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Keeping only the first two diagrams in equation 8.23, and approximating NN-1N-2..... expand the exponential in a power series through the third power. Multiply each term out, and show that all the numerical coefficients give precisely the correct symmetry factors for the disconnected diagrams.

Short Answer

Expert verified

By doing the expansion, the symmetry factors come out naturally fromZc.

Step by step solution

01

Given Information 

We need to find all the numerical coefficients give precisely the correct symmetry factors for the disconnected diagrams.

02

Simplify

Lets first write out the expression 8.23in mathematical form (without diagrams):

Zc=exp12NN1V2d3r1d3r2f12+12NN1N2V3d3r1d3r2d3r3f12f23

Now we can do the approximation NN-1N-2.. Then we need to expand 's Zcexp function to the third power:

Zcexp12N2V2d3r1d3r2f12+12N3V3d3r1d3r2d3r3f12f23expλ1+λ+12λ2+16λ3+Zc=1+12N2V2d3r1d3r2f12+12N3V3d3r1d3r2d3r3f12f23+18N4V4d3r1d3r2d3r3d3r4f12f34+18N6V6d3r1d3r2d3r3d3r4d3r5d3r6f12f23f45f56+14N5V5d3r1d3r2d3r3d3r4d3r5f12f14f45+

To examine those integrals we have to add one more degree of integrals comming from the λ3of the. This would give:

Zc=1+12N2V2d3r1d3r2f12+12N3V3d3r1d3r2d3r3f12f23+18N4V4d3r1d3r2d3r3d3r4f12f34+18N6V6d3r1d3r2d3r3d3r4d3r5d3r6f12f23f45f56+14N5V5d3r1d3r2d3r3d3r4d3r5f12f34f45+148N6V6d3r1d3r2d3V3d3r4d3r5d3r6f12f34f56+116N7V7d3r1d3r2d3r3d3r4d3r5d3r6d3r7f12f34f56f67+148N9V9d3r1d3r2d3r3d3r4d3r5d3r6d3r7d3r8d3r9f12f23f45f56f78f89

We can see that in front of every integral asymmetry factor arises, we can check that on the example of this last integral:

+148N9V9d3r1d3r2d3r3d3r4d3r5d3r6d3r7d3r8d3r9f12f23f45f56f78f89

If we draw it's diagram and look for dots that can change the place we get exactly 48permutations:

03

Explanation 

Another example can be integral:

116N8V8d3r1d3r2d3r3d3r4d3r5d3r6d3r7d3r8f12f34f45f67f78

We can see that counting permutations, which is counting the dots with the same role in the integral and possible place where they can be interchanged, is exactly what we get from Taylor's expansion of $Z,c$.By doing the expansion, the symmetry factors come out naturally.

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Most popular questions from this chapter

For a two-dimensional Ising model on a square lattice, each dipole (except on the edges) has four "neighbors"-above, below, left, and right. (Diagonal neighbors are normally not included.) What is the total energy (in terms of ε) for the particular state of the 4×4square lattice shown in Figure 8.4?

Figure 8.4. One particular state of an Ising model on a 4×4square lattice (Problem 8.15).

For each of the diagrams shown in equation 8.20, write down the corresponding formula in terms of f-functions, and explain why the symmetry factor gives the correct overall coefficient.

Problem 8.13. Use the cluster expansion to write the total energy of a monatomic nonideal gas in terms of a sum of diagrams. Keeping only the first diagram, show that the energy is approximately
U32NkT+N2V·2π0r2u(r)e-βu(r)dr
Use a computer to evaluate this integral numerically, as a function of T, for the Lennard-Jones potential. Plot the temperature-dependent part of the correction term, and explain the shape of the graph physically. Discuss the correction to the heat capacity at constant volume, and compute this correction numerically for argon at room temperature and atmospheric pressure.

At T = 0, equation 8.50 says that s¯=1. Work out the first temperature-dependent correction to this value, in the limit βn1. Compare to the low-temperature behaviour of a real ferromagnet, treated in Problem 7.64.

Consider an Ising model of 100 elementary dipoles. Suppose you wish to calculate the partition function for this system, using a computer that can compute one billion terms of the partition function per second. How long must you wait for the answer?

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