Chapter 5: Q. 5.21 (page 163)
Is heat capacity (C) extensive or intensive? What about specific heat (c) ? Explain briefly.
Short Answer
Heat capacity is an extensive property
Specific heat is an intensive property.
Chapter 5: Q. 5.21 (page 163)
Is heat capacity (C) extensive or intensive? What about specific heat (c) ? Explain briefly.
Heat capacity is an extensive property
Specific heat is an intensive property.
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Get started for freeConsider again the aluminosilicate system treated in Problem 5.29. Calculate the slopes of all three phase boundaries for this system: kyanite andalusite, kyanite-sillimanite, and andalusite-sillimanite. Sketch the phase diagram, and calculate the temperature and pressure of the triple point.
The standard enthalpy change upon dissolving one mole of oxygen at 25°C is -11.7 kJ. Use this number and the van't Hoff equation (Problem 5.85) to calculate the equilibrium (Henry's law) constant for oxygen in water at 0°C and at 100° C. Discuss the results briefly.
Osmotic pressure measurements can be used to determine the molecular weights of large molecules such as proteins. For a solution of large molecules to qualify as "dilute," its molar concentration must be very low and hence the osmotic pressure can be too small to measure accurately. For this reason, the usual procedure is to measure the osmotic pressure at a variety of concentrations, then extrapolate the results to the limit of zero concentration. Here are some data for the protein hemoglobin dissolved in water at :
Concentration (grams/liter) | (cm) |
5.6 | 2.0 |
16.6 | 6.5 |
32.5 | 12.8 |
43.4 | 17.6 |
54.0 | 22.6 |
The quantity is the equilibrium difference in fluid level between the solution and the pure solvent,. From these measurements, determine the approximate molecular weight of hemoglobin (in grams per mole).
An experimental arrangement for measuring osmotic pressure. Solvent flows across the membrane from left to right until the difference in fluid level,, is just enough to supply the osmotic pressure.
Go through the arithmetic to verify that diamond becomes more stable than graphite at approximately 15 kbar.
Prove that the entropy of mixing of an ideal mixture has an infinite slope, when plotted vs. x, at x = 0 and x= 1.
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