Chapter 8: Q 8.20 (page 345)
Use a computer to plot as a function of kT/, as predicted by mean field theory, for a two-dimensional Ising model (with a square lattice).
Short Answer
Therefore,
Chapter 8: Q 8.20 (page 345)
Use a computer to plot as a function of kT/, as predicted by mean field theory, for a two-dimensional Ising model (with a square lattice).
Therefore,
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Get started for freeConsider an Ising model of just two elementary dipoles, whose mutual interaction energy is . Enumerate the states of this system and write down their Boltzmann factors. Calculate the partition function. Find the probabilities of finding the dipoles parallel and antiparallel, and plot these probabilities as a function of . Also calculate and plot the average energy of the system. At what temperatures are you more likely to find both dipoles pointing up than to find one up and one down?
Modify the ising program to compute the average energy of the system over all iterations. To do this, first add code to the initialise subroutine compute the initial energy of the lattice; then, whenever a dipole is flipped, change the energy variable by the appropriate amount. When computing the average energy, be sure to average over all iterations, not just those iterations in which a dipole is actually flipped (why?). Run the program for a 5 x 5 lattice for T values from 4 down to l in reasonably small intervals, then plot the average energy as a function of T. Also plot the heat capacity. Use at least 1000 iterations per dipole for each run, preferably more. If your computer is fast enough, repeat for a 10x 10 lattice and for a 20 x 20 lattice. Discuss the results. (Hint: Rather than starting over at each temperature with a random initial state, you can save time by starting with the final state generated at the previous, nearby temperature. For the larger lattices you may wish to save time by considering only a smaller temperature interval, perhaps from 3 down to 1.5.)
Keeping only the first two diagrams in equation , and approximating expand the exponential in a power series through the third power. Multiply each term out, and show that all the numerical coefficients give precisely the correct symmetry factors for the disconnected diagrams.
At T = 0, equation 8.50 says that . Work out the first temperature-dependent correction to this value, in the limit . Compare to the low-temperature behaviour of a real ferromagnet, treated in Problem 7.64.
Use the cluster expansion to write the total energy of a monatomic nonideal gas in terms of a sum of diagrams. Keeping only the first diagram, show that the energy is approximatelyUse a computer to evaluate this integral numerically, as a function of T, for the Lennard-Jones potential. Plot the temperature-dependent part of the correction term, and explain the shape of the graph physically. Discuss the correction to the heat capacity at constant volume, and compute this correction numerically for argon at room temperature and atmospheric pressure.
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