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In Problem4.3 you showed that Y21(θ,ϕ)=-15/8πsinθcosθeiϕ. Apply the raising operator to find localid="1656065252558" Y22(θ,ϕ). Use Equation 4.121to get the normalization.

Short Answer

Expert verified

The value ofY22θ,ϕis14152πheiϕsinθ2.

Step by step solution

01

Define Raising Operator

An operator that raises or lowers the eigenvalue of another operator (collectively called as ladder operators) is referred to as a raising or lowering operator.

02

Find the value of Y22(θ,ϕ)

In this step evaluate first the spherical harmonic is Y21θ,ϕ.

From problem 4.3, the value of Y21

Y21=-158ττsinθcosθeioL+=heiϕθ+icotθϕL+Y21=Y22

Now, determine the spherical harmonic Y22θ,ϕas follows,

localid="1658464225727" Y21=-158πheiϕeiϕ)(sinθcosθ)θ+icotθsinθcosθeiϕϕ=-158πheiϕeiϕ(cos2θ-sin2θ)+icotθsinθcosθ(ieiϕ)=-158πheiϕcos2θ-cos2θeiϕ=152πhe2iϕsin2θ=12152πh(e2iϕsinθ)2

Thus, the value ofY22θ,ϕislocalid="1658464244244" 12152πheiϕsin2θ2.

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Most popular questions from this chapter

Deduce the condition for minimum uncertainty inSx andSy(that is, equality in the expression role="math" localid="1658378301742" σSxσSy(ħ/2)|<Sz>|, for a particle of spin 1/2 in the generic state (Equation 4.139). Answer: With no loss of generality we can pick to be real; then the condition for minimum uncertainty is that bis either pure real or else pure imaginary.

What is the probability that an electron in the ground state of hydrogen will be found inside the nucleus?

  1. First calculate the exact answer, assuming the wave function is correct all the way down tor=0. Let b be the radius of the nucleus.
  2. Expand your result as a power series in the small numbera=2bla, and show that the lowest-order term is the cubic:P(4l3)(bla)3. This should be a suitable approximation, provided thatba(which it is).
  3. Alternatively, we might assume thatψ(r)is essentially constant over the (tiny) volume of the nucleus, so thatP(4l3)πb3lψ(0)l2.Check that you get the same answer this way.
  4. Useb10-15manda05×10-10mto get a numerical estimate forP. Roughly speaking, this represents the fraction of its time that the electron spends inside the nucleus:"

A hydrogenic atom consists of a single electron orbiting a nucleus with Z protons. (Z=1 would be hydrogen itself,Z=2is ionized helium ,Z=3is doubly ionized lithium, and so on.) Determine the Bohr energies En(Z), the binding energyE1(Z), the Bohr radiusa(Z), and the Rydberg constant R(Z)for a hydrogenic atom. (Express your answers as appropriate multiples of the hydrogen values.) Where in the electromagnetic spectrum would the Lyman series fall, for Z=2and Z=3? Hint: There’s nothing much to calculate here— in the potential (Equation 4.52) Ze2, so all you have to do is make the same substitution in all the final results.

V(r)=-e24πo0˙1r (4.52).

[Attempt this problem only if you are familiar with vector calculus.] Define the (three-dimensional) probability current by generalization of Problem 1.14:

J=ih2m(ψψ*-ψ*ψ)

(a) Show that satisfies the continuity equation .J=-t|ψ|2which expresses local conservation of probability. It follows (from the divergence theorem) that sJ.da=-ddtv|ψ|2d3rwhere Vis a (fixed) volume and is its boundary surface. In words: The flow of probability out through the surface is equal to the decrease in probability of finding the particle in the volume.

(b) FindJfor hydrogen in the staten=2,l=1,m=1 . Answer:

h64ma5re-r/asinθϕ^

(c) If we interpretmJas the flow of mass, the angular momentum is

L=m(r×J)d3r

Use this to calculate Lzfor the stateψ211, and comment on the result.

(a) Using Equation 4.88, work out the first four Laguerre polynomials.

(b) Using Equations 4.86, 4.87, and 4.88, find v(ρ), for the case n=5,I=2.

(c) Find v(ρ)again (for the case role="math" localid="1658315521558" n=5,I=2), but this time get it from the recursion formula (Equation 4.76).

Lq(x)=eqq!(ddx)q(e-x-x9)(4.88)v(ρ)=Ln-2l+1l-1(4.86)Lqp(x)(-1)pddxρLp+q(x)(4.87)cj+1=2(j+l+1-n)(j+1)(j+2l+2)cj(4.76)

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