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For each of the diagrams shown in equation 8.20, write down the corresponding formula in terms of f-functions, and explain why the symmetry factor gives the correct overall coefficient.

Short Answer

Expert verified

The formula for the figures are:

(a)=12(N)(N-1)1V2d3r1d3r2f12

(b)=12(N)(N-1)(N-2)1V3d3r1d3r2d3r3f12f13

(c)=18(N)(N-1)(N-2)(N-3)1V4d3r1d3r2d3r3d3r4f12f34

(d)=16(N)(N-1)(N-2)1V3d3r1d3r2d3r3f12f23f13

(e)=16(N)(N-1)(N-2)(N-3)1V4d3r1d3r2d3r3d3r4f12f23f24

(f)=14(N)(N-1)(N-2)(N-3)(N-4)1V5d3r1d3r2d3r3d3r4d3r5f12f34f45

(g)=148(N)(N-1)(N-2)(N-3)(N-4)(N-5)1V6d3r1d3r2d3r3d3r4d3r5d3r6f12f34f56

(h)=16(N)(N-1)(N-2)(N-3)1V4d3r1d3r2d3r3d3r4f12f13f24

Step by step solution

01

Step 1. The rules which helps in converting pictures into the formula:

(1) For each dot the equation is written as ias1Vd3ri, than for 1 dot multiply it by N, for 2 multiply by N-1and for 3 dot multiply by N-2and so on.

(2) The factor fijis written for the line which connects the iand jdots.

(3) Divide the equation by the symmetric factor of the diagram. Symmetric factor is defined as the permutation of dots that does not alter the figure.

02

Step 2. The diagrams given in the equation

Figure : The representation of give diagrams in numbers.
03

Step 3. The representation of give diagrams in numbers. 

(a) Equation for 2 dots:

1V2d3r1d3r2

Multiplying the equation with N,N-1for 2 dots

(N)(N-1)1V2d3r1d3r2

The factor for two dots isf12

(N)(N-1)1V2d3r1d3r2f12

The symmetry factor for the two dots is 2 because the two dots is arranged in two ways.

Thus, the formula for two dots in the figure becomes,

(a)=12(N)(N-1)1V2d3r1d3r2f12

(b) Equation for 3 dots:

1V3d3r1d3r2d3r3

Multiplying with N,N-1,N-2for 3 dots

(N)(N-1)(N-2)1V3d3r1d3r2d3r3

The factor for two dots is f12,f13

(N)(N-1)(N-2)1V3d3r1d3r2d3r3f12f13

The symmetry factor for the three dots is 2 because the first and third dot is arranged in two ways.

Thus, the formula for three dots in the figure becomes,

(b)=12(N)(N-1)(N-2)1V3d3r1d3r2d3r3f12f13.

04

Step 4. Equation for (c) and (d) part.

(c) Equation for 4 dots:

1V4d3r1d3r2d3r3d3r4

Multiplying by N,N-1,N-2,N-3for 4 dots,

(N)(N-1)(N-2)(N-3)1V4d3r1d3r2d3r3d3r4

The factors for 4 dots are f12andf34,

(N)(N-1)(N-2)(N-3)1V4d3r1d3r2d3r3d3r4f12f34,

The symmetry factor 4 dots is 8

Thus, the formula for 4 dots become:

(c)=18(N)(N-1)(N-2)(N-3)1V4d3r1d3r2d3r3d3r4f12f34

(d) Equation for 3 dots:

1V3d3r1d3r2d3r3

Multiplying with N,N-1,N-2for three dots,

(N)(N-1)(N-2)1V3d3r1d3r2d3r3

The factor for three dots are f12,f23,f13,

(N)(N-1)(N-2)1V3d3r1d3r2d3r3f12f23f13

The symmetry factor for 3 dots in the figure is 6, because of the addition of third line in dots

Thus, the formula for the figure is,

(d)=16(N)(N-1)(N-2)1V3d3r1d3r2d3r3f12f23f13

05

Step 5. Equation for (e) and (f) part

(e) Equation for 4 dots:

1V4d3r1d3r2d3r3d3r4

Multiplying with N,N-1,N-2,N-3for 4 dots,

(N)(N-1)(N-2)(N-3)1V4d3r1d3r2d3r3d3r4

The factor for 4 dots for the figure is,f12,f23,andf24

(N)(N-1)(N-2)(N-3)1V4d3r1d3r2d3r3d3r4f12f23f24

The symmetry factor for the figure is 6, attained by putting dot 2 in center and arrange the other dots. So this is arranged in 6 ways.

Thus, the formula for figure (e) is:

(e)=16(N)(N-1)(N-2)(N-3)1V4d3r1d3r2d3r3d3r4f12f23f24

(f) Equation for 5 dots:

1V5d3r1d3r2d3r3d3r4d3r5

Multiplying with N,N-1,N-2,N-3,N-4for 5 Dots,

(N)(N-1)(N-2)(N-3)(N-4)1V5d3r1d3r2d3r3d3r4d3r5

The factor for 5 dots is f12f34f45.

