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A battery has specific capacity \(252 \frac{\mathrm{C}}{\mathrm{g}}\) and mass of \(50 \mathrm{~g}\). Its overall density is \(2.245 \frac{\mathrm{g}}{\mathrm{m}^{3}}\). (a) Find the specific capacity in \(\frac{\mathrm{mA} \cdot \mathrm{h}}{\mathrm{g}}\). (b) Find the capacity in mA.h. (c) Find the charge density in \(\frac{\mathrm{mA} \cdot \mathrm{h}}{\mathrm{m}^{3}}\).

Short Answer

Expert verified
(a) 70 mA.h/g; (b) 3500 mA.h; (c) 157.15 mA.h/m^3.

Step by step solution

01

Identify the Given Specific Capacity

The specific capacity of the battery is given as \(252 \frac{\mathrm{C}}{\mathrm{g}}\). The task is to convert this to \(\frac{\mathrm{mA} \cdot \mathrm{h}}{\mathrm{g}}\).
02

Convert Coulombs to Milliampere-Hours

Use the conversion factor: 1 Coulomb (C) = 1 Ampere-Second (A.s) and 1 mA.h = 3.6 Coulombs. Therefore, \(\frac{252 \text{ C}}{\text{g}} \times \frac{1 \text{ A.s}}{1 \text{ C}} \times \frac{1 \text{ mA.h}}{3.6 \text{ C}} = \frac{70 \text{ mA.h}}{\text{g}}\).
03

Calculate the Battery Capacity

The mass of the battery is given as \(50 \text{ g}\). To find the overall capacity of the battery, multiply the specific capacity in \(\frac{\mathrm{mA} \cdot \mathrm{h}}{\mathrm{g}}\) by the mass: \(70 \frac{\mathrm{mA} \cdot \mathrm{h}}{\mathrm{g}} \times 50 \text{ g} = 3500 \text{ mA.h}\).
04

Calculate the Charge Density

The overall density of the battery is \(2.245 \frac{\mathrm{g}}{\mathrm{m}^3}\). To find the charge density in terms of \(\frac{\mathrm{mA} \cdot \mathrm{h}}{\mathrm{m}^3}\), multiply the specific capacity converted in Step 2 by the density:\(70 \frac{\mathrm{mA} \cdot \mathrm{h}}{\mathrm{g}} \times 2.245 \frac{\mathrm{g}}{\mathrm{m}^3} = 157.15 \frac{\mathrm{mA} \cdot \mathrm{h}}{\mathrm{m}^3}\).

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Key Concepts

These are the key concepts you need to understand to accurately answer the question.

Understanding Specific Capacity
Specific capacity is an important metric in evaluating a battery's performance. It tells us how much electric charge a battery can store per unit mass.
This value is usually expressed in terms of Coulombs per gram (\(\frac{\mathrm{C}}{\mathrm{g}}\)) or in milliampere-hours per gram (\(\frac{\mathrm{mA}\cdot\mathrm{h}}{\mathrm{g}}\)).

To convert the specific capacity from \(\frac{\mathrm{C}}{\mathrm{g}}\) to \(\frac{\mathrm{mA}\cdot\mathrm{h}}{\mathrm{g}}\), we must use the relationship between Coulombs and milliampere-hours.
Remember, 1 Coulomb is equal to 1 Ampere-Second (A⋅s). Additionally, 1 milliampere-hour (mA⋅h) equals 3.6 Coulombs.

In our original problem, a specific capacity of \(252 \frac{\mathrm{C}}{\mathrm{g}}\) was given.
Using the relevant conversion factor, it was converted to \(70 \frac{\mathrm{mA}\cdot\mathrm{h}}{\mathrm{g}}\).
This conversion allows us to easily calculate and compare battery capacities in familiar units.
Exploring Charge Density
Charge density helps us understand how much charge is held in a specific volume of battery material.
It combines the specific capacity (charge per mass) with the overall material density.
For this reason, charge density is typically given in units of \(\frac{\mathrm{mA}\cdot \mathrm{h}}{\mathrm{m}^3}\).

