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A particle near earth's surface traveling faster than about 11km/shas enough kinetic energy to completely escape from the earth, despite earth's gravitational pull. Molecules in the upper atmosphere that are moving faster than this will therefore escape if they do not suffer any collisions on the way out.

(a) The temperature of earth's upper atmosphere is actually quite high, around 1000K.Calculate the probability of a nitrogen molecule at this temperature moving faster than 11km/s, and comment on the result.

(b) Repeat the calculation for a hydrogen molecule (H2)and for a helium atom, and discuss the implications.

(c) Escape speed from the moon's surface is only about 2.4km/s. Explain why the moon has no atmosphere.

Short Answer

Expert verified

(a) The probability of a nitrogen molecule at this temperature moving faster than 11Km/sis P0thus N2molecule won't be escaping to all.

(b) The calculation for a hydrogen molecule (H2)and for a Helium (He)atom and the implications islocalid="1650900603347" P1.4e-120Thus, all these gas molecules are not able to escape the atmosphere.

(c) All gas molecules escape and there is no atmosphere left on the moon.

Step by step solution

01

Part(a) Step1: Given information

We are given that,

escape velocity =11km/s

Temperature,T=1000k

02

Part(a) Step2: simplify

The probability density function for velocity in a gas is given by the maxwell Boltzmann distribution

f(v)=m2πRT324πv2e-mv2RT

therefore probability of velocity being greater than 11km/sis

P(v>11km/s)=11,000f(v)dv

P=11,000m2πRT324πv2e-mv2RTdv

Replacing vx&a=RT2m

we get,

P=11,0002πx2e-x22a2a3dx

This, integral is not simple & we will need to use error function.

P=erfcx2a+2πxe-x22a2a

where, erfcis the error function complement

Here,erfc(x)=1π-xxe-t2dt

not possible by hand calculation, so using web tool

a=RT2m

where m=molecular mass of gases=28amu

a=1.38×10-23×10002×28×1.67×10-27

a=385.3

x2a=110002×385.3=20.188

erfc(20.188)0.0

P=0.0+2e-176

P0thus, the N2molecule wont be escaping at all.

03

Part(b) Step1: Given information

We are given that,

ForH2,

m=2venergy thing else is same.

m=2×1.67×10-27

04

Part(b) Step2: simplify

Now we put the values in formula,

a=1.38×10-23×10002×2×1.67×10-27

a=1441.63

x2a=5.39

localid="1650109697287" erfcx2a0

P=0+1.4e-12

P1.4e-120

thus, probability is still very small of velocity >11km/s.

Since the mass of helium lies in between that of hydrogen and N2,the velocity >11km/sis also0.

Thus all these gas molecules are not able to escape the atmosphere.

05

Part(c) Step1: given information

We are given that,

Since, the escape velocity of moon is 2.4km/s

06

Part(c) Step2: Explanation

The molecule of atmospheric gases on surface of moon can move with thermal velocities greater than the velocities of moon,

Thus, all gas molecules escape and there is no atmosphere left on moon.

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Most popular questions from this chapter

Consider a classical particle moving in a one-dimensional potential well ux, as shown. The particle is in thermal equilibrium with a reservoir at temperature T, so the probabilities of its various states are determined by Boltzmann statistics.

{a) Show that the average position of the particle is given by

x=xe-βuxdxe-βuxdx

where each integral is over the entire xaxis.

A one-dimensional potential well. The higher the temperature, the farther the particle will stray from the equilibrium point.

(b) If the temperature is reasonably low (but still high enough for classical mechanics to apply), the particle will spend most of its time near the bottom of the potential well. In that case we can expand u(z) in a Taylor series about the equilibrium point

ux=ux0+x-x0dudxx0+12x-x02d2udx2x0+13!x-x03d3udx3x0+........

Show that the linear term must be zero, and that truncating the series after the quadratic term results in the trivial prediction x=x0.

(c) If we keep the cubic term in the Taylor series as well, the integrals in the formula for xbecome difficult. To simplify them, assume that the cubic term is small, so its exponential can be expanded in a Taylor series (leaving the quadratic term in the exponent). Keeping only the smallest temperature-dependent term, show that in this limit x differs from by a term proportional to kT. Express the coefficient of this term in terms of the coefficients of the Taylor series ux

(d) The interaction of noble gas atoms can be modeled using the Lennard Jones potential,

ux=u0x0x12-2x0x6

Sketch this function, and show that the minimum of the potential well is at x=x0, with depth u0. For argon, x0=3.9Aand u0=0.010eV. Expand the Lennard-Jones potential in a Taylor series about the equilibrium point, and use the result of part ( c) to predict the linear thermal expansion coefficient of a noble gas crystal in terms of u0. Evaluate the result numerically for argon, and compare to the measured value α=0.0007K-1

A water molecule can vibrate in various ways, but the easiest type of vibration to excite is the "flexing' mode in which the hydrogen atoms move toward and away from each other but the HO bonds do not stretch. The oscillations of this mode are approximately harmonic, with a frequency of 4.8 x 1013Hz. As for any quantum harmonic oscillator, the energy levels are 12hf,32hf,52hf, and so on. None of these levels are degenerate.

(a) state and in each of the first two excited states, assuming that it is in equilibrium with a reservoir (say the atmosphere) at 300 K. (Hint: Calculate 2 by adding up the first few Boltzmann factors, until the rest are negligible.) Calculate the probability of a water molecule being in its flexing ground

(b) Repeat the calculation for a water molecule in equilibrium with a reservoir at 700 K (perhaps in a steam turbine).

Consider a hypothetical atom that has just two states: a ground state with energy zero and an excited state with energy 2 eV. Draw a graph of the partition function for this system as a function of temperature, and evaluate the partition function numerically at T = 300 K, 3000 K, 30,000 K, and 300,000 K.

The most common measure of the fluctuations of a set of numbers away from the average is the standard deviation, defined as follows.

(a) For each atom in the five-atom toy model of Figure 6.5, compute the deviation of the energy from the average energy, that is, Ei-E¯,fori=1to5. Call these deviations ΔEi.

(b) Compute the average of the squares of the five deviations, that is, ΔEi2¯. Then compute the square root of this quantity, which is the root-mean- square (rms) deviation, or standard deviation. Call this number σE. Does σEgive a reasonable measure of how far the individual values tend to stray from the average?

(c) Prove in general that

σE2=E2¯-(E¯)2

that is, the standard deviation squared is the average of the squares minus the square of the average. This formula usually gives the easier way of computing a standard deviation.

(d) Check the preceding formula for the five-atom toy model of Figure 6.5.

Prove that the probability of finding an atom in any particular energy level is P(E)=(1/Z)e-F/kT, whereF=E-TS and the "'entropy" of a level is k times the logarithm of the number of degenerate states for that level.

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