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The radionuclide C11decays according to

C11โ†’B11+e++v,T1/2=20.3

The maximum energy of the emitted positrons is 0.960 MeV. (a) Show that the disintegration energy Qfor this process is given by

role="math" localid="1661759171201" Q=(mC-mB-2me)c2

WheremCandmBare the atomic masses ofC11andB11, respectively, andmeis the mass of a positron. (b) Given the mass valuesmC=11.011434u,mB=11.009305uandme=0.0005486u, calculate Qand compare it with the maximum energy of the emitted positron given above. (Hint:LetmC andmBbe the nuclear masses and then add in enough electrons to use the atomic masses.)

Short Answer

Expert verified
  1. The disintegration energy Q for this process is given byQ=mC-mB-2mec2.
  2. The value of Q is 0.961 MeV and the value is almost the same value as given maximum energy of the emitted positrons.

Step by step solution

01

Given data

The radioactive decay,C11โ†’B11+e++v,T1/2=20.3min

Maximum energy of the emitted positrons,Emax=0.960MeV

Atomic mass ofC11,mC=11.011434u,

Atomic mass ofB11,mB=11.009305u ,

Atomic mass of a positron,me=0.0005486u

02

Understanding the concept of disintegration energy

For nuclear fission of radioactive nuclide, the radionuclide needs to disintegrate by releasing some energy change. Again, nuclides with nuclear radii have nuclear mass acting into the disintegrating energy. But, we know that the sum of nuclear mass and the electronic mass which is the sum of total electron mass gives us the atomic mass. Thus, considering this concept, we can get the disintegration energy that is in the form of atomic masses of the nuclides.

03

Step 3:a) Calculation of the disintegration energy of the process

Since, the positron has the same mass as an electron and the neutrino has negligible mass. Then, the energy considering its nuclear radii can be given as:

โˆ†mc2=mB+me-mCc2

Now, since carbon has 6 electrons (see Appendix F and/or G) and boron has 5 electrons, we can add and subtract 6meto the above expression and obtain the above expression as:

โˆ†mc2=mB+7me-mC-6mec2=mB+2me-mCc2

The above final expression involves the atomic masses of the nuclidesas well an โ€œextraโ€ term corresponding to two electron masses.

Now, the above term considering the energy of an electron can be given as:

โˆ†mc2=mC-mBc2-20.511MeV,asmec2=0.511MeV......1

Hence, the disintegration energy Q for this process is given by Q=mC-mB-2mec2where, mCand mBare the atomic masses of C11and B11, respectively, and meis the mass of a positron.

04

b) Calculation of the value of Q

Using the given data in equation (1), we can get the disintegration energy or the Q-value of the decay process as follows:

โˆ†mc2=11.011434u-11.009305u931.5MeV/u-1.022MeV=0.961MeV

Hence, the value of Q is 0.961MeVand is almost the same value as given maximum energy of the positrons.

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Most popular questions from this chapter

At, t = 0a sample of radionuclide Ahas twice the decay rate as a sample of radionuclide B.The disintegration constants are ฮปAandฮปBwithฮปA>ฮปB. Will the two samples ever have (simultaneously) the same decay rate?

Calculate the mass of a sample of (initially pure) K40that has an initial decay rate of1.70ร—105disintegrations/s. The isotope has a half-life of 1.28ร—109y.

A certain radionuclide is being manufactured in a cyclotron at a constant rate R. It is also decaying with disintegration constantฮป. Assume that the production process has been going on for a time that is much longer than the half-life of the radionuclide. (a) Show that the numbers of radioactive nuclei present after such time remains constant and is given byN=Rฮป. (b) Now show that this result holds no matter how many radioactive nuclei were present initially. The nuclide is said to be in secular equilibriumwith its source; in this state its decay rate is just equal to its production rate.

Question: At the end of World War II, Dutch authorities arrested Dutch artist Hans van Meegeren for treason because, during the war, he had sold a masterpiece painting to the Nazi Hermann Goering. The painting, Christ and His Disciples at Emmausby Dutch master Johannes Vermeer (1632โ€“1675), had been discovered in 1937 by van Meegeren, after it had been lost for almost 300 years. Soon after the discovery, art experts proclaimed that Emmauswas possibly the best Vermeer ever seen. Selling such a Dutch national treasure to the enemy was unthinkable treason. However, shortly after being imprisoned, van Meegeren suddenly announced that he, not Vermeer, had painted Emmaus. He explained that he had carefully mimicked Vermeer's style, using a 300-year-old canvas and Vermeerโ€™s choice of pigments; he had then signed Vermeerโ€™s name to the work and baked the painting to give it an authentically old look.

Was van Meegeren lying to avoid a conviction of treason, hoping to be convicted of only the lesser crime of fraud? To art experts, Emmauscertainly looked like a Vermeer but, at the time of van Meegerenโ€™s trial in 1947, there was no scientific way to answer the question. However, in 1968 Bernard Keisch of Carnegie-Mellon University was able to answer the question with newly developed techniques of radioactive analysis.

Specifically, he analyzed a small sample of white lead-bearing pigment removed from Emmaus. This pigment is refined from lead ore, in which the lead is produced by a long radioactive decay series that starts with unstableU238and ends with stablePB206.To follow the spirit of Keischโ€™s analysis, focus on the following abbreviated portion of that decay series, in which intermediate, relatively short-lived radionuclides have been omitted:

Th230โ†’75.4kyRa226โ†’1.60kyPb210โ†’22.6yPb206

The longer and more important half-lives in this portion of the decay series are indicated.

a) Show that in a sample of lead ore, the rate at which the number ofPb210nuclei changes is given by

dN210dt=ฮป226N226-ฮป210N210,

whereN210andN226are the numbers ofPb210nuclei and Ra226nuclei in the sample andฮป210andฮป226are the corresponding disintegration constants. Because the decay series has been active for billions of years and because the half-life of Pb210is much less than that of role="math" localid="1661919868408" Ra226, the nuclidesRa226andPb210are in equilibrium; that is, the numbers of these nuclides (and thus their concentrations) in the sample do not change. (b) What is the ratioR226R210of the activities of these nuclides in the sample of lead ore? (c) What is the N226N210ratioof their numbers? When lead pigment is refined from the ore, most of the radiumRa226 is eliminated. Assume that only 1.00% remains. Just after the pigment is produced, what are the ratios (d)R226R210 and (e)N226N210? Keisch realized that with time the ratioR226R210of the pigment would gradually change from the value in freshly refined pigment back to the value in the ore, as equilibrium between thePb210and the remainingRa226is established in the pigment. If Emmauswere painted by Vermeer and the sample of pigment taken from it was 300 years old when examined in 1968, the ratio would be close to the answer of (b). If Emmauswere painted by van Meegeren in the 1930s and the sample were only about 30 years old, the ratio would be close to the answer of (d). Keisch found a ratio of 0.09. (f) Is Emmausa Vermeer?

Locate the nuclides displayed in Table 42-1 on the nuclidic chart of Fig. 42-5. Verify that they lie in the stability zone.

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