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Your 200gcup of tea is boiling-hot. About how much ice should you add to bring it down to a comfortable sipping temperature of 65C? (Assume that the ice is initially at -15C. The specific heat capacity of ice is (0.5cal/gC..)

Short Answer

Expert verified

The sum of these three heat is equal to the heat lost by the team=45.9g

Step by step solution

01

Step : 1 Thermal capacity

We have a 200gram cup of boiling tea and want to chill it down to 65oCbefore drinking it, so we put a mass mof ice (at -15OC) into it. Given that ice has a thermal capacity of Assuming that the tea has the same heat capacity as pure water 1calg1K1, the tea's heat capacity must fall by 35, implying that it must give up some heat:

Qwater=mcΔT

Qtea=200×1×(35)=7000cal

02

Step : 2  Stages of melting ice 

The required heat to raise the temperature of ice to its melting point in the first phase is:

Q1=mcΔT

where mis the ice's mass, cis the ice's specific heat 0.5calg1K1is the temperature difference between the ice's original temperature and the melting point, so:

Q1=m0.5×(0(15))=7.5mcal

The amount of heat necessary to melt the ice in the second stage is:

Q2=m×L

where Lis the heat 80cal/gfor melting ice

Q2=m×80=80mcal

The amount of heat lost by the tea in the third phase to achieve a water temperature of 650Cis,

Q3=mcΔT

where mis the mass of melted ice (water), and cis water's specific heat.1calg1K1andΔT is the temperature difference between the beginning temperature of melting ice and the ultimate temperature of the combination at 650C.

03

Step :3 Sum of three heat

Because the sum of these three heats equals the heat lost by the tea, equations (1),(2),(3)and(4) can be used,

Qtea=Q1+Q2+Q3

7000=7.5m+80m+65m=152.5m

m=45.9g

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Most popular questions from this chapter

For a solid, we also define the linear thermal expansion coefficient, α, as the fractional increase in length per degree:

αΔL/LΔT
(a) For steel, α is 1.1 x 10-5 K-1. Estimate the total variation in length of a 1 km steel bridge between a cold winter night and a hot summer day.
(b) The dial thermometer in Figure 1.2 uses a coiled metal strip made of two different metals laminated together. Explain how this works.
(c) Prove that the volume thermal expansion coefficient of a solid is equal to the sum of its linear expansion coefficients in the three directions β=αx + αy + αz. (So for an isotropic solid, which expands the same in all directions, β =3 α .)


Does it ever make sense to say that one object is "twice as hot" as another? Does it matter whether one is referring to Celsius or Kelvin temperatures? Explain.

Even at low density, real gases don’t quite obey the ideal gas law. A systematic way to account for deviations from ideal behavior is the virial

expansion,

PVnRT(1+B(T)(V/n)+C(T)(V/n)2+)

where the functions B(T), C(T), and so on are called the virial coefficients. When the density of the gas is fairly low, so that the volume per mole is large, each term in the series is much smaller than the one before. In many situations, it’s sufficient to omit the third term and concentrate on the second, whose coefficient B(T)is called the second virial coefficient (the first coefficient is 1). Here are some measured values of the second virial coefficient for nitrogen (N2):

T(K)
B(cm3/mol)
100–160
200–35
300–4.2
4009.0
50016.9
60021.3
  1. For each temperature in the table, compute the second term in the virial equation, B(T)/(V/n), for nitrogen at atmospheric pressure. Discuss the validity of the ideal gas law under these conditions.
  2. Think about the forces between molecules, and explain why we might expect B(T)to be negative at low temperatures but positive at high temperatures.
  3. Any proposed relation between P, V, andT, like the ideal gas law or the virial equation, is called an equation of state. Another famous equation of state, which is qualitatively accurate even for dense fluids, is the van der Waals equation,
    (P+an2V2)(Vnb)=nRT
    where a and b are constants that depend on the type of gas. Calculate the second and third virial coefficients (Band C) for a gas obeying the van der Waals equation, in terms of aand b. (Hint: The binomial expansion says that (1+x)p1+px+12p(p1)x2, provided that |px|1. Apply this approximation to the quantity [1(nb/V)]1.)
  4. Plot a graph of the van der Waals prediction for B(T), choosing aand bso as to approximately match the data given above for nitrogen. Discuss the accuracy of the van der Waals equation over this range of conditions. (The van der Waals equation is discussed much further in Section 5.3.)

In analogy with the thermal conductivity, derive an approximate formula for the viscosity of an ideal gas in terms of its density, mean free path, and average thermal speed. Show explicitly that the viscosity is independent of pressure and proportional to the square root of the temperature. Evaluate your formula numerically for air at room temperature and compare to the experimental value quoted in the text.

Make a rough estimate of how far food coloring (or sugar) will diffuse through water in one minute.

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