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What is the relation between the standard deviation and the precision of a procedure? What is the relation between standard deviation and accuracy?

Short Answer

Expert verified

Precision is inversely related to standard deviation; the higher the standard deviation, the less exact the experiment. The link between accuracy and standard deviation, on the other hand, is not required.

Step by step solution

01

Definition of standard deviation, precision and accuracy.

  • The standard deviation is a measurement of a collection of values' variance or dispersion. A low standard deviation implies that the values are close to the set's mean, whereas a high standard deviation suggests that the values are dispersed over a larger range.
  • The precision of a material refers to how near two or more measurements are to one other.
  • The degree of similarity between a measurement and its real value is known as accuracy.
02

The relation between standard deviation and the precision of a procedure.

Precision, as defined, is the degree to which the obtained data are in agreement with one another. The standard deviation, which quantifies how near the data are to the estimated mean, may be used to judge whether an experiment is exact or not. As a result, standard deviation and accuracy are inversely proportional: the higher the standard deviation, the less exact the experiment.

03

The relation between standard deviation and accuaracy.

The term "accuracy" refers to how near the data is to the "true" value. As a result, since standard deviation solely evaluates experimental results, there is no required link between accuracy and standard deviation.

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Most popular questions from this chapter

Nitrite(NO2-)was measured by two methods in rainwater and unchlorinated drinking water. The resultsยฑstandard deviation (number of samples) are

SOURCE. Data from I. Sarudi and I. Nagy, Talanta 1995,42,1099

(a) Do the two methods agree with each other at theconfidence level for both rainwater and drinking water?

(b) For each method, does the drinking water contain significantly more nitrite than the rainwater (at the 95%confidence level)?

Consider the least-squares problem in Figure 4-11.

(a) Suppose that a single new measurement produces a yvalue of 2.58. Find the corresponding xvalue and its standard uncertainty, ux.

(b) Suppose you measure yfour times and the average is 2.58. Calculate uxbased on four measurements, not one.

(c) Find the 95%confidence intervals for (a) and (b).

The CdSe content (g/L) of six different samples of nanocrystals was measured by two methods. Do the two methods differ significantly at the 95 % confidence level?

Bicarbonate in replicate samples of horse blood was measured four times by each of two methods with the following results:

Method 1:31.40, 31.24, 31.18, 31.43 mM

Method 2:30.70, 29.49, 30.01, 30.15mM

(a) Find the mean, standard deviation, and standard uncertainty (= standard deviation of the mean) for each analysis.

(b) Are the standard deviations significantly different at the 95%confidence level?

A straight line is drawn through the points (3.0,-3.87ร—104),(10.0,-12.99ร—104),(20.0,-25.93ร—104),(30.0,-38.89ร—104), and (40.0,-51.96ร—104) to give m=-1.29872ร—104, b=256.695,um=13.190,ub=323.57, and sy=392.9. Express the slope and intercept and their uncertainties with reasonable significant figures.

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