Chapter 1: Q 1.63 (page 44)
At about what pressure would the mean free path of an air molecule at room temperature equal , the size of a typical laboratory apparatus?
Short Answer
The mean free path pressure is
Chapter 1: Q 1.63 (page 44)
At about what pressure would the mean free path of an air molecule at room temperature equal , the size of a typical laboratory apparatus?
The mean free path pressure is
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Get started for freeCalculate the total thermal energy in a liter of helium at room temperature and atmospheric pressure. Then repeat the calculation for a liter of air.
Problem 1.36. In the course of pumping up a bicycle tire, a liter of air at atmospheric pressure is compressed adiabatically to a pressure of 7 atm. (Air is mostly diatomic nitrogen and oxygen.)
(a) What is the final volume of this air after compression?
(b) How much work is done in compressing the air?
(c) If the temperature of the air is initially , what is the temperature after compression?
Two identical bubbles of gas form at the bottom of a lake, then rise to the surface. Because the pressure is much lower at the surface than at the bottom, both bubbles expand as they rise. However, bubble A rises very quickly, so that no heat is exchanged between it and the water. Meanwhile, bubble B rises slowly (impeded by a tangle of seaweed), so that it always remains in thermal equilibrium with the water (which has the same temperature everywhere). Which of the two bubbles is larger by the time they reach the surface? Explain your reasoning fully.
Measured heat capacities of solids and liquids are almost always at constant pressure, not constant volume. To see why, estimate the pressure needed to keep fixed as increases, as follows.
(a) First imagine slightly increasing the temperature of a material at constant pressure. Write the change in volume,, in terms of and the thermal expansion coefficient introduced in Problem 1.7.
(b) Now imagine slightly compressing the material, holding its temperature fixed. Write the change in volume for this process, , in terms of and the isothermal compressibility , defined as
(c) Finally, imagine that you compress the material just enough in part (b) to offset the expansion in part (a). Then the ratio of is equal to , since there is no net change in volume. Express this partial derivative in terms of . Then express it more abstractly in terms of the partial derivatives used to define . For the second expression you should obtain
This result is actually a purely mathematical relation, true for any three quantities that are related in such a way that any two determine the third.
(d) Compute for an ideal gas, and check that the three expressions satisfy the identity you found in part (c).
(e) For water at . Suppose you increase the temperature of some water from . How much pressure must you apply to prevent it from expanding? Repeat the calculation for mercury, for which and
Given the choice, would you rather measure the heat capacities of these substances at constant or at constant ?
Given an example to illustrate why you cannot accurately judge the temperature of an object by how hot or cold it feels to the touch?
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