Chapter 7: Q8P (page 308)
Evaluate and (Equations and ). Check your answers against Equations and .
Short Answer
Equations and matches the two integrals, and the results are the same.
Chapter 7: Q8P (page 308)
Evaluate and (Equations and ). Check your answers against Equations and .
Equations and matches the two integrals, and the results are the same.
All the tools & learning materials you need for study success - in one app.
Get started for free(a) Prove the following corollary to the variational principle: If then where is the energy of the first excited state. Comment: If we can find a trial function that is orthogonal to the exact ground state, we can get an upper bound on the first excited state. In general, it's difficult to be sure that is orthogonal to since (presumably) we don't know the latter. However, if the potential is an even function of x, then the ground state is likewise even, and hence any odd trial function will automatically meet the condition for the corollary.
(b) Find the best bound on the first excited state of the one-dimensional harmonic oscillator using the trial function
Find the best bound on for the one-dimensional harmonic oscillator using a trial wave function of the form role="math" localid="1656044636654" where A is determined by normalization and b is an adjustable parameter.
Use a gaussian trial function (Equation 7.2) to obtain the lowest upper bound you can on the ground state energy of (a) the linear potential (b) the quartic potential:
InProblem 7.7we found that the trial wave function with shielding (Equation 7.27), which worked well for helium, is inadequate to confirm the existence of a bound state for the negative hydrogen ion.
(7.27)
Chandrasekhar used a trial wave function of the form
(7.62).
Where
(7.63)
In effect, he allowed two different shielding factors, suggesting that one electron is relatively close to the nucleus, and the other is farther out. (Because electrons are identical particles, the spatial wave function must be symmetries with respect to interchange. The spin state—which is irrelevant to the calculation—is evidently anti symmetric.) Show that by astute choice of the adjustable parameters and you can getless than -13.6.
Answer: :
Where.Chandrasekhar used
(Since this is larger than 1, the motivating interpretation as an effective nuclear charge cannot be sustained, but never mindit’s still an acceptable trial wave function) and.
Find the best bound on for the delta-function potential using a triangular trial function (Equation 7.10, only centered at the origin). This time a is an adjustable parameter.
What do you think about this solution?
We value your feedback to improve our textbook solutions.