To find the charge density, we multiply the specific capacity converted to \(\frac{\mathrm{mA}\cdot\mathrm{h}}{\mathrm{g}}\) by the battery's overall density.
  • In our case, the specific capacity conversion yielded \(70 \frac{\mathrm{mA}\cdot\mathrm{h}}{\mathrm{g}}\).
  • The battery's overall density was given as \(2.245 \frac{\mathrm{g}}{\mathrm{m}^3}\).
Multiply these two values to get \(157.15 \frac{\mathrm{mA}\cdot \mathrm{h}}{\mathrm{m}^3}\).
This reveals how effectively the battery material stores charge within a given volume.
Role of Conversion Factors
Conversion factors are essential for transforming quantities from one unit to another in scientific calculations. They make it easier to work with various units comfortably.
When dealing with electric charge and capacity in batteries, using the right conversion factors allows for a seamless transition between different measurements, such as from Coulombs to milliampere-hours.

In our example, we used the following key conversion factors:
  • 1 Coulomb \(= 1 \text{ A ⋅ s}\)
  • 1 milliampere-hour \(= 3.6 \text{ C}\)
Using these, we converted specific capacity from \(\frac{\mathrm{C}}{\mathrm{g}}\) to \(\frac{\mathrm{mA} \cdot \mathrm{h}}{\mathrm{g}}\), enabling further calculations for charge density.
Without these factors, accurately comparing and calculating dimensions would be challenging.
Understanding and applying conversion factors are vital skills in the study of batteries and electrical engineering.

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Most popular questions from this chapter

A battery has a specific capacity of \(55 \frac{\mathrm{mA} \cdot \mathrm{h}}{\mathrm{g}}\) and a nominal voltage of \(2.4 \mathrm{~V}\). The battery has a mass of \(165 \mathrm{~g}\). Find the energy stored in the battery in \(\mathrm{J}\).

A battery has a sulfur cathode where the reaction \(\mathrm{S}+2 e^{-} \rightarrow \mathrm{S}^{2-}\) occurs. The anode is made from a mystery material, \(X,\) and at the anode, the reaction \(\mathrm{X} \rightarrow \mathrm{X}^{2+}+2 e^{-}\) occurs. The theoretical specific capacity of the sulfur reaction is \(1.76 \frac{\mathrm{A} \cdot \mathrm{h}}{\mathrm{g}}\) and the theoretical specific capacity of material \(X\) is \(0.819 \frac{\mathrm{A} \cdot \mathrm{h}}{\mathrm{g}}\). The theoretical specific capacity of the materials combined is \(0.559 \frac{\mathrm{A} \cdot \mathrm{h}}{\mathrm{g}}\). What is material \(\mathrm{X},\) and what is \(V_{r p}\), the redox potential of the battery? (Hint: Use a periodic table and a list of redox potentials.)

Suppose the chemical reactions and corresponding redox potentials in a battery are given by [137]: \(\mathrm{Li} \rightarrow \mathrm{Li}^{+}+e^{-} \quad V_{r p}=3.04 \mathrm{~V}\) \(\mathrm{S}+2 e^{-} \rightarrow \mathrm{S}^{2-} \quad V_{r p}=-0.57 \mathrm{~V}\) (a) Find the overall theoretical specific capacity of the battery in \(\frac{\mathrm{C}}{\mathrm{g}}\). (b) Find the overall theoretical specific energy of the battery in \(\frac{\mathrm{J}}{\mathrm{g}}\). (c) Which material, lithium or sulfur, gets oxidized, and which material gets reduced?

Consider a battery with a lithium electrode and a silver chloride (AgCl) electrode. Assume the following chemical reactions occur in the battery, and the redox potential for each reaction is shown. \(\mathrm{AgCl}+e^{-} \rightarrow \mathrm{Ag}+\mathrm{Cl}^{-} \quad V_{r p}=0.22 \mathrm{~V}\) \(\mathrm{Li} \rightarrow \mathrm{Li}^{+}+e^{-} \quad V_{r p}=3.04 \mathrm{~V}\) (a) Which reaction is likely to occur at the cathode, and which reaction is likely to occur at the anode? Justify your answer. (b) What is the overall theoretical cell voltage? (c) If the battery is connected to a \(1 \mathrm{k} \Omega\) load, approximately what is the power delivered to that load?

A bottle contains 3 liters of a chemical solution with a pH of 8 . (a) Does the bottle contain an acid or a base? (b) Approximately how many \(\mathrm{H}^{+}\) ions are in the bottle? (c) Would a 3 liter bottle with a pH of 9 contain more or less ions of \(\mathrm{H}^{+}\) than the bottle with a \(\mathrm{pH}\) of 8 ? (d) How many times as many/few \(\mathrm{H}^{+}\) ions are in the bottle with solution of \(\mathrm{pH} 8\) than in the bottle with solution of \(\mathrm{pH} 9\) ?

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