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13.1D The term acid rain is frequently used today. Define what is meant by the term. Discuss the origin and consequences of acid rain. Also discuss options for its control.

Short Answer

Expert verified
Acid rain: precipitation with elevated acidity. Origin: emissions of SO2 and NOx. Consequences: environmental and structural damage. Control: cleaner energy sources, emission reductions, and regulations.

Step by step solution

01

- Define Acid Rain

Acid rain refers to any form of precipitation (rain, snow, sleet, or fog) that contains elevated levels of hydrogen ions (low pH), making it acidic. Typically, natural rain is slightly acidic with a pH of about 5.6, but acid rain has a pH below 5.6.
02

- Origin of Acid Rain

Explain that acid rain is caused by the emission of sulfur dioxide (SO2) and nitrogen oxides (NOx) into the atmosphere. These pollutants can come from natural sources like volcanoes, but primarily they are from human activities such as burning fossil fuels in power plants, vehicles, and industrial processes. The pollutants react in the atmosphere to form sulfuric acid (H2SO4) and nitric acid (HNO3), which then fall back to the surface as acid rain.
03

- Environmental Consequences

Discuss how acid rain can have several harmful effects on the environment: it can damage forests, harm aquatic life in lakes and rivers by lowering the pH of the water, and deteriorate buildings and monuments made of limestone and marble by reacting with the minerals.
04

- Human Health Impact

Mention that while acid rain itself does not pose a direct health risk to humans, the pollutants that cause acid rain (SO2 and NOx) can lead to respiratory problems and other health issues.
05

- Control Measures

Discuss various ways to control acid rain, such as using cleaner sources of energy (wind, solar), reducing emissions through technological advancements (scrubbers in industrial chimneys, catalytic converters in vehicles), and implementing strict environmental regulations to limit SO2 and NOx emissions.

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Environmental Pollution
Environmental pollution refers to the introduction of harmful substances or products into the environment. It can come from various sources, like industrial activities, transportation, and agricultural practices.
One significant type of pollution is air pollution, which includes emissions of gases like sulfur dioxide (SO2) and nitrogen oxides (NOx). These pollutants can result from burning fossil fuels in power plants and vehicles.
When these pollutants are released into the atmosphere, they can lead to serious environmental problems such as acid rain. Acid rain can harm ecosystems, corrode buildings, and affect human health indirectly.
Sulfur Dioxide Emissions
Sulfur dioxide (SO2) is a colorless gas with a sharp, pungent smell. It is produced by volcanic eruptions and from human activities, primarily the burning of fossil fuels that contain sulfur. Factories, power plants, and vehicles are major sources of SO2 emissions.
When sulfur dioxide is released into the atmosphere, it can react with water, oxygen, and other chemicals to form sulfuric acid (H2SO4). This acid can then mix with precipitation, creating acid rain, which has a much lower pH than normal rainwater.
To control sulfur dioxide emissions, many countries have imposed stringent regulations. Technologies such as flue-gas desulfurization (scrubbers) are used in power plants to remove SO2 from exhaust gases. Additionally, switching to low-sulfur fuels and increasing the use of renewable energy sources can significantly reduce these emissions.
Nitrogen Oxides
Nitrogen oxides (NOx) are a group of highly reactive gases, including nitrogen dioxide (NO2) and nitrogen monoxide (NO). These gases are primarily produced from vehicle exhaust, industrial processes, and the burning of fossil fuels.
In the atmosphere, nitrogen oxides can react with other chemicals to form nitric acid (HNO3), which can then combine with water in the atmosphere and result in acid rain. Acid rain due to NOx can have detrimental effects on aquatic ecosystems by increasing the acidity of bodies of water, making them inhospitable for fish and other wildlife.
Reducing nitrogen oxide emissions is essential for controlling acid rain. This can be done by implementing catalytic converters in vehicles, promoting public transportation, and adopting cleaner industrial practices. Governments also play a key role by setting and enforcing environmental standards to limit NOx emissions.

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Most popular questions from this chapter

13.6D A factory requires \(3750 \mathrm{~kW}\) of electric power and highquality steam at \(107^{\circ} \mathrm{C}\) with a mass flow rate of \(2.2 \mathrm{~kg} / \mathrm{s}\). Two options are under consideration: Option 1: A single boiler generates steam at \(2.0 \mathrm{MPa}, 320^{\circ} \mathrm{C}\), supplying a turbine that exhausts to a condenser at \(0.007\) MPa. Steam is extracted from the turbine at \(107^{\circ} \mathrm{C}\), returning as a liquid to the boiler after use. Option 2: A boiler generates steam at \(2.0 \mathrm{MPa}, 320^{\circ} \mathrm{C}\), supplying a turbine that exhausts to a condenser at \(0.007 \mathrm{MPa}\). A separate process steam boiler generates the required steam at \(107^{\circ} \mathrm{C}\), which is returned as a liquid to the boiler after use. The boilers are fired with natural gas and \(20 \%\) excess air. For \(7200 \mathrm{~h}\) of operation annually, evaluate the two options on the basis of cost.

13.10 A sample of dried feedlot manure is being tested for use as a fuel. The mass analysis of the sample is \(42.7 \%\) carbon, \(5.5 \%\) hydrogen \(\left(\mathrm{H}_{2}\right), 31.3 \%\) oxygen \(\left(\mathrm{O}_{2}\right), 2.4 \%\) nitrogen \(\left(\mathrm{N}_{2}\right)\), \(0.3 \%\) sulfur, and \(17.8 \%\) noncombustible ash. The sample is burned completely with \(120 \%\) of theoretical air. Determine (a) the balanced reaction equation. (b) the air-fuel ratio on a mass basis.

13.54 A gaseous mixture of butane \(\left(\mathrm{C}_{4} \mathrm{H}_{10}\right)\) and \(80 \%\) excess air at \(25^{\circ} \mathrm{C}, 3\) atm enters a reactor. Complete combustion occurs, and the products exit as a mixture at \(1200 \mathrm{~K}, 3 \mathrm{~atm}\). Coolant enters an outer jacket as a saturated liquid and saturated vapor exits at essentially the same pressure. No significant heat transfer occurs from the outer surface of the jacket, and kinetic and potential energy effects are negligible. Determine for the jacketed reactor (a) the mass flow rate of the coolant, in \(\mathrm{kg}\) per kmol of fuel. (b) the rate of entropy production, in \(\mathrm{kJ} / \mathrm{K}\) per kmol of fuel. (c) the rate of exergy destruction, in kJ per kmol of fuel, for \(T_{0}=25^{\circ} \mathrm{C}\) Consider each of two coolants: water at 1 bar and ammonia at 10 bar.

11\. For a given fuel, how would the adiabatic flame temperature vary if the percent of theoretical air were increased? Why?

13.11 A sample of dried Appanoose County coal has a mass analysis of \(71.1 \%\) carbon, \(5.1 \%\) hydrogen \(\left(\mathrm{H}_{2}\right), 9.0 \%\) oxygen 13.11 A sample of dried Appanoose County coal has a mass analysis of \(71.1 \%\) carbon, \(5.1 \%\) hydrogen \(\left(\mathrm{H}_{2}\right), 9.0 \%\) oxygen \(\left(\mathrm{O}_{2}\right), 1.4 \%\) nitrogen \(\left(\mathrm{N}_{2}\right), 5.8 \%\) sulfur, and the rest noncombustile ash. For complete combustion with the theoretical amount of air, determine (a) the amount of \(\mathrm{SO}_{2}\) produced, in kg per \(\mathrm{kg}\) of coal. (b) the air-fuel ratio on a mass basis.

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