In classical electrodynamics the force on a particle of charge q
moving with velocity through electric and magnetic fields E and B is given
by the Lorentz force law:
This force cannot be expressed as the gradient of a scalar potential energy
function, and therefore the Schrödinger equation in its original form (Equation 1.1)
cannot accommodate it. But in the more sophisticated form
there is no problem; the classical Hamiltonian iswhere A
is the vector potentialand is the scalar potential ,
so the Schrödinger
equation (making the canonical substitutionbecomes
(a) Show that
(b) As always (see Equation ) we identifywith. Show that
(c) In particular, if the fields and are uniform over the volume of the wave packet,
show thatso the expectation value of moves
according to the Lorentz force law, as we would expect from Ehrenfest's theorem.