(N)(N-1)(N-2)(N-3)(N-4)1V5d3r1d3r2d3r3d3r4d3r5f12f34f45

The symmetry factor for the figure is 4, by putting dot number 4 in center, the other number is arranged in 4 ways.

Thus, the formula for figure (f) is

(f)=14(N)(N-1)(N-2)(N-3)(N-4)1V5d3r1d3r2d3r3d3r4d3r5f12f34f45.

06

Step 6. Equation for (g) and (h) part

(g) Equation for 6 dots:

1V6d3r1d3r2d3r3d3r4d3r5d3r6

Multiplying by N,N-1,N-2,N-3,N-4,N-5for 6 dots,

(N)(N-1)(N-2)(N-3)(N-4)(N-5)1V6d3r1d3r2d3r3d3r4d3r5d3r6

The factors for 6 dots are f12f34f56,

(N)(N-1)(N-2)(N-3)(N-4)(N-5)1V6d3r1d3r2d3r3d3r4d3r5d3r6f12f34f56

The symmetry factor for 6 dots is 48.

Thus, the formula for 6 dots become:

(g)=148(N)(N-1)(N-2)(N-3)(N-4)(N-5)1V6d3r1d3r2d3r3d3r4d3r5d3r6f12f34f56

(h) Equation for 4 dots:

1V4d3r1d3r2d3r3d3r4

Multiplying by N,N-1,N-2,N-3for 4 dots,

(N)(N-1)(N-2)(N-3)1V4d3r1d3r2d3r3d3r4

The factors for figure are f12f13f24,

(N)(N-1)(N-2)(N-3)1V4d3r1d3r2d3r3d3r4f12f13f24

The symmetry factor for the figure is 6, attained by putting one dot fixed and arrange the other dots. So this is arranged in 6 ways.

Thus the formula for the figure:

(h)=16(N)(N-1)(N-2)(N-3)1V4d3r1d3r2d3r3d3r4f12f13f24

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Most popular questions from this chapter

Draw all the connected diagrams containing four dots. There are six diagrams in total; be careful to avoid drawing two diagrams that look superficially different but are actually the same. Which of the diagrams would remain connected if any single dot were removed?

The Ising model can be used to simulate other systems besides ferromagnets; examples include anti ferromagnets, binary alloys, and even fluids. The Ising model of a fluid is called a lattice gas. We imagine that space is divided into a lattice of sites, each of which can be either occupied by a gas molecule or unoccupied. The system has no kinetic energy, and the only potential energy comes from interactions of molecules on adjacent sites. Specifically, there is a contribution of -u0to the energy for each pair of neighbouring sites that are both occupied.

(a) Write down a formula for the grand partition function for this system, as a function of u0, T, and p.

(b) Rearrange your formula to show that it is identical, up to a multiplicative factor that does not depend on the state of the system, to the ordinary partition function for an Ising ferromagnet in the presence of an external magnetic field B, provided that you make the replacements u04ϵand μ2μBB-8ϵ. (Note that is the chemical potential of the gas while uB is the magnetic moment of a dipole in the magnet.)

(c) Discuss the implications. Which states of the magnet correspond to low density states of the lattice gas? Which states of the magnet correspond to high-density states in which the gas has condensed into a liquid? What shape does this model predict for the liquid-gas phase boundary in the P-T plane?

Modify the ising program to compute the average energy of the system over all iterations. To do this, first add code to the initialise subroutine compute the initial energy of the lattice; then, whenever a dipole is flipped, change the energy variable by the appropriate amount. When computing the average energy, be sure to average over all iterations, not just those iterations in which a dipole is actually flipped (why?). Run the program for a 5 x 5 lattice for T values from 4 down to l in reasonably small intervals, then plot the average energy as a function of T. Also plot the heat capacity. Use at least 1000 iterations per dipole for each run, preferably more. If your computer is fast enough, repeat for a 10x 10 lattice and for a 20 x 20 lattice. Discuss the results. (Hint: Rather than starting over at each temperature with a random initial state, you can save time by starting with the final state generated at the previous, nearby temperature. For the larger lattices you may wish to save time by considering only a smaller temperature interval, perhaps from 3 down to 1.5.)

You can estimate the size of any diagram by realizing that fr is of order 1 out to a distance of about the diameter of a molecule, andf0 beyond that. Hence, a three-dimensional integral of a product of f's will generally give a result that is of the order of the volume of a molecule. Estimate the sizes of all the diagrams shown explicitly in equation8.20 and explain why it was necessary to rewrite the series in exponential form.

The critical temperature of iron is 1043K. Use this value to make a rough estimate of the dipole-dipole interaction energy ε, in electron-volts.

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