(ω0+ω)t'-1ω0+ω+ej(ω0-ω)t'-1ω0-ω(9.25).Hba'=Vba2e-iωt,Hab'=Vab2eiωt(9.29).

(The latter is required to make the Hamiltonian matrix hermitian—or, if you prefer, to pick out the dominant term in the formula analogous to Equation 9.25 forca(t). ) Rabi noticed that if you make this so-called rotating wave approximation at the beginning of the calculation, Equation 9.13 can be solved exactly, with no need for perturbation theory, and no assumption about the strength of the field.

c.a=-ihHab'e-iω0tcb,c.b=-ihHba'e-iω0tca,

(a) Solve Equation 9.13 in the rotating wave approximation (Equation 9.29), for the usual initial conditions: ca(0)=1,cb(0)=0. Express your results (ca(t)andcb(t))in terms of the Rabi flopping frequency,

ωr=12(ω-ω0)2+(Vab/h)2 (9.30).

(b) Determine the transition probability,Pab(t), and show that it never exceeds 1. Confirm that.

ca(t)2+cb(t)2=1.

(c) Check that Pab(t)reduces to the perturbation theory result (Equation 9.28) when the perturbation is “small,” and state precisely what small means in this context, as a constraint on V.

Pab(t)=cb(t)2Vab2hsin2ω0-ωt/2ω0-ω2(9.28)

(d) At what time does the system first return to its initial state?


A hydrogen atom is placed in a (time-dependent) electric fieldE=E(t)k.calculateallfourmatrixelementsHij,oftheperturbationH,=eEzbetween the ground state (n = 1 ) the (quadruply degenerate) first excited states (n = 2 ) . Also showthatHii,=0 for all five states. Note: There is only one integral to be done here, if you exploit oddness with respect to z; only one of the n = 2 states is “accessible” from the ground state by a perturbation of this form, and therefore the system functions as a two-state configuration—assuming transitions to higher excited states can be ignored.

See all solutions

Recommended explanations on Physics Textbooks

View all explanations

What do you think about this solution?

We value your feedback to improve our textbook solutions.

Study anywhere. Anytime. Across all devices.

Sign-up for free