Chapter 5: 5.21 (page 166)
Is heat capacity (C) extensive or intensive? What about specific heat (c) ? Explain briefly.
Short Answer
Heat capacity is an extensive property
Specific heat is an intensive property.
Chapter 5: 5.21 (page 166)
Is heat capacity (C) extensive or intensive? What about specific heat (c) ? Explain briefly.
Heat capacity is an extensive property
Specific heat is an intensive property.
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Get started for freeWhen plotting graphs and performing numerical calculations, it is convenient to work in terms of reduced variables, Rewrite the van der Waals equation in terms of these variables, and notice that the constants a and b disappear.
Graphite is more compressible than diamond.
(a) Taking compressibilities into account, would you expect the transition from graphite to diamond to occur at higher or lower pressure than that predicted in the text?
(b) The isothermal compressibility of graphite is about 3 x 10-6 bar-1, while that of diamond is more than ten times less and hence negligible in comparison. (Isothermal compressibility is the fractional reduction in volume per unit increase in pressure, as defined in Problem 1.46.) Use this information to make a revised estimate of the pressure at which diamond becomes more stable than graphite (at room temperature).
Use the result of the previous problem to calculate the freezing temperature of seawater.
Plot the Van der Waals isotherm for T/Tc = 0.95, working in terms of reduced variables. Perform the Maxwell construction (either graphically or numerically) to obtain the vapor pressure. Then plot the Gibbs free energy (in units of NkTc) as a function of pressure for this same temperature and check that this graph predicts the same value for the vapor pressure.
Because osmotic pressures can be quite large, you may wonder whether the approximation made in is valid in practice: Is really a linear function of to the required accuracy? Answer this question by discussing whether the derivative of this function changes significantly, over the relevant pressure range, in realistic examples.
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