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(a) What isL+Y1I? (No calculation allowed!)

(b) Use the result of (a), together with Equation 4.130 and the fact thatLzY1I=hIYII to determineYII(θ,ϕ) , up to a normalization constant.

(c) Determine the normalization constant by direct integration. Compare your final answer to what you got in Problem 4.5.

Short Answer

Expert verified

(a) The value of L+Y1Iis 0.

(b) The value of YII(θ,ϕ)is A sinθeiϕI.

(c) The normalization constant is 12I+1I!2I+1!π.

Step by step solution

01

Normalization constant

A normalizing constant guarantees that the probability of a probability density function is 1. The constant can appear in many forms, including scalar values, equations, and even functions.

As a result, there is not a "one size fits all" constant; instead, any probability distribution that does not sum to 1 will have its own normalization constant.

02

(a) Determination of the value of the expression

The operator L+ is the raising operator that is acting on the function YIm. It gives a result proportional to YIm+1but the maximum value of m is I . So, YIIis the top function.

Thus, the value of L+YII is 0.

03

(b) Determination of the value of YII(θ,f)  

Consider LzYII=hIYIIand use the definition of Lzto solve for YII.

localid="1658204848834" LzY1I(θ,ϕ)=hIY1I(θ,ϕ)-ihY1I(θ,ϕ)ϕ=hIY1I(θ,ϕ)Y1IY1I=iIϕY1I(θ,ϕ)=f(θ)eiIϕ

It can be observed that from part (a) localid="1658204942389" L+YII=0. So, substitute 0 for L+YIIin the above expression.

L+fθeiIϕ=0

Unravele the definition.

hefθθ.eiIϕ+icotθfθeiIϕϕ=0fθθ.eiIϕ+icotθfθileilϕ=0fθθ=lcotθfθ

Integrate both sides of the above equation.

fθfθdθ=IcotθdθInfθ=lInsinθ+kInfθ=lInAsinIθfθ=AsinI(θ)YIIθ,ϕ=AsinIθeilϕ

Here, A isanormalization constant.

Thus, the value of YIIθ,ϕis A sinθeiϕl.

04

Step 4: (c) Determination of normalization constant

To normalize the function 1=YIIθ,ϕ2sinθdθdϕis required.

Substitute in AsinθeiϕIfor YIIin the expression.

1=A202π0πsin2Iθsinθdθdϕ=2πA20πsin2Iθsinθdθ=2πA20πsin2I+1θdθ

Use integral table for solving the expression.

=4πA22.4.6...2l1.3.5...2l+1=4πA22.4.6...2l21.2.3.5...2l2l+1=4πA22ll22l+1!A=12I+1l!2l+1!π

Thus, the normalization constant is12I+1l!2l+1!π.12I+1l!2l+1!π.

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Most popular questions from this chapter

What is the probability that an electron in the ground state of hydrogen will be found inside the nucleus?

  1. First calculate the exact answer, assuming the wave function is correct all the way down tor=0. Let b be the radius of the nucleus.
  2. Expand your result as a power series in the small numbera=2bla, and show that the lowest-order term is the cubic:P(4l3)(bla)3. This should be a suitable approximation, provided thatba(which it is).
  3. Alternatively, we might assume thatψ(r)is essentially constant over the (tiny) volume of the nucleus, so thatP(4l3)πb3lψ(0)l2.Check that you get the same answer this way.
  4. Useb10-15manda05×10-10mto get a numerical estimate forP. Roughly speaking, this represents the fraction of its time that the electron spends inside the nucleus:"

(a) NormalizeR20 (Equation 4.82), and construct the functionψ200.

(b) NormalizeR21(Equation 4.83), and construct the function.

(a) From the definition (Equation 4.46), construct n1(x)andn2(x).

(b) Expand the sines and cosines to obtain approximate formulas forn1(x)androle="math" localid="1656329588644" n2(x), valid whenx1.. Confirm that they blow up at the origin.

[Attempt this problem only if you are familiar with vector calculus.] Define the (three-dimensional) probability current by generalization of Problem 1.14:

J=ih2m(ψψ*-ψ*ψ)

(a) Show that satisfies the continuity equation .J=-t|ψ|2which expresses local conservation of probability. It follows (from the divergence theorem) that sJ.da=-ddtv|ψ|2d3rwhere Vis a (fixed) volume and is its boundary surface. In words: The flow of probability out through the surface is equal to the decrease in probability of finding the particle in the volume.

(b) FindJfor hydrogen in the staten=2,l=1,m=1 . Answer:

h64ma5re-r/asinθϕ^

(c) If we interpretmJas the flow of mass, the angular momentum is

L=m(r×J)d3r

Use this to calculate Lzfor the stateψ211, and comment on the result.

a) Check that the spin matrices (Equations 4.145 and 4.147) obey the fundamental commutation relations for angular momentum, Equation 4.134.

Sz=h2(100-1)(4.145).Sx=h2(0110),sy=h2(0-ii0)(4.147).[Sx,Sy]=ihSz,[Sy,Sz]=ihSx,[Sz,Sx]=ihSy(4.134).(b)ShowthatthePaulispinmatrices(Equation4.148)satisfytheproductruleσx(0110),σy(0-ii0),σz(100-1)(4.148).σjσk=δjk+io'IjklσI,(4.153).

Wheretheindicesstandforx,y,orz,ando'jklistheLevi-Civitasymbol:+1ifjkl=123,231,or2=312;-1ifjkl=132,213,or321;otherwise.

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