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In Problem 1.55 you used the virial theorem to estimate the heat capacity of a star. Starting with that result, calculate the entropy of a star, first in terms of its average temperature and then in terms of its total energy. Sketch the entropy as a function of energy, and comment on the shape of the graph.

Short Answer

Expert verified

The required expression for the entropy of a star is S=-32NKln2U3NK+f(N,V)and the graph can be sketched as below.

Step by step solution

01

Given Information

The heat capacity of a star that was estimated using the virial theorem is given as:

CV=-32NK

Where,

Nis the number of particles (typically dissociated protons and electrons).

The negative sign symbolizes that it is a gravitational bound system.

02

Calculation

The change in entropy is given as:

S=CV(T)TdT

Where,

CV= specific heat

T= Temperature in Kelvin

By substituting the value of CVin the above equation, we get,

S=-32NKTdTS=-32NK1TdTS=-32NKTln(T)+f(N,V)..........(1)

In this equation, fis the function of Nand volume V.

Total energy of gravitationally bound system is negative and from the virial theorem, it is found that:

U=-K=-32NKT

By rearranging the terms, we get,

T=-2U3NK

By substituting this value in equation (1), we get,

S=-32NKln2U3NK+f(N,V)

For plotting the graph, let us further simplify the above equation,

S=-32NKln(U)-32NKln3NK2+f(N,V)S=-32NKln(U)+g(N,V)

From the above equation, the graph can be plotted as below:

03

Final answer

Hence, the required expression is: S=-32NKln2U3NK+f(N,V)

The graph of entropy as a function can be sketched as follow:

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Most popular questions from this chapter

Show that the entropy of a two-state paramagnet, expressed as a function of temperature, is S=Nk[ln(2coshx)xtanhx], where x=μB/kT. Check that this formula has the expected behavior as T0and T.

Use a computer to study the entropy, temperature, and heat capacity of an Einstein solid, as follows. Let the solid contain 50 oscillators (initially), and from 0 to 100 units of energy. Make a table, analogous to Table 3.2, in which each row represents a different value for the energy. Use separate columns for the energy, multiplicity, entropy, temperature, and heat capacity. To calculate the temperature, evaluate ΔU/ΔSfor two nearby rows in the table. (Recall that U=qϵfor some constant ϵ.) The heat capacity (ΔU/ΔT)can be computed in a similar way. The first few rows of the table should look something like this:

(In this table I have computed derivatives using a "centered-difference" approximation. For example, the temperature .28is computed as 2/(7.15-0).) Make a graph of entropy vs. energy and a graph of heat capacity vs. temperature. Then change the number of oscillators to 5000 (to "dilute" the system and look at lower temperatures), and again make a graph of heat capacity vs. temperature. Discuss your prediction for the heat capacity, and compare it to the data for lead, aluminum, and diamond shown in Figure 1.14. Estimate the numerical value of εin electron-volts, for each of those real solids.

In order to take a nice warm bath, you mix 50 liters of hot water at 55°C with 25 liters of cold water at 10°C. How much new entropy have you created by mixing the water?

Use a computer to reproduce Table 3.2 and the associated graphs of entropy, temperature, heat capacity, and magnetization. (The graphs in this section are actually drawn from the analytic formulas derived below, so your numerical graphs won't be quite as smooth.)

As shown in Figure 1.14, the heat capacity of diamond near room temperature is approximately linear in T. Extrapolate this function up to 500K, and estimate the change in entropy of a mole of diamond as its temperature is raised from298K to 500K. Add on the tabulated value at298K (from the back of this book) to obtain S(500K).

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