Chapter 5: Q 5.83 (page 211)
Write down the equilibrium condition for each of the following reactions:
Short Answer
Hence, the equilibrium condition for each reaction is given.
Chapter 5: Q 5.83 (page 211)
Write down the equilibrium condition for each of the following reactions:
Hence, the equilibrium condition for each reaction is given.
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Get started for freeCompare expression 5.68 for the Gibbs free energy of a dilute solution to expression 5.61 for the Gibbs free energy of an ideal mixture. Under what circumstances should these two expressions agree? Show that they do agree under these circumstances, and identify the function f(T, P) in this case.
When solid quartz "dissolves" in water, it combines with water molecules in the reaction
(a) Use this data in the back of this book to compute the amount of silica dissolved in water in equilibrium with solid quartz, at 25° C
(b) Use the van't Hoff equation (Problem 5.85) to compute the amount of silica dissolved in water in equilibrium with solid quartz at 100°C.
The metabolism of a glucose molecule (see previous problem) occurs in many steps, resulting in the synthesis of 38 molecules of ATP (adenosine triphosphate) out of ADP (adenosine diphosphate) and phosphate ions. When the ATP splits back into ADP and phosphate, it liberates energy that is used in a host of important processes including protein synthesis, active transport of molecules across cell membranes, and muscle contraction. In a muscle, the reaction ATP ADP + phosphate is catalyzed by an enzyme called myosin that is attached to a muscle filament. As the reaction takes place, the myosin molecule pulls on an adjacent filament, causing the muscle to contract. The force it exerts averages about 4 piconewtons and acts over a distance of about . From this data and the results of the previous problem, compute the "efficiency" of a muscle, that is, the ratio of the actual work done to the maximum work that the laws of thermodynamics would allow.
Suppose that an unsaturated air mass is rising and cooling at the dry adiabatic lapse rate found in problem 1.40. If the temperature at ground level is 25 C and the relative humidity there is 50%, at what altitude will this air mass become saturated so that condensation begins and a cloud forms (see Figure 5.18)? (Refer to the vapor pressure graph drawn in Problem 5.42)
Suppose you start with a liquid mixture of 60% nitrogen and 40% oxygen. Describe what happens as the temperature of this mixture increases. Be sure to give the temperatures and compositions at which boiling begins and ends.
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