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Obtain equation 5.76 by induction. The combinatorial question is this: How many different ways you can put N identical balls into d baskets (never mind the subscriptfor this problem). You could stick all of them into the third basket, or all but one in the second basket and one in the fifth, or two in the first and three in the third and all the rest in the seventh, etc. Work it out explicitly for the casesN=1,N=2,N=3andN=4; by that stage you should be able to deduce the general formula.

Short Answer

Expert verified

The derived expression isf(N,d)=d+N-1!N!(d-1)!

Step by step solution

01

Define the Schrodinger equation

  • A differential equation that uses the wave-like characteristics of particles in a field to describe matter in terms of quantum mechanics. The probability density of a particle in space and time is relevant to the response.
  • The time-dependent Schrödinger equation is represented as

ihddt|ψ(t)>=H^|ψ(t)>

02

Analyze the equation

For N=1, balls can be put any of d baskets

So, there are d ways.

For N=2

1) We can put two balls in any of d baskets waysdways

2) We can put one ball in one of baskets, and the other in one of the remaining d-1

Because balls are identical, we must divide by2d(d-1)2

Total number:

d+d(d-1)2=d(d+1)2ways

1) We can put three balls in one ofbasketsd.

2) We can put one in one basket, and two in one of remaining d-1d(d-1)

3) We can put one ball in one of baskets, second in one of the remaining d-1, and third in one of remaining d-2.

Because balls are identical, we must divide by 3!d(d-1)(d+2)3!

Total number:

d+d(d-1)+d(d-1)(d-2)6=d2+d(d2-3d+2)6=d(d+1)(d+2)6

For N=4

1) We can put four balls in one of d baskets d.

2) We can put one in one basket, and three in one of remainingd-1d(d-1)

3) We can put two balls in one basket, and two in one of the remainingd-1d(d-1)2

4) We can put two balls in one basket, one in one of the remainingd-1, and last one in one of the remainingd-2d(d-1)(d-2)2

5) All four balls are in different baskets.d(d-1)(d-2)(d-3)4!

Total number of balls

d+d(d-1)2+d(d-1)(d-2)6+d(d-1)(d-2)(d-3)24=d(d+1)(d+2)(d+3)24=d2+d(d-1)22+d(d-1)(d-2)(d-3)24=d2424d+12(d-1)2+(d-1)(d-2)(d-3)=d2412d2+12+d3-5d2+6d-d2+5d-6=d24(d3+6d2+11d+6)=d(d+1)(d+2)(d+3)24 So, for number of balls in dthebasket is

localid="1658227901414" f(N,d)=d(d+1)(d+2)+..............(d+N-1)N!f(N,d)=(d+N-1)!N!(d-1)!f(N,d)=(d+N)!(n+1)!(d-1)!

03

Deriving the equation using induction

By using induction

N=0f(0,d)=1

We assume that following expression is valid:f(N,d)=(d+N-1)!N!(d-1)!.

We check forN+1:

d+NN+1=d+N-1N+d+N-1N+1=(d+N-1)!N!(d-1)!+(d+N-1)!(N+1)!(d-2)=(d+N-1)!N!(d-1)(d-2)!+(d+N-1)!(N+1)N!(d-2)!=(d+N-1)!N!(d-2)!1d-1+1N+1=(d+N-1)!N!(d-2)!N+d(d+1)(N+1)=(d+N)!(N+1)!(d-1)!

Therefore the derived expression is(N,d)=(d+N-1)!N!(d-1)! .

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Most popular questions from this chapter

In view ofProblem 5.1, we can correct for the motion of the nucleus in hydrogen by simply replacing the electron mass with the reduced mass.

(a) Find (to two significant digits) the percent error in the binding energy of hydrogen (Equation 4.77) introduced by our use of m instead of μ.

E1=-m2h2e24π'2=-13.6eV(4.77).

(b) Find the separation in wavelength between the red Balmer lines n=3n=2for hydrogen and deuterium (whose nucleus contains a neutron as well as the proton).

