Chapter 20: Q2P (page 525)
Explain how a laser generates light. List important properties of laser light.
Short Answer
The laser is based on quantum phenomena in the transmission of energy by radiation.
Chapter 20: Q2P (page 525)
Explain how a laser generates light. List important properties of laser light.
The laser is based on quantum phenomena in the transmission of energy by radiation.
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Get started for freeThe variation of refractive index, n, with wavelength for fused silica is given by
where is expressed in .
(a) Make a graph of n versus with points at the following wavelengths: 0.2,0.4,0.6,0.8,1,2,3,4,5, and .
(b) The ability of a prism to spread apart (disperse) neighboring wavelengths increases as the slope increases. Is the dispersion of fused silica greater for blue light or red light?
Explain how beam chopping reduces line noise and noise from source drift.
The prism shown here is used to totally reflect light at aangle. No surface of this prism is silvered. Use Snell's law to explain why total reflection occurs. What is the minimum refractive index of the prism for total reflection?
The path length of a cell for infrared spectroscopy can be measured by counting interference fringes (ripples in the transmission spectrum). The following spectrum shows 30interference maxima between 1906andobtained by placing an empty KBrcell in a spectrophotometer.
The fringes arise because light reflected from the cell compartment interferes constructively or destructively with the unreflected beam.
If the reflected beam travels an extra distance, it will interfere constructively with the unreflected beam. If the reflection path length is , destructive interference occurs. Peaks therefore arise when and troughs occur when, where is an integer. If the medium between KBr theplates has refractive index n, the wavelength in the medium is l/n, so the equations become . The cell path length can be shown to be given by
where Nmaxima occur between wavelengthsand. Calculate the path length of the cell that gave the interference fringes shown earlier.
Results of an electrochemical experiment are shown in the figure. In each case, a voltage is applied between two electrodes at timeand the absorbance of a solution decreases until the voltage is stepped back to its initial value at time. The upper traces show the average results for 100,300, and 1000 repetitions of the experiment. The measured signal-to-rms noise ratio in the upper trace is 60.0. Predict the signal-to-noise ratios expected for 300 cycles, 100 cycles, and 1 cycle and compare your answers with the observed values in the figure.
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