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Write down the relations for steady one-dimensional heat conduction and mass diffusion through a plane wall, and identify the quantities in the two equations that correspond to each other.

Short Answer

Expert verified
Answer: The parallel quantities in both equations are: 1. Heat flux (q) in Fourier's law corresponds to mass flux (J) in Fick's law. 2. Temperature gradient (dT/dx) in Fourier's law corresponds to concentration gradient (dC/dx) in Fick's law. 3. Thermal conductivity (k) in Fourier's law corresponds to diffusivity (D) in Fick's law.

Step by step solution

01

Heat Conduction Relation (Fourier's Law)

For one-dimensional steady heat conduction through a plane wall, we use Fourier's law, which is the basic governing equation of heat conduction. The equation is given as: \begin{equation} q = -k\dfrac{dT}{dx} \end{equation} where, \(q\): Heat flux (W/m²), \(k\): Thermal conductivity of the material (W/mK), \(\frac{dT}{dx}\): Temperature gradient in the direction of heat flow (K/m).
02

Mass Diffusion Relation (Fick's Law)

For one-dimensional steady mass diffusion through a plane wall, we use Fick's first law, which is the basic relation for mass diffusion. The equation is given as: \begin{equation} J = -D\dfrac{dC}{dx} \end{equation} where, \(J\): Mass flux (kg/m²s), \(D\): Diffusivity of the material (m²/s), \(\frac{dC}{dx}\): Concentration gradient in the direction of mass flow (kg/m³).
03

Identify Corresponding Quantities

Now we will compare the two equations and identify the parallel quantities in both relations: 1. Heat flux \(q\) and mass flux \(J\) - these parameters represent the flow rate of heat and mass, respectively. 2. Temperature gradient \(\frac{dT}{dx}\) and concentration gradient \(\frac{dC}{dx}\) - these parameters relate to the driving forces for heat flow and mass flow in the system. 3. Thermal conductivity \(k\) and diffusivity \(D\) - these parameters define the capacity of the medium to conduct heat and allow mass diffusion, respectively. In conclusion, Fourier's law and Fick's law both describe the flow of heat and mass through a plane wall under steady-state conditions. The key quantities in both equations that correspond to each other are heat flux (q) and mass flux (J), temperature (T) gradient and concentration (C) gradient, and thermal conductivity (k) and diffusivity (D).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Fourier's Law
Fourier's Law is a fundamental principle used to describe heat conduction. In simple terms, heat conduction is the process by which heat energy is transferred through a material without any movement of the medium itself. The law is expressed mathematically as:\[ q = -k \frac{dT}{dx} \]- **Heat Flux \(q\):** This represents the flow of heat per unit area through a material, commonly measured in watts per square meter \((W/m^2)\).
- **Thermal Conductivity \(k\):** This property measures how well a material can conduct heat. The higher the thermal conductivity, the better the material conducts heat.
- **Temperature Gradient \(\frac{dT}{dx}\):** This is the change in temperature over a distance, acting as the driving force for the heat flow. The negative sign in the equation indicates that heat flows from hot to cold regions.
Fourier's Law applies to situations where there is no change in heat energy storage, meaning the amount of heat entering and leaving the body remains constant over time. This condition is known as the steady state.
Fick's Law
Fick's Law describes the diffusion process, where particles move from an area of high concentration to an area of low concentration. This movement is essential in many natural and industrial processes, such as the diffusion of gases or the distribution of nutrients in cells. The law can be expressed as:\[ J = -D \frac{dC}{dx} \]- **Mass Flux \(J\):** This is the amount of mass flowing through a unit area per unit time, typically measured in kilograms per square meter per second \((kg/m^2s)\).
- **Diffusivity \(D\):** This is a measure of how easily particles can spread through the medium. Higher diffusivity indicates more efficient diffusion.
- **Concentration Gradient \(\frac{dC}{dx}\):** The rate of change in concentration acts as the driving force for diffusion, similar to temperature in heat conduction. The negative sign suggests that diffusion occurs from higher to lower concentration areas.
Fick's Law is analogous to Fourier's Law, with both describing steady transfer processes driven by gradients. This relationship helps to understand how energy and mass transfer are fundamentally similar.
Conduction and Diffusion
Conduction and diffusion are two fundamental processes in heat and mass transfer, often described by Fourier's and Fick's laws, respectively. While both involve the transfer of entities – energy in conduction and particles in diffusion – they operate under similar principles where the flow is driven by gradients.### Key Parallels Between Conduction and Diffusion:
  • **Flux Representation:** Both processes describe the flow rate, with heat flux \(q\) in conduction and mass flux \(J\) in diffusion. These are measures of how much energy or mass crosses a boundary over time.
  • **Gradient as a Driving Force:** In conduction, the temperature gradient \(\frac{dT}{dx}\) drives the heat flow, while in diffusion, the concentration gradient \(\frac{dC}{dx}\) drives particle movement. Gradients indicate the direction and intensity of flow.
  • **Material Properties:** Thermal conductivity \(k\) in conduction and diffusivity \(D\) in diffusion define how readily the medium can transfer heat or mass. These properties are crucial in determining the efficiency of the conduction and diffusion processes.
By recognizing these parallels, students can better grasp how similar principles govern distinct processes, making it easier to apply these concepts to diverse scenarios in science and engineering. Understanding these concepts is crucial for solving practical problems in fields like mechanical engineering, chemical processes, and environmental studies.

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Most popular questions from this chapter

Air at \(52^{\circ} \mathrm{C}, 101.3 \mathrm{kPa}\), and 10 percent relative humidity enters a 5 -cm-diameter tube with an average velocity of \(5 \mathrm{~m} / \mathrm{s}\). The tube inner surface is wetted uniformly with water, whose vapor pressure at \(52^{\circ} \mathrm{C}\) is \(13.6 \mathrm{kPa}\). While the temperature and pressure of air remain constant, the partial pressure of vapor in the outlet air is increased to \(10 \mathrm{kPa}\). Detemine \((a)\) the average mass transfer coefficient in \(\mathrm{m} / \mathrm{s},(b)\) the log-mean driving force for mass transfer in molar concentration units, \((c)\) the water evaporation rate in \(\mathrm{kg} / \mathrm{h}\), and \((d)\) the length of the tube.

A recent attempt to circumnavigate the world in a balloon used a helium-filled balloon whose volume was \(7240 \mathrm{~m}^{3}\) and surface area was \(1800 \mathrm{~m}^{2}\). The skin of this balloon is \(2 \mathrm{~mm}\) thick and is made of a material whose helium diffusion coefficient is \(1 \times 10^{-9} \mathrm{~m}^{2} / \mathrm{s}\). The molar concentration of the helium at the inner surface of the balloon skin is \(0.2 \mathrm{kmol} / \mathrm{m}^{3}\) and the molar concentration at the outer surface is extremely small. The rate at which helium is lost from this balloon is (a) \(0.26 \mathrm{~kg} / \mathrm{h}\) (b) \(1.5 \mathrm{~kg} / \mathrm{h}\) (c) \(2.6 \mathrm{~kg} / \mathrm{h}\) (d) \(3.8 \mathrm{~kg} / \mathrm{h}\) (e) \(5.2 \mathrm{~kg} / \mathrm{h}\)

Heat convection is expressed by Newton's law of cooling as \(\dot{Q}=h A_{s}\left(T_{s}-T_{\infty}\right)\). Express mass convection in an analogous manner on a mass basis, and identify all the quantities in the expression and state their units.

Explain how vapor pressure of the ambient air is determined when the temperature, total pressure, and relative humidity of the air are given.

Benzene \((M=78.11 \mathrm{~kg} / \mathrm{kmol})\) is a carcinogen, and exposure to benzene increases the risk of cancer and other illnesses in humans. A truck transporting liquid benzene was involved in an accident that spilled the liquid on a flat highway. The liquid benzene forms a pool of approximately \(10 \mathrm{~m}\) in diameter on the highway. In this particular windy day at \(25^{\circ} \mathrm{C}\) and \(1 \mathrm{~atm}\) with an average wind velocity of \(10 \mathrm{~m} / \mathrm{s}\), the liquid benzene surface is experiencing mass transfer to air by convection. Nearby at the downstream of the wind is a residential area that could be affected by the benzene vapor. Local health officials have assessed that if the benzene level in the air reaches \(500 \mathrm{~kg}\) within the hour of the spillage, residents should be evacuated from the area. If the benzene vapor pressure is \(10 \mathrm{kPa}\), estimate the mass transfer rate of benzene being convected to the air, and determine whether the residents should be evacuated or not.

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