(c) Find the binding energy of positronium (in which the proton is replaced by a positron—positrons have the same mass as electrons, but opposite charge).

(d) Suppose you wanted to confirm the existence of muonic hydrogen, in which the electron is replaced by a muon (same charge, but 206.77 times heavier). Where (i.e. at what wavelength) would you look for the “Lyman-α” line n=2n=1?.

Certain cold stars (called white dwarfs) are stabilized against gravitational collapse by the degeneracy pressure of their electrons (Equation 5.57). Assuming constant density, the radius R of such an object can be calculated as follows:

P=23EtotV=23h2kF510π2m=(3π2)2/3h25mp5/3(5.57)

(a) Write the total electron energy (Equation 5.56) in terms of the radius, the number of nucleons (protons and neutrons) N, the number of electrons per nucleon d, and the mass of the electron m. Beware: In this problem we are recycling the letters N and d for a slightly different purpose than in the text.

Etot=h2V2π2m0kFK4dk=h2kF5V10π2m=h2(3π2Nd)5/310π2mV-2/3(5.56)

(b) Look up, or calculate, the gravitational energy of a uniformly dense sphere. Express your answer in terms of G (the constant of universal gravitation), R, N, and M (the mass of a nucleon). Note that the gravitational energy is negative.

(c) Find the radius for which the total energy, (a) plus (b), is a minimum.

R=(9π4)2/3h2d5/3GmM2N1/3

(Note that the radius decreases as the total mass increases!) Put in the actual numbers, for everything except , using d=1/2 (actually, decreases a bit as the atomic number increases, but this is close enough for our purposes). Answer:

(d) Determine the radius, in kilometers, of a white dwarf with the mass of the sun.

(e) Determine the Fermi energy, in electron volts, for the white dwarf in (d), and compare it with the rest energy of an electron. Note that this system is getting dangerously relativistic (seeProblem 5.36).

(a) Write down the Hamiltonian for two noninteracting identical particles in the infinite square well. Verify that the fermion ground state given in Example 5.1 is an eigenfunction of H, with the appropriate eigenvalue.

(b) Find the next two excited states (beyond the ones in Example 5.1) - wave functions and energies - for each of the three cases (distinguishable, identical bosons, identical fermions).

Typically, the interaction potential depends only on the vectorr=r1-r2between

the two particles. In that case the Schrodinger equation seperates, if we change variables from r1,r2andR=(m1r1+m2r2)I(m1+m2)(the center of mass).

(a)Show that

localid="1655976113066" r1=R+(μ/m1)r,r2=R-(μ/m)r,and1=(μ/m)R+r,2=(μ/m1)R-r,where

localid="1655976264171" μ=m1m2m1+m2(5.15).

is the reduced mass of the system

(b) Show that the (time-independent) Schrödinger equation (5.7) becomes

-h22m112ψ-h22m222ψ+=-h22(m1+m2)R2ψ-h22μr2ψ+V(r)ψ=.(5.7).

(c) Separate the variables, letting ψ(R,r)=ψR(R)ψr(r)Note that ψRsatisfies the

one-particle Schrödinger equation, with the total mass (m1+m2)in place of m, potential zero, and energy ERwhile ψrsatisfies the one-particle Schrödinger equation with the reduced mass in place of m, potential V(r) , and energy localid="1655977092786" Er. The total energy is the sum: E=ER+Er. What this tells us is that the center of mass moves like a free particle, and the relative motion (that is, the motion of particle 2 with respect to particle 1) is the same as if we had a single particle with the reduced mass, subject to the potential V. Exactly the same decomposition occurs in classical mechanics; it reduces the two-body problem to an equivalent one-body problem.

Show that most of the energies determined by Equation 5.64are doubly degenerate. What are the exceptional cases? Hint: Try it for N=1,2,3,4.... , to see how it goes. What are the possible values of cos(ka)in each case?

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