Chapter 8: Q7P (page 334)
Use the WKB approximation to find the allowed energies of the harmonic oscillator.
Short Answer
The allowed energies of the harmonic oscillator are
Chapter 8: Q7P (page 334)
Use the WKB approximation to find the allowed energies of the harmonic oscillator.
The allowed energies of the harmonic oscillator are
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Get started for freeConsider the case of a symmetrical double well, such as the one pictured in Figure. We are interested in Figure 8.13bound states with E<V(0) .
(a) Write down the WKB wave functions in regions (i) , (ii) , and (iii) . Impose the appropriate connection formulas at and (this has already been done, in Equation , for ; you will have to work out for yourself), to show that
FIGURE 8.13: Symmetrical double well; Problem 8.15.
Where
.
(b) Because v(x) is symmetric, we need only consider even and odd (-)wave functions. In the former case , and in the latter case . Show that this leads to the following quantization condition:
.
Where
Equation 8.59determines the (approximate) allowed energies (note that Ecomes into 1 and , so and are both functions of E ).
(c) We are particularly interested in a high and/or broad central barrier, in which case is large, and is huge. Equation 8.59 then tells us thatA must be very close to a half-integer multiple of . With this in mind, write localid="1658823154085" . where localid="1658823172105" , and show that the quantization condition becomes
localid="1658823190448" .
(d) Suppose each well is a parabola: 16
localid="1658823244259" .
Sketch this potential, find (Equation 8.58 ), and show that
localid="1658823297094"
Comment: If the central barrier were impenetrable localid="1658823318311" , we would simply have two detached harmonic oscillators, and the energies, localid="1658823339386" , would be doubly degenerate, since the particle could be in the left well or in the right one. When the barrier becomes finite (putting the two wells into "communication"), the degeneracy is lifted. The even (localid="1658823360600" ) states have slightly lower energy, and the odd ones have slightly higher energy.
(e) Suppose the particle starts out in the right well-or, more precisely, in a state of the form
localid="1658823391675"
which, assuming the phases are picked in the "natural" way, will be concentrated in the right well. Show that it oscillates back and forth between the wells, with a period
localid="1658823416179"
(f) Calculate , for the specific potential in part (d), and show that for , localid="1658823448873" .
Consider the quantum mechanical analog to the classical problem of a ball (mass m) bouncing elastically on the floor.
(a) What is the potential energy, as a function of height x above the floor? (For negative x, the potential is infinite x - the ball can't get there at all.)
(b) Solve the Schrödinger equation for this potential, expressing your answer in terms of the appropriate Airy function (note that Bi(z) blows up for large z, and must therefore be rejected). Don’t bother to normalize .
(c) Using and , find the first four allowed energies, in joules, correct to three significant digits. Hint: See Milton Abramowitz and Irene A. Stegun, Handbook of Mathematical Functions, Dover, New York (1970), page 478; the notation is defined on page 450.
(d) What is the ground state energy, in ,eV of an electron in this gravitational field? How high off the ground is this electron, on the average? Hint: Use the virial theorem to determine .
Derive the connection formulas at a downward-sloping turning point, and confirm equation8.50.
Use the WKB approximation in the form
to estimate the bound state energies for hydrogen. Don't forget the centrifugal term in the effective potential (Equation ). The following integral may help:
Note that you recover the Bohr levels when
Analyze the bouncing ball (Problem 8.5) using the WKB approximation.
(a) Find the allowed energies, , in terms of , and .
(b) Now put in the particular values given in Problem8.5 (c), and compare the WKB approximation to the first four energies with the "exact" results.
(c) About how large would the quantum number n have to be to give the ball an average height of, say, 1 meter above the ground?
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