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In this problem you will use the mean field approximation to analyse the behaviour of the Ising model near the critical point.

(a) Prove that, when x1,tanhxx-13x3

(b) Use the result of part (a) to find an expression for the magnetisation of the Ising model, in the mean field approximation, when T is very close to the critical temperature. You should find MTc-Tβ¯,whereβ(not to be confused with 1/kT) is a critical exponent, analogous to the f defined for a fluid in Problem 5.55. Onsager's exact solution shows that β=1/8in two dimensions, while experiments and more sophisticated approximations show that β1/3in three dimensions. The mean field approximation, however, predicts a larger value.

(c) The magnetic susceptibility χis defined as χ(M/B)T. The behaviour of this quantity near the critical point is conventionally written as χT-Tc-γ , where y is another critical exponent. Find the value of in the mean field approximation, and show that it does not depend on whether T is slightly above or slightly below Te. (The exact value of y in two dimensions turns out to be 7/4, while in three dimensions γ1.24.)

Short Answer

Expert verified

Hence proved that when x1,tanhxx-13x3

b)β=0.5c)γ=1

Step by step solution

01

Given information

In this problem we will use the mean field approximation to analyse the behaviour of the Ising model near the critical point.

02

Explanation

a) The function tanh x has the following definition:

tanhx=e2x-1e2x+1ex1+x+x22+x36+tanhx1+2x+(2x)22+(2x)36-11+2x+12x+(2x)22+(2x)362+2xx+2x22+4x361+x;(1+x)-11-xx+x2+2x33(1-x)=x-x2+x2-x3+2x33=x-x33

(b)This expression will now be used to expand relation 8.50:

role="math" s¯=tanh(βϵns¯)Tc=nϵk,β=1kT,βnϵ=TcTTcT·s¯-s¯Tc/T33s¯=TcT·s¯1-Tc/T23·s¯2TTc=1-Tc/T23·s¯2Tc23T2·s¯2=1-TTcTc23T2·s¯2=1-TTc/·3T2Tc2s¯2=3·T2Tc2·1-TTcs¯=3·T2Tc21-TTc,TTc-=3·T2Tc2Tc-TTc,t=T-TcTc=-3t(1+t)2,|t|<<1,(1+t)21+2r-3t(1+2t)-3t=-3T-TcTcs¯~Tc-Tβ=0.5

We may conclude that the same critical exponent applies to magnetisation because it is proportional to s.

03

Explanation

(c) To calculate susceptibility, we must differentiate the non-approximate formula for sin relation to B, which we shall manually insert:

s¯=tanh(β(ϵns¯+B))/ddBχ=β(1+ϵnχcosh2[β(ϵns¯+B)]

We can get χby setting B = 0 and rearranging terms:

χ=β(1+ϵnχ)cosh2[βϵns¯]χ=βcosh2[βϵns¯]-βϵnβϵn=TcTs¯(3|t|)0.5forTTc-cosh(x)1+x22cosh2TcTs¯1+Tc/T2·3|t|221+3Tc2T2|t|χβ1+3Tc2T2|t|-TcT1+3Tc2T2|t|-TcT=3Tc2T2|t|+1-TcT=3Tc2T2|t|-|t|=|t|3Tc2T2-1=|t|·3Tc2-T2T2χβ|t|·3Tc2-T2T21kBT·T2|t|·3Tc2-T21kB·T|t|·3Tc2-T2TTc1kB·Tc|t|·2Tc2χ12kB·1|t|TcχT-Tc-1γ=1

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Most popular questions from this chapter

Problem 8.13. Use the cluster expansion to write the total energy of a monatomic nonideal gas in terms of a sum of diagrams. Keeping only the first diagram, show that the energy is approximately
U32NkT+N2V·2π0r2u(r)e-βu(r)dr
Use a computer to evaluate this integral numerically, as a function of T, for the Lennard-Jones potential. Plot the temperature-dependent part of the correction term, and explain the shape of the graph physically. Discuss the correction to the heat capacity at constant volume, and compute this correction numerically for argon at room temperature and atmospheric pressure.

For each of the diagrams shown in equation 8.20, write down the corresponding formula in terms of f-functions, and explain why the symmetry factor gives the correct overall coefficient.

Draw all the connected diagrams containing four dots. There are six diagrams in total; be careful to avoid drawing two diagrams that look superficially different but are actually the same. Which of the diagrams would remain connected if any single dot were removed?

Show that the Lennard-Jones potential reaches its minimum value at r=r0, and that its value at this minimum is -u0. At what value of rdoes the potential equal zero?

The Ising model can be used to simulate other systems besides ferromagnets; examples include anti ferromagnets, binary alloys, and even fluids. The Ising model of a fluid is called a lattice gas. We imagine that space is divided into a lattice of sites, each of which can be either occupied by a gas molecule or unoccupied. The system has no kinetic energy, and the only potential energy comes from interactions of molecules on adjacent sites. Specifically, there is a contribution of -u0to the energy for each pair of neighbouring sites that are both occupied.

(a) Write down a formula for the grand partition function for this system, as a function of u0, T, and p.

(b) Rearrange your formula to show that it is identical, up to a multiplicative factor that does not depend on the state of the system, to the ordinary partition function for an Ising ferromagnet in the presence of an external magnetic field B, provided that you make the replacements u04ϵand μ2μBB-8ϵ. (Note that is the chemical potential of the gas while uB is the magnetic moment of a dipole in the magnet.)

(c) Discuss the implications. Which states of the magnet correspond to low density states of the lattice gas? Which states of the magnet correspond to high-density states in which the gas has condensed into a liquid? What shape does this model predict for the liquid-gas phase boundary in the P-T plane?

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