Chapter 3: Q. 3.12 (page 97)
Estimate the change in the entropy of the universe due to heat escaping from your home on a cold winter day.
Short Answer
The entropy change on a cold winter day can be estimated to be.
Chapter 3: Q. 3.12 (page 97)
Estimate the change in the entropy of the universe due to heat escaping from your home on a cold winter day.
The entropy change on a cold winter day can be estimated to be.
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Get started for freeUse the definition of temperature to prove the zeroth law of thermodynamics, which says that if system A is in thermal equilibrium with system B, and system B is in thermal equilibrium with system C, then system A is in thermal equilibrium with system C. (If this exercise seems totally pointless to you, you're in good company: Everyone considered this "law" to be completely obvious until 1931, when Ralph Fowler pointed out that it was an unstated assumption of classical thermodynamics.)
In Problem you computed the entropy of an ideal monatomic gas that lives in a two-dimensional universe. Take partial derivatives with respect to , and N to determine the temperature, pressure, and chemical potential of this gas. (In two dimensions, pressure is defined as force per unit length.) Simplify your results as much as possible, and explain whether they make sense.
A liter of air, initially at room temperature and atmospheric pressure, is heated at constant pressure until it doubles in volume. Calculate the increase in its entropy during this process.
What partial-derivative relation can you derive from the thermodynamic identity by considering a process that takes place at constant entropy? Does the resulting equation agree with what you already knew? Explain.
When the sun is high in the sky, it delivers approximately 1000 watts of power to each square meter of earth's surface. The temperature of the surface of the sun is about , while that of the earth is about .
(a) Estimate the entropy created in one year by the flow of solar heat onto a square meter of the earth.
(b) Suppose you plant grass on this square meter of earth. Some people might argue that the growth of the grass (or of any other living thing) violates the second law of thermodynamics, because disorderly nutrients are converted into an orderly life form. How would you respond?
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