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How is the concentration of a commodity defined? How is the concentration gradient defined? How is the diffusion rate of a commodity related to the concentration gradient?

Short Answer

Expert verified
Answer: The diffusion rate of a commodity is directly proportional to the concentration gradient, as stated in Fick's first law. A higher concentration gradient results in a faster diffusion rate, meaning that solute particles move more quickly from regions of higher concentration to regions of lower concentration.

Step by step solution

01

Definition of Concentration of a Commodity

The concentration of a commodity is defined as the amount of a substance (solute) present in a given volume of another substance (solvent). It is often represented by the letter 'C' and is usually expressed in moles per liter (M or mol/L).
02

Definition of Concentration Gradient

The concentration gradient is a term used to describe the change in concentration of a commodity in a particular space or direction. It represents the difference in concentration between two points divided by the distance between those points. Mathematically, it can be written as: \(\Delta C / \Delta x\) where \(\Delta C\) represents the change in concentration, and \(\Delta x\) represents the change in distance (or the distance between the two points).
03

Relationship between Diffusion Rate and Concentration Gradient

The diffusion rate of a commodity is related to the concentration gradient through Fick's first law. Fick's first law states that the rate of diffusion of a solute is directly proportional to the concentration gradient and the diffusion coefficient (D) of the solute in the solvent. Mathematically, it can be expressed as: \(J = -D \frac{\Delta C}{\Delta x}\) where \(J\) represents the diffusion rate (or the rate at which the solute particles move), \(D\) is the diffusion coefficient of the solute, \(\Delta C\) is the difference in concentration, and \(\Delta x\) is the distance between two points. This implies that a higher concentration gradient results in a faster diffusion rate. In other words, the more significant the difference in concentration between two points, the faster the solute particles will move from the regions of higher concentration to the regions of lower concentration.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Concentration of a Commodity
When discussing the concentration of a commodity in the context of chemistry or physics, it refers to the amount of a specific substance, or solute, within a given volume of solvent. Imagine pouring a spoonful of salt into a glass of water; the amount of salt dissolved in the water dictates the solution's concentration. Typically, concentration is measured in moles per liter (mol/L), occasionally referred to as molarity. This standardization allows scientists and students alike to compare and calculate reactions and diffusion rates with precision.

Importance of Accurate Concentration Measurement

  • Ensures consistent results in chemical experiments.
  • Crucial for calculating reactant and product yields in reactions.
  • Helps predict how substances will diffuse in various environments.
Concentration Gradient
The concentration gradient is fundamental to understanding how substances move from one area to another. It is the measure of how the concentration of a commodity changes over a distance. Consider two adjacent rooms, one filled with perfume and the other with clean air. Over time, the scent diffuses to the other room - this movement is a result of the concentration gradient. Mathematically speaking, the gradient is represented as \(\Delta C / \Delta x\), with \(\Delta C\) being the change in concentration and \(\Delta x\) the distance over which this change occurs.

Role of Concentration Gradient in Nature and Industry

  • Drives the transport of nutrients and waste in biological systems.
  • Used in engineering to design efficient systems for gas exchange or chemical extraction.
Fick's First Law
Fick's first law is a cornerstone principle in the study of diffusion, indicating that the diffusion rate - how fast a substance spreads out - is proportional to the concentration gradient. Essentially, it illustrates how particles will naturally move from an area of higher concentration to one of lower concentration. Represented by the equation \(J = -D \frac{\Delta C}{\Delta x}\), it quantifies this relationship, with \(J\) indicating the diffusion rate, \(D\) the diffusion coefficient, and \(\Delta C/\Delta x\) the concentration gradient. The negative sign indicates the direction of diffusion, against the concentration gradient.

Implications of Fick's Law

  • Enables the prediction of drug delivery rates in medical patches.
  • Assists in environmental modeling of pollutant dispersion.
Diffusion Coefficient
The diffusion coefficient (\(D\)) is a property that reflects how easily a substance can move through another medium. It is influenced by various factors, such as temperature, viscosity of the medium, and the size of the particles diffusing. The coefficient guides us in understanding the ease with which molecules or ions can traverse a particular environment.

Factors Affecting the Diffusion Coefficient

  • Temperature: Generally, higher temperatures increase the diffusion rate.
  • Solvent viscosity: In a more viscous medium, diffusion is typically slower.
  • Particle size: Smaller particles tend to diffuse more rapidly than larger ones.

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Most popular questions from this chapter

A thick part made of nickel is put into a room filled with hydrogen at \(3 \mathrm{~atm}\) and \(85^{\circ} \mathrm{C}\). Determine the hydrogen concentration at a depth of \(2-\mathrm{mm}\) from the surface after \(24 \mathrm{~h}\).

When the density of a species \(A\) in a semi-infinite medium is known at the beginning and at the surface, explain how you would determine the concentration of the species \(A\) at a specified location and time.

Benzene-free air at \(25^{\circ} \mathrm{C}\) and \(101.3 \mathrm{kPa}\) enters a 5 -cm-diameter tube at an average velocity of \(5 \mathrm{~m} / \mathrm{s}\). The inner surface of the \(6-m\)-long tube is coated with a thin film of pure benzene at \(25^{\circ} \mathrm{C}\). The vapor pressure of benzene \(\left(\mathrm{C}_{6} \mathrm{H}_{6}\right)\) at \(25^{\circ} \mathrm{C}\) is \(13 \mathrm{kPa}\), and the solubility of air in benezene is assumed to be negligible. Calculate \((a)\) the average mass transfer coefficient in \(\mathrm{m} / \mathrm{s},(b)\) the molar concentration of benzene in the outlet air, and \((c)\) the evaporation rate of benzene in \(\mathrm{kg} / \mathrm{h}\).

Consider a brick house that is maintained at \(20^{\circ} \mathrm{C}\) and 60 percent relative humidity at a location where the atmospheric pressure is \(85 \mathrm{kPa}\). The walls of the house are made of 20 -cm-thick brick whose permeance is \(23 \times 10^{-12} \mathrm{~kg} / \mathrm{s} \cdot \mathrm{m}^{2} \cdot \mathrm{Pa}\). Taking the vapor pressure at the outer side of the wallboard to be zero, determine the maximum amount of water vapor that will diffuse through a \(3-\mathrm{m} \times 5-\mathrm{m}\) section of a wall during a 24-h period.

When handling corrosive and toxic substances, chemical resistant gloves should be worn. When selecting gloves to handle a substance, the suitability of the gloves should be considered. Depending on the material of the gloves, they could be easily permeable by some substances. An employee is handling tetrachloroethylene solution for a metal-cleaning process. Dermal exposure to tetrachloroethylene can cause skin irritation, and long-term exposure to it can have adverse neurological effects on humans. As a protective measure, the employee wears rubber-blend gloves while handling the tetrachloroethylene solution. The average thickness of the gloves is \(0.67 \mathrm{~mm}\), and the mass diffusivity of tetrachloroethylene in the gloves is \(3 \times 10^{-8} \mathrm{~m}^{2} / \mathrm{s}\). Estimate how long can the employee's hand be in contact with the tetrachloroethylene solution before the concentration of the solution at the inner glove surface reaches \(1 \%\) of the concentration at the outer surface. Is this type of glove suitable for handling tetrachloroethylene solution?

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