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An electron is emitted from a middle-mass nuclide (A=150, say) with a kinetic energy of 1.0 MeV. (a) What is its de-Broglie wavelength? (b) Calculate the radius of the emitting nucleus. (c) Can such an electron be confined as a standing wave in a “box” of such dimensions? (d) Can you use these numbers to disprove the (abandoned) argument that electrons actually exist in nuclei?

Short Answer

Expert verified
  1. The de-Broglie wavelength of the electron is9×102fm .
  2. The radius of the emitting nucleus is 6.4 fm .
  3. No, the electron cannot be confined as a standing wave in a “box” of such dimensions due to their large wavelengths.
  4. Yes, these numbers can be used to disprove the argument that electrons actually exist.

Step by step solution

01

The given data

  1. Mass number of the nuclide A = 150.
  2. Kinetic energy of the emitted electron.
02

Understanding the concept of size and confinement

The electron can only be confined within a given structure only if its wavelength is smaller than the atomic radius of the nuclide. Now, the wavelength of an electron is associated with the momentum according to the de-Broglie concept. Thus, by comparing the wavelength with the calculated atomic radius of the nuclide, consider the strong argument for the case of confinement.

The kinetic energy of a particle in motion:

K=mc2 ….. (i)

The energy and momentum relation according to relativistic concept,

pc=K2+m2c4 …… (ii)

The atomic radius of a nuclide using its nucleon or mass number,

r=r0A13 …… (iii)

The de-Broglie wavelength of a particle of smaller size:

λ=hp …… (iv)

03

a) Calculate the de-Broglie wavelength

Consider the known data, mc2=0.511MeVand hc = 1240 MeV.fm

Substitute the value of momentum from equation (ii) in equation (iv), consider de-Broglie wavelength of the electron as follows:

λ=hcK2+m2c4=hcK2+2Kmc2fromequation(i,K=mc2)

Substitute the values as:

λ=1240MeV.fm1.0MeV2+21.0MeV0.511MeV=9×102fm

Hence, the value of the wavelength is9×102fm .

04

b) Calculate the radius of the emitting nucleus

Using the given data in equation (iii), determine the radius of the emitting nucleus as follows:

r=1.2fm1501/3=6.4fm

Hence, the value of the radius is 6.4 fm .

05

c) Calculate whether the electron of the given nuclide can be confined as a standing wave

Since,λ>>rfrom parts (a) and (b) calculationsthe electron cannot be confined in the nuclide. Recall that at leastλ2 is needed in any particular direction, to support a standing wave in an “infinite well.” A finite well is able to supportslightlyless than λ2(as one caninfer from the ground state wave function in Fig. 39-6), but in the present caseλris far too big to be supported.

06

d) Determine whether an argument can be raised for part (c)

A strong cas e can be made on the basis of the remarks in part (c), above.

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Most popular questions from this chapter

Question: At the end of World War II, Dutch authorities arrested Dutch artist Hans van Meegeren for treason because, during the war, he had sold a masterpiece painting to the Nazi Hermann Goering. The painting, Christ and His Disciples at Emmausby Dutch master Johannes Vermeer (1632–1675), had been discovered in 1937 by van Meegeren, after it had been lost for almost 300 years. Soon after the discovery, art experts proclaimed that Emmauswas possibly the best Vermeer ever seen. Selling such a Dutch national treasure to the enemy was unthinkable treason. However, shortly after being imprisoned, van Meegeren suddenly announced that he, not Vermeer, had painted Emmaus. He explained that he had carefully mimicked Vermeer's style, using a 300-year-old canvas and Vermeer’s choice of pigments; he had then signed Vermeer’s name to the work and baked the painting to give it an authentically old look.

Was van Meegeren lying to avoid a conviction of treason, hoping to be convicted of only the lesser crime of fraud? To art experts, Emmauscertainly looked like a Vermeer but, at the time of van Meegeren’s trial in 1947, there was no scientific way to answer the question. However, in 1968 Bernard Keisch of Carnegie-Mellon University was able to answer the question with newly developed techniques of radioactive analysis.

Specifically, he analyzed a small sample of white lead-bearing pigment removed from Emmaus. This pigment is refined from lead ore, in which the lead is produced by a long radioactive decay series that starts with unstableU238and ends with stablePB206.To follow the spirit of Keisch’s analysis, focus on the following abbreviated portion of that decay series, in which intermediate, relatively short-lived radionuclides have been omitted:

Th23075.4kyRa2261.60kyPb21022.6yPb206

The longer and more important half-lives in this portion of the decay series are indicated.

a) Show that in a sample of lead ore, the rate at which the number ofPb210nuclei changes is given by

dN210dt=λ226N226-λ210N210,

whereN210andN226are the numbers ofPb210nuclei and Ra226nuclei in the sample andλ210andλ226are the corresponding disintegration constants. Because the decay series has been active for billions of years and because the half-life of Pb210is much less than that of role="math" localid="1661919868408" Ra226, the nuclidesRa226andPb210are in equilibrium; that is, the numbers of these nuclides (and thus their concentrations) in the sample do not change. (b) What is the ratioR226R210of the activities of these nuclides in the sample of lead ore? (c) What is the N226N210ratioof their numbers? When lead pigment is refined from the ore, most of the radiumRa226 is eliminated. Assume that only 1.00% remains. Just after the pigment is produced, what are the ratios (d)R226R210 and (e)N226N210? Keisch realized that with time the ratioR226R210of the pigment would gradually change from the value in freshly refined pigment back to the value in the ore, as equilibrium between thePb210and the remainingRa226is established in the pigment. If Emmauswere painted by Vermeer and the sample of pigment taken from it was 300 years old when examined in 1968, the ratio would be close to the answer of (b). If Emmauswere painted by van Meegeren in the 1930s and the sample were only about 30 years old, the ratio would be close to the answer of (d). Keisch found a ratio of 0.09. (f) Is Emmausa Vermeer?

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