Typically, the interaction potential depends only on the vectorbetween
the two particles. In that case the Schrodinger equation seperates, if we change variables from and(the center of mass).
(a)Show that
localid="1655976113066"
localid="1655976264171"
is the reduced mass of the system
(b) Show that the (time-independent) Schrödinger equation (5.7) becomes
(c) Separate the variables, letting Note that satisfies the
one-particle Schrödinger equation, with the total mass in place of m, potential zero, and energy while satisfies the one-particle Schrödinger equation with the reduced mass in place of m, potential V(r) , and energy localid="1655977092786" . The total energy is the sum: . What this tells us is that the center of mass moves like a free particle, and the relative motion (that is, the motion of particle 2 with respect to particle 1) is the same as if we had a single particle with the reduced mass, subject to the potential V. Exactly the same decomposition occurs in classical mechanics; it reduces the two-body problem to an equivalent one-body problem.