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What is the physical significance of the Lewis number? How is it defined? What does a Lewis number of 1 indicate?

Short Answer

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Answer: The Lewis number (Le) is a dimensionless number that represents the relative rate of diffusive transport of heat and mass in a fluid system, helping to understand the balance between heat and mass transfer. A Lewis number of 1 implies that the rates of heat and mass diffusion are equal in the system, meaning that the temperature and concentration fields in the system are similar and the analysis of the problem becomes simpler.

Step by step solution

01

Define the Lewis number

The Lewis number (Le) is a dimensionless number used in analyzing heat and mass transfer problems. It represents the relative rate of diffusive transport of heat and mass in a fluid system. The Lewis number is defined as the ratio of the thermal diffusivity, α, to the mass diffusivity, D: \[Le = \frac{α}{D}\]
02

Explain the physical significance of the Lewis number

The Lewis number helps to understand the balance between the heat and mass transfer in a system. In other words, it quantifies the relative importance of heat conduction to mass diffusion in a medium. When studying transport phenomena such as simultaneous heat and mass transfer in problems like evaporation, condensation, or combustion, the Lewis number becomes a crucial parameter for deciding appropriate models and approximations.
03

Interpret what a Lewis number of 1 indicates

A Lewis number of 1 implies that the rates of heat and mass diffusion are equal in the system. This means that the rate at which heat is conducted through the medium is the same as the rate at which mass diffuses through the medium. In such cases, the temperature and concentration fields in the system are similar, making the analysis of the problem simpler. Lewis number of 1 is typically assumed in many engineering applications where the difference between heat and mass transfer rates does not significantly affect the overall performance of the system.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Dimensionless Numbers
Dimensionless numbers play a crucial role in the study of fluid dynamics and transport phenomena. They serve as handy tools for simplifying complex problems by reducing the number of variables. This makes it easier to analyze and compare different systems. Examples of dimensionless numbers include the Reynolds number, the Prandtl number, and the Lewis number, among many others.

These numbers are ratios that represent relationships between different physical quantities, such as forces or rates. By utilizing dimensionless numbers, engineers and scientists can better understand the balance and behavior of physical processes within a system.
  • They help in relating the behavior of real-world systems to theoretical models.
  • They enable scaling, which is the ability to understand how changes in size or other parameters can affect system behavior.
  • They allow results obtained from model experiments to be applicable to other similar systems, irrespective of their absolute size.
Understanding dimensionless numbers is key to grasping the concepts of heat and mass transfer within transport phenomena.
Heat and Mass Transfer
Heat and mass transfer are fundamental concepts in the study of energy and matter motion within physical systems. They involve the movement of energy and matter, respectively, from one place to another, usually driven by differences in temperature and concentration.

The study of heat transfer involves mechanisms such as conduction, convection, and radiation, while mass transfer primarily involves diffusion and convective mass transport. The key aim is to understand how these transfers occur under various conditions and how they can be predicted and controlled.
  • Conduction: This is the transfer of heat through a substance without any motion of the substance itself. It's mainly observed in solids.
  • Convection: Here, heat is transferred by fluid movement, often occurring in liquids and gases.
  • Radiation: This mode of heat transfer happens without any medium, through electromagnetic waves.
Mass transfer, on the other hand, involves the movement of different substances, often observed in situations like the diffusion of a gas in a liquid or the evaporation of liquids. Understanding both heat and mass transfer is essential for analyzing many natural and industrial processes.
Transport Phenomena
Transport phenomena cover a broad field of study that includes the transfer of momentum, heat, and mass within physical systems. This area is essential for the development of processes in engineering and many natural sciences.

The key components of transport phenomena are:
  • Momentum Transfer: Often referred to as fluid dynamics, it involves the study of how forces are transferred within fluids.
  • Heat Transfer: The process of thermal energy being moved within or between substances.
  • Mass Transfer: The movement of various constituents within physical systems.
Each type of transfer is governed by its own set of mathematical equations, which help predict and understand the rate and direction of transfer. These principles are vital in designing and optimizing engineering systems, such as in chemical reactors, heat exchangers, and environmental systems. Entering the world of transport phenomena allows us to grasp how these different types of transfers are interconnected and influence the behavior of complex systems.
Thermal Diffusivity
Thermal diffusivity is a material property that indicates how quickly heat spreads throughout a material. It is expressed as the ratio of thermal conductivity to the product of density and specific heat capacity.

The formula for thermal diffusivity, \( \alpha \), is:
\[ \alpha = \frac{k}{\rho c_p} \]
where:
  • \( k \) is the thermal conductivity of the material.
  • \( \rho \) is the density of the material.
  • \( c_p \) is the specific heat capacity at constant pressure.
A high thermal diffusivity means that, when a material is exposed to thermal gradients, it can conduct heat quickly compared to storing it. This is crucial for applications where rapid heat conduction is desired, such as in heat sinks or thermal barrier coatings.

In the context of the Lewis number, thermal diffusivity is compared to mass diffusivity to understand the relative rates of heat and mass transfer, giving insights into the efficiency of processes like drying, curing, and combustion.
Mass Diffusivity
Mass diffusivity, also known as diffusion coefficient, is a measure of how fast a substance diffuses through a medium. This property is crucial in processes where concentration gradients drive mass transfer.

The diffusion coefficient, \( D \), is defined by Fick's first law, which states that the mass flux of a component is proportional to the concentration gradient:
\[ J = -D \frac{dC}{dx} \]
where:
  • \( J \) is the mass flux.
  • \( \frac{dC}{dx} \) is the concentration gradient.
Mass diffusivity is a key factor in establishing the rate at which different species mix in applications such as chemical reactions, pollutant transport in air or water, and biological processes like respiration.

In systems characterized by a Lewis number, comparing mass diffusivity with thermal diffusivity helps to determine which of these processes, heat, or mass transfer, will dominate under given conditions. Analyzing mass diffusivity allows for enhanced control over processes that rely heavily on efficient mass transfer dynamics, like separation processes and catalysis.

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Most popular questions from this chapter

An 8-cm-internal-diameter, 30-cm-high pitcher halffilled with water is left in a dry room at \(15^{\circ} \mathrm{C}\) and \(87 \mathrm{kPa}\) with its top open. If the water is maintained at \(15^{\circ} \mathrm{C}\) at all times also, determine how long it will take for the water to evaporate completely.

What is the relation \((f / 2) \mathrm{Re}=\mathrm{Nu}=\mathrm{Sh}\) known as? Under what conditions is it valid? What is the practical importance of it? \(\mathrm{St}_{\text {mass }} \mathrm{Sc}^{2 / 3}\) and what are the names of the variables in it? Under what conditions is it valid? What is the importance of it in engineering?

Hydrogen can cause fire hazards, and hydrogen gas leaking into surrounding air can lead to spontaneous ignition with extremely hot flames. Even at very low leakage rate, hydrogen can sustain combustion causing extended fire damages. Hydrogen gas is lighter than air, so if a leakage occurs it accumulates under roofs and forms explosive hazards. To prevent such hazards, buildings containing source of hydrogen must have adequate ventilation system and hydrogen sensors. Consider a metal spherical vessel, with an inner diameter of \(5 \mathrm{~m}\) and a thickness of \(3 \mathrm{~mm}\), containing hydrogen gas at \(2000 \mathrm{kPa}\). The vessel is situated in a room with atmospheric air at \(1 \mathrm{~atm}\). The ventilation system for the room is capable of keeping the air fresh, provided that the rate of hydrogen leakage is below \(5 \mu \mathrm{g} / \mathrm{s}\). If the diffusion coefficient and solubility of hydrogen \(\mathrm{gas}\) in the metal vessel are \(1.5 \times 10^{-12} \mathrm{~m}^{2} / \mathrm{s}\) and \(0.005 \mathrm{kmol} / \mathrm{m}^{3}\).bar, respectively, determine whether or not the vessel is safely containing the hydrogen gas.

The mass diffusivity of ethanol \(\left(\rho=789 \mathrm{~kg} / \mathrm{m}^{3}\right.\) and \(M=46 \mathrm{~kg} / \mathrm{kmol}\) ) through air was determined in a Stefan tube. The tube has a uniform cross-sectional area of \(0.8 \mathrm{~cm}^{2}\). Initially, the ethanol surface was \(10 \mathrm{~cm}\) from the top of the tube; and after 10 hours have elapsed, the ethanol surface was \(25 \mathrm{~cm}\) from the top of the tube, which corresponds to \(0.0445 \mathrm{~cm}^{3}\) of ethanol being evaporated. The ethanol vapor pressure is \(0.0684\) atm, and the concentration of ethanol is zero at the top of the tube. If the entire process was operated at \(24^{\circ} \mathrm{C}\) and \(1 \mathrm{~atm}\), determine the mass diffusivity of ethanol in air.

Pure \(\mathrm{N}_{2}\) gas at \(1 \mathrm{~atm}\) and \(25^{\circ} \mathrm{C}\) is flowing through a 10-m-long, 3-cm-inner diameter pipe made of 2 -mm-thick rubber. Determine the rate at which \(\mathrm{N}_{2}\) leaks out of the pipe if the medium surrounding the pipe is \((a)\) a vacuum and \((b)\) atmospheric air at \(1 \mathrm{~atm}\) and \(25^{\circ} \mathrm{C}\) with 21 percent \(\mathrm{O}_{2}\) and 79 percent \(\mathrm{N}_{2}\).

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