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For the most general normalized spinor (Equation 4.139),

compute{Sx},{Sy},{Sz},{Sx2},{Sy2},and{Sx2}.checkthat{Sx2}+{Sy2}+{Sz2}={S2}.

X=(ab)=aX++bX(4.139).

Short Answer

Expert verified

By solving we find the above value to beSx2+Sy2+Sz2=h24.

Step by step solution

01

Calculating

ComputingSx,Sy,Sz,Sx2,Sy2andSz2

Sx=h2a*b*0110(-)ba=h2a*b*(-)bah2a*b+b*a=hReab*.

Sy=h2a*b*0-ii0ab=h2a*b*-ibia

=h2-ia*b+iab*=h2iab*-a*b=-hlmab*.

Sz=h2a*b*100-1ab=h2a*b*a-b=h2a*a-b*b=h2a2b2.

Sx2=h2401100110=h240110=h24

Sy2=h2401100110=h24

localid="1655968926137" Sz2=h2401100110=h24soSx2=Sy2=Sz2=h24

02

Checking that<Sx2>+<Sy2>+<Sz2>+<S2>.

Sx2+Sy2+Sz2=34h2=ss+1h2=12?12+1h2=34h2=S2

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Most popular questions from this chapter

Consider the three-dimensional harmonic oscillator, for which the potential is

V(r)=12mฯ‰2r2

(a) Show that separation of variables in cartesian coordinates turns this into three one-dimensional oscillators, and exploit your knowledge of the latter to determine the allowed energies. Answer:

En=(n+3/2)hฯ‰

(b) Determine the degeneracyofd(n)ofEn.

In Problem4.3 you showed that Y21(ฮธ,ฯ•)=-15/8ฯ€sinฮธcosฮธeiฯ•. Apply the raising operator to find localid="1656065252558" Y22(ฮธ,ฯ•). Use Equation 4.121to get the normalization.

Use equations 4.27 4.28 and 4.32 to construct Y00,Y21Check that they are normalized and orthogonal

Determine the commutator of S2withSZ(1)(whereSโ‰กS(1)+S(2)) Generalize your result to show that

[S2,S1]=2Ih(S1ร—S2)

Comment: Because Sz(1)does not commute with S2, we cannot hope to find states that are simultaneous eigenvectors of both. In order to form eigenstates ofS2weneed linear combinations of eigenstates ofSz(1). This is precisely what the Clebsch-Gordan coefficients (in Equation 4.185) do for us, On the other hand, it follows by obvious inference from Equation 4.187that the sumrole="math" localid="1655980965321" S(1)+S(2)does commute withdata-custom-editor="chemistry" S2, which is a special case of something we already knew (see Equation 4.103).

Use separation of variables in Cartesian coordinates to solve infinite cubical well

V(x,y,z)=0if x,y,z are all between 0 to a;

V(x,y,z)=โˆžOtherwise

a) Find the stationary states and the corresponding energies

b) Call the distinct energies E1,E2,E3,..in the order of increasing energy. Findlocalid="1658127758806" E1,E2,E3,E4,E5,E6determine their degeneracies (that is, the number of different states that share the same energy). Comment: In one dimension degenerate bound states do not occur but in three dimensions they are very common.

c) What is the degeneracy of E14 and why is this case interesting?

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