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Evaluate Dand X(Equations and ). Check your answers against Equations 7.47and 7.48.

Short Answer

Expert verified

Equations 7.45and 7.46matches the two integrals, and the results are the same.

Step by step solution

01

Definition of integral

An integral is a number that is assigned to a function in order to explain displacement, area, volume, and other notions that occur when infinitesimal data is combined.

Integration is the term used to describe the process of locating integrals.

02

Evaluate  D and X

Calculate two integrals:

D=aψ0(r1)|1r2|ψ0(r1)X=aψ0(r1)|1r1|ψ0(r2)

whereψ0(r)=er/aπa3, andr1=r and r2=r2+R22rRcosθ

The first integral is,

D=1πa2er/a1r2er/ar2drsinθdθdφ=2a20r2e2r/adr0πsinθdθr2+R22rRcosθ

As,

u=r2+R22rRcosθdu=2rRsinθ

The limits will be

0(rR)2    π(r+R)2

D=1Ra20re2r/adr(rR)2(r+R)2duu=2Ra20re2r/a[r+R|rR|]dr=2Ra2[0Rre2r/a(r+RR+r)dr+Rre2r/a(r+Rr+R)dr]=2Ra2[20Rr2e2r/adr+2RRre2r/adr]

Further, evaluate and get,

D=4Ra2{a38[e2r/a(4R2a24Ra2)+2]+Ra24e2R/a(2Ra+1)}=4Ra2a24{a2e2R/a(4R2a24Ra2)+a+Re2R/a(2Ra+1)}=1R{2Re2R/aae2R/a+a+Re2R/a}=aRaRe2R/ae2R/aD=aR(1+aR)e2R/a

03

The Second integral

Now, the second integral,

X=1πa2er/a1rer2/ar2drsinθdθdφ=2a20rer/adr0πexp(r2+R22rRcosθa)sinθdθ

As,

u=r2+R22rRcosθdu=2rRsinθ

Thus, The limits will be 0(rR)2   π(r+R)2

Use this in the integral and get,

X=1Ra20er/adr(rR)2(r+R)2eu/adu=1Ra20er/a2a2[e|rR|/a(|rR|a+1)eR/aer/a(ra+Ra+1)]dr

04

Separate the integral, which containsthe absolute value

Now separate the integral, which contains the absolute value, into two parts:

X=2R{0er/ae|rR|/a(|rR|a+1)eR/a0e2r/a(ra+Ra+1)dr}=2R{0Rer/aeR/aer/a(Rara+1)dr+Rer/aeR/aer/a(Ra+ra+1)dreR/a0[rae2r/a+(Ra+1)e2r/a]dr}=2eR/aR{R2aR22a+R+e2R/aRe2r/a(Ra+ra+1)dr1aa24(Ra+1)a2}=2eR/aR{R22a+R+e2R/a[1aa4e2R/a(a+2R)+(1Ra)a2e2R/a]a4a2(Ra+1)}

Further evaluate as:

=2eR/aR{R22a+R+14(a+2R)+a2(1Ra)a4a2(Ra+1)}=2eR/aR(R22a+R2)X=eR/a(1+Ra)

Thus, after calculating the two integrals, it is found that both yield the same outcome as equations 7.45and 7.46.

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Most popular questions from this chapter

(a) Prove the following corollary to the variational principle: If ψψgs=0thenáHñEfe whereEfe is the energy of the first excited state. Comment: If we can find a trial function that is orthogonal to the exact ground state, we can get an upper bound on the first excited state. In general, it's difficult to be sure that is orthogonal toψgsi since (presumably) we don't know the latter. However, if the potentialV(x) is an even function of x, then the ground state is likewise even, and hence any odd trial function will automatically meet the condition for the corollary.

(b) Find the best bound on the first excited state of the one-dimensional harmonic oscillator using the trial functionψ(x)=Axe-bx2

Find the best bound on Egsfor the one-dimensional harmonic oscillator using a trial wave function of the form role="math" localid="1656044636654" ψ(x)=Ax2+b2.,where A is determined by normalization and b is an adjustable parameter.

Use a gaussian trial function (Equation 7.2) to obtain the lowest upper bound you can on the ground state energy of (a) the linear potential V(x)=α|x| (b) the quartic potential:V(x)=αx4

InProblem 7.7we found that the trial wave function with shielding (Equation 7.27), which worked well for helium, is inadequate to confirm the existence of a bound state for the negative hydrogen ion.

ψ1(r1,r2)z3πa3e-z(r1+r2)/a (7.27)

Chandrasekhar used a trial wave function of the form

ψ(r1,r2)A[ψ1(r1)ψ2(r2)+ψ2(r1)ψ1(r2)] (7.62).

Where

ψ1(r)z13πa3e-z1/a,ψ1(r)z23πa3e-z2/a,(7.63)

In effect, he allowed two different shielding factors, suggesting that one electron is relatively close to the nucleus, and the other is farther out. (Because electrons are identical particles, the spatial wave function must be symmetries with respect to interchange. The spin state—which is irrelevant to the calculation—is evidently anti symmetric.) Show that by astute choice of the adjustable parameters Z1and Z2you can get<H>less than -13.6.

Answer: :<H>=E1x6+y6(-x8+2x7+12x6y2-12x5y2-18x3y4+118xy6-12y8).

Wherexz1+z2.y2z1z2Chandrasekhar usedZ1=1.039

(Since this is larger than 1, the motivating interpretation as an effective nuclear charge cannot be sustained, but never mindit’s still an acceptable trial wave function) andZ2=0.283.

Find the best bound on Egsfor the delta-function potentialV(x)=-αδ(x), using a triangular trial function (Equation 7.10, only centered at the origin). This time a is an adjustable parameter.

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