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(a) For a given value of the principal quantum number nfor a hydrogen atom, how many values of the orbital quantum number Iare possible?

(b) For a given value of I, how many values of the orbital magnetic quantum numbermIare possible?

(c) For a given value of n, how many values ofmIare possible?

Short Answer

Expert verified

(a) There are distinct values of orbital quantum number I are possible For a given value of the principal quantum number for a hydrogen atom.

(b) There are 2I + 1 distinct values of orbital magnetic quantum number mIfor a given value of .

(c) There are 2n + 1 distinct values of orbital magnetic quantum number mIfor a given value of n .

Step by step solution

01

Principal, orbital, and orbital magnetic quantum number:

Each atom's electron is given one of four quantum numbers, the primary quantum number n , to describe the state of that electron.

A measurement of the angular momentum's magnitude is the orbital quantum number I .

The angular momentum vector's orientation in space is connected to the orbital magnetic quantum numbermI .

02

(a) Finding how many values of the orbital quantum number  are possible for a given value of the principal quantum number  for a hydrogen atom:

For a hydrogen atom, the values of orbital quantum number I for a given value of n are 0,1,2,....,(n-1) .

Hence, there are distinct values of orbital quantum number I are possible For a given value of the principal quantum number n for a hydrogen atom.

03

(b) Finding how many value the orbital magnetic quantum number mI are possible for a given value of I :

For a hydrogen atom, the values of orbital magnetic quantum number for a given value of I is -I,-(I-1),-(I-2),............,+(I-1),+I.

Hence, there are 2I+1 distinct values of orbital magnetic quantum number mIfor a given value of I .

04

(c) Finding how many value the orbital magnetic quantum number  are possible for a given value of

In step 3, there are 2I+1 distinct values of orbital magnetic quantum number mIfor a given value of I .

Also, in step 2, there are n distinct values of orbital quantum number I are possible For a given value of the principal quantum number for a hydrogen atom.

The conclusion is that, there are 2n+1 distinct values of orbital magnetic quantum number mI for a given value of n .

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Most popular questions from this chapter

The wave function for the hydrogen-atom quantum state represented by the dot plot shown in Fig. 39-21, which has n = 2 and l=ml=0, is

ฮจ200(r)=142ฯ€a-3/2(2-ra)e-r/2a

in which a is the Bohr radius and the subscript onฮจ(r)gives the values of the quantum numbers n,l,ml. (a) Plotฮจ(2002r)and show that your plot is consistent with the dot plot of Fig. 39-21. (b) Show analytically thatฮจ(2002r)has a maximum at r=4a. (c) Find the radial probability densityP200(r)for this state. (d) Show that

โˆซ0โˆžP200(r)dr=1

and thus that the expression above for the wave function ฮจ200(r)has been properly normalized.

An electron is confined to a narrow-evacuated tube of length 3.0 m; the tube functions as a one-dimensional infinite potential well. (a) What is the energy difference between the electronโ€™s ground state and its first excited state? (b) At what quantum number n would the energy difference between adjacent energy levels be 1.0 ev-which is measurable, unlike the result of (a)? At that quantum number, (c) What multiple of the electronโ€™s rest energy would give the electronโ€™s total energy and (d) would the electron be relativistic?

In atoms, there is a finite, though very small, probability that, at some instant, an orbital electron will actually be found inside the nucleus. In fact, some unstable nuclei use this occasional appearance of the electron to decay by electron capture. Assuming that the proton itself is a sphere of radius 1.1ร—10-15mand that the wave function of the hydrogen atomโ€™s electron holds all the way to the protonโ€™s center, use the ground-state wave function to calculate the probability that the hydrogen atomโ€™s electron is inside its nucleus.

(a) Show that for the region x>L in the finite potential well of Fig. 39-7, ฯˆ(x)=De2kxis a solution of Schrรถdingerโ€™s equation in its one-dimensional form, where D is a constant and k is positive. (b) On what basis do we find this mathematically acceptable solution to be physically unacceptable?

Identify the correspondence principle